• Journal of the Korean Chemical Society
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• v.43 no.2
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• pp.161-166
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• 1999

Transfer of lanthanide ions across the liquid/liquid interface facilitated by ionopore ETH4120 has been studied by using cyclic voltammetry (CV) and chronopotentiometry with cyclic linear current-scanning (CPCLCS) under the condition where the concentration of ETH4120 in nitrobenzene was much smaller than the concentration of lanthanide ions in aqueous solution. One cathodic current peak (transfer from aqueous to nitrobenzene phase) and two anodic current waves (transfer from nitrobenzene to aqueous phase) were observed. The cathodic wave was due to the formation of 1:1 (metal:ligand) complex and two anodic waves showed successive formation of 1:2 and 1:3 complexes in nitrobenzene solution. But there was no cathodic wave corresponding to two anodic waves. The ion transfer mechanism has also been discussed.

• Biotechnology and Bioprocess Engineering:BBE
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• v.11 no.3
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• pp.245-250
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• 2006

The effects of aliphatic hydrocarbons (n-hexadecane and n-dodecane) on the volumetric oxygen mass transfer coefficient $(k_L\;a)$ were studied in flat alveolar airlift reactor and continuous stirred tank reactors (CSTRs). In the flat alveolar airlift reactor, high aeration rates (>2vvm) were required in order to obtain efficient organic-aqueous phase dispersion and reliable $k_La$ measurements. Addition of 1% (v/v) n-hexadecane or n-dodecane increased the $k_La$ 1.55- and 1.33-fold, respectively, compared to the control (superficial velocity: $25.8{\times}10^{-3}m/s$, sparger orifice diameter: 0.5 mm). Analysis of the gas-liquid interfacial area a and the liquid film mass transfer coefficient $k_L$ suggests that the observed $k_La$ increase was a function of the media's liquid film mass transfer. Addition of 1% (v/v) n-hexadecane or n-dodecane to analogous setups using CSTRs led to a $k_La$ increase by a factor of 1.68 and 1.36, respectively (superficial velocity: $2.1{\times}10^{-3}m/s$, stirring rate: 250 rpm). These results propose that low-concentration addition of oxygen-vectors to aerobic microbial cultures has additional benefit relative to incubation in purely aqueous media.

• Bulletin of the Korean Chemical Society
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• v.34 no.2
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• pp.475-481
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• 2013

By using ionic liquid 1-hexylpyridinium hexafluorophosphate ($HPPF_6$) based carbon ionic liquid electrode (CILE) as the substrate electrode, a $CoMoO_4$ nanorods and myoglobin (Mb) composite was casted on the surface of CILE with chitosan (CTS) as the film forming material to obtain the modified electrode (CTS/$CoMoO_4$-Mb/CILE). Spectroscopic results indicated that Mb retained its native structures without any conformational changes after mixed with $CoMoO_4$ nanorods and CTS. Electrochemical behaviors of Mb on the electrode were carefully investigated by cyclic voltammetry with a pair of well-defined redox peaks from the heme Fe(III)/Fe(II) redox center of Mb appeared, which indicated that direct electron transfer between Mb and CILE was realized. Electrochemical parameters such as the electron transfer number (n), charge transfer coefficient (${\alpha}$) and electron transfer rate constant ($k_s$) were estimated by cyclic voltammetry with the results as 1.09, 0.53 and 1.16 $s^{-1}$, respectively. The Mb modified electrode showed good electrocatalytic ability toward the reduction of trichloroacetic acid in the concentration range from 0.1 to 32.0 mmol $L^{-1}$ with the detection limit as 0.036 mmol $L^{-1}$ ($3{\sigma}$), and the reduction of $H_2O_2$ in the concentration range from 0.12 to 397.0 ${\mu}mol\;L^{-1}$ with the detection limit as 0.0426 ${\mu}mol\;L^{-1}$ ($3{\sigma}$).

• Korean Chemical Engineering Research
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• v.47 no.4
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• pp.459-464
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• 2009

Gas-liquid mass transfer characteristics were investigated in pressurized three-phase slurry bubble columns with variation of column diameter. Effects of gas velocity, operating pressure, liquid viscosity, solid content in the slurry phase and column diameter on the gas-liquid volumetric mass transfer coefficient($k_La$) were determined. The effects of operating variables on the mass transfer coefficient tended to change with variation of column diameter. The mass transfer coefficient increased with increasing gas velocity or operating pressure but decreased with increasing column diameter, liquid viscosity or solid concentration in the slurry phase. The increase trend of $k_La$ value with increasing gas velocity and the decrease trend of $k_La$ value with increasing liquid viscosity, tended to decrease gradually with increasing column diameter. However, the effects of operating pressure and solid concentration in the slurry phase on the $k_La$ value did not change considerably with variation of column diameter. The values of $k_La$ were well correlated with operating variables with in this experimental conditions as $k_La=0.02D^{-0.26}U_G^{0.28}P^{0.43}{\mu}_L^{-0.04}S_c^{-0.35}$.

• Journal of Information Display
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• v.2 no.4
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• pp.15-18
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• 2001

We report simple techniques to manufacture low-powered, high-resolution, reflective cholesteric displays using flexible plastic substrates. We use wax transfer printing to replace photo-lithography and incorporate polymer walls to increase the mechanical strength and lifetime of the displays. These printing methods can easily be adapted to roll-to-roll production.

• Journal of the Korean Society of Industry Convergence
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• v.3 no.3
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• pp.209-217
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• 2000

An attempt has been made to examine the highest liquid surface by means of measuring the movement of liquid free surface wave in the agitated vessel wall. Also, Relationship has been investigated between transition frequency, $N_z$ for behavior of liquid free surface and transition frequency for behavior of mass transfer coefficient in the agitated vessel wall. A surface wave is occured within agitated vessel, the highest height of wetted vessel wall, $h_w$ is coincided with the highest liquid surface, h. However the lowest height of wetted vessel, $h^*{_w}$ is not descended to lowest liquid free surface, $h^*$. The proposed model has been tested sucessfully for the behavior of liquid free surface.

• Structural Engineering and Mechanics
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• v.36 no.5
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• pp.561-573
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• 2010

The potential of the liquid column vibration absorber (LCVA) as a seismic vibration control device for structures has been explored in this paper. In this work, the structure has been modeled as a linear, viscously damped single-degree-of-freedom (SDOF) system. The governing differential equations of motion for the damper liquid and for the coupled structure-LCVA system have been derived from dynamic equilibrium. The nonlinear orifice damping in the LCVA has been linearized by a stochastic equivalent linearization technique. A transfer function formulation for the structure-LCVA system has been presented. The design parameters of the LCVA have been identified and by applying the transfer function formulation the optimum combination of these parameters has been determined to obtain the most efficient control performance of the LCVA in terms of the reduction in the root-mean-square (r.m.s.) displacement response of the structure. The study has been carried out for an example structure subjected to base input characterized by a white noise power spectral density function (PSDF). The sensitivity of the performance of the LCVA to the coefficient of head loss and to the tuning ratio have also been examined and compared with that of the liquid column damper (LCD). Finally, a simulation study has been carried out with a recorded accelerogram, to demonstrate the effectiveness of the LCVA.

• Progress in Superconductivity and Cryogenics
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• v.8 no.1
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• pp.65-70
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• 2006

Transient heat transfer caused by an impulsive heating in subcooled liquid nitrogen is investigated experimentally. This study is part of out ongoing efforts directed to a stable cryogenic cooling system lot superconducting fault current limiters (SFCL). A thin heater attached by epoxy on one surface of a GFRP plate is immersed in liquid-nitrogen bath at temperatures between 77 K and 55 K. A strong heat flux up to $150W/cm^2$ is generated lot 100 ms, and the temperature of the heater sulfate is measured as a function of time. The behavior of bubbles on the heating surface can be explained by comparing the measured temperature history for vertical and two horizontal (up and down) orientations. It is concluded that the subcooling of liquid nitrogen below 70 K is very effective in suppressing bubbles, resulting in better thermal protection and faster recovery from an impulsive heat.

• Journal of the Korean Society of Visualization
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• v.22 no.1
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• pp.6-17
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• 2024

This study examined the natural convection heat flow characteristics of the melting process of PCM (palm oil) inside a liquid flexitank(bag) for a cargo container. A film heating element was installed on the bottom of the container, and numerical analysis was performed under heat flux conditions of 1,000 to 4,000 W/m². As a result, the melt interface of the PCM rises to a nearly horizontal state over time. In the initial stage, conduction heat transfer dominates, but gradually waves at the cell flow and melt interfaces are formed due to natural convection heat transfer. As melting progresses, the Ra number increases parabolically, and the Nu number increases linearly and has a constant value. The Nu number rises slowly under low heat flux conditions, whereas under high heat flux conditions, the Nu number rises rapidly. As the heat flux increases, the internal temperature oscillation of the liquid phase after melting increases. However, under high heat flux conditions, excess heat exceeding the latent heat is generated, and the temperature of the molten liquid is raised, so the increase in melting rate decreases. Therefore, the appropriate heating element specification applied to a 20-ton palm oil container is 2,000 W/m².

• International Journal of Air-Conditioning and Refrigeration
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• v.13 no.2
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• pp.99-106
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• 2005

Falling film heat transfer has been widely used in many applications in which heat and mass transfer occur simultaneously, such as evaporative coolers, cooling towers, absorption chillers, etc. In such cases, it is desirable that the falling film spreads widely on the surface to form a thin liquid film to enlarge contact surface and to reduce the thermal resistance across the film and/or the flow resistance to the vapor stream over the film. In this respect, hydrophilic treatment of the surface has been tried to improve the surface wettability by decreasing the contact angle between the liquid and the surface. However, the hydrophilic treatment was found not very effective to increase the surface wettedness of inclined surfaces, since the liquid flow forms rivulet patterns instead of a thin film as it flows down the inclined surface and accelerates gradually by the gravity. In this work, a novel method is suggested to improve the surface wettedness enormously. In this work, the surface is treated to have a thin hydrophilic porous layer on the surface. With this treatment, the liquid can spread widely on the surface by the capillary force resulting from the porous structure. In addition to this, the liquid can be held within the porous structure to improve surface wettedness regardless of the surface inclination. The experiment on the evaporative cooling of inclined surfaces has been conducted to verify the effectiveness of the surface treatment. It is measured that the latent heat transfer increases almost by $80\%$ at the hydrophilic porous layer coated surface as compared with the untreated surface.