• Bulletin of the Korean Chemical Society
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• 제5권3호
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• pp.126-129
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• 1984

The reaction of aryl halides with phenoxides and alkoxides were investigated under phase transfer catalytic conditions. 2,4-Dinitro- and 4-nitrohalobenzenes reacted readily with phenoxides in NaOH(aq)-benzene in the presence of Bu4N+Br, affording the products quantitatively. Although the aryl halides did not react with alkoxides under the same condition, the reactions were completed within 2 hours at room temperature when conducted under solid-liquid phase transfenr catalytic condition. The reactivity of aryl halides was in the order, Ar = 2,4-dinitrophenyl > 4-nitrophenyl, and X = F > Cl, consistent with the SNAr mechanism. The reactivity of oxyanions increased with the change of reaction condition from liquid-liquid to solid-liquid phase transfer catalysis. The results were explained with the concentration and the degree of hydration of the anion in benzene.

• 대한기계학회논문집B
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• 제23권3호
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• pp.320-329
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• 1999

An experimental study has been performed to investigate the heat transfer characteristics of impinging jets with corrugated nozzle and wake generation plate. Three different shapes of corrugated nozzle and five different shapes of wake generation plate were tested to improve the heat transfer characteristics of impinging jet. Heat transfer coefficients were obtained by using transient method based on the liquid crystal thermography. The effects of corrugated nozzle and wake generation plate on the heat transfer characteristics of impinging jets were discussed in detail. The results showed that both the corrugated nozzle and the wake generation plate improved the heat transfer characteristics of impinging jet. Especially, heat transfer coefficients around stagnation region of impinging jets were highly increased.

• 한국분무공학회지
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• 제15권4호
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• pp.202-207
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• 2010

Mist cooling is widely employed as a cooling technique of high temperature surfaces, and it has heat transfer characteristics similar to boiling heat transfer which has the convection, nucleate and film boiling regions. In the present study, mist cooling heat transfer was experimentally investigated for the mist flow impacting on the heated surfaces of mico-fins. The mist flow was generated by supersonic vibration. Experiments were conducted under the test conditions of droplet flow rate, $Q=6.02{\times}10^{-9}{\sim}3.47{\times}10^{-8}\;m^3/s$ and liquid temperature, $T_f=30{\sim}35^{\circ}C$. From the experimental results, it is found that an increase in the droplet flow rate improves mist cooling heat transfer in the both case of smooth surface and surfaces of micro-fins. Micro-fins surfaces enhance the mist cooling heat transfer. Besides, the experimental results show that an increase in the droplet flow rate decrease the heat transfer efficiency of mist cooling.

• 한국항공운항학회지
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• 제14권2호
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• pp.33-38
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• 2006

Heat transfer coefficients and static pressure distributions on a gas turbine vane endwall were experimentally investigated in a 5 bladed linear cascade. The Reynolds number based on an axial chord length and the cascade exit velocity was 500,000. Both heat transfer and pressure measurements on the vane endwall were made at the two different turbulence intensity levels of 6.8% and 10.8%. Detailed heat transfer coefficient distributions on the vane endwall region were measured using a hue detection based transient liquid crystals technique. Results show various regions of high and low heat transfer coefficients on the vane endwall surface due to several types of secondary flows and vortices. Heat transfer coefficient and endwall static pressure distributions showed similar trends for both turbulence intensity, however, the averaged heat transfer coefficients for higher turbulence intensity case was higher than the lower turbulence intensity case by 15%.

• 대한기계학회논문집
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• 제19권9호
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• pp.2386-2398
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• 1995

The paper describes the results of an experimental investigation of the heat transfer rate on the endwall surface within the plane turbine cascade passage and includes the effect of the heat transfer for the two different boundary layer thicknesses and Reynolds numbers. The limiting streamlines on the endwall surface have been visualized by the oil film method in order to compare with the endwall heat transfer. The hue-capturing method using the termochromatic liquid crystals with great spatial resolution has been used to provide the local distribution of the endwall heat transfer coefficients. Because the detailed contours of the local heat transfer coefficients over the entire endwall can be obtained from the hue-capturing method, it has been possible to obtain information on the endwall heat transfer within the plane turbine cascade passage from these heat transfer contours.

• 설비공학논문집
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• 제11권5호
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• pp.647-657
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• 1999

An experimental study has been peformed to investigate the heat transfer characteristics of impinging jets with multiple orifice nozzles. Four different shapes of multiple orifice nozzle were tested to improve the heat transfer characteristics of impinging jet. Heat transfer coefficients were obtained by using transient and steady method based on the liquid crystal thermography, and both methods showed very similar results. The effects of multiple orifice nozzles on the heat transfer characteristics of impinging jets were discussed in detail. The results showed that multiple orifice nozzles improved the heat transfer characteristics of impinging jet. Especially, heat transfer coefficients around stagnation region of impinging jets were highly increased.

• 한국환경과학회지
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• 제9권5호
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• pp.389-392
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• 2000

In this study a packed tower was selected for the treatment apparatus of $NH_3$ gas produced in industry. Formerly latticework packing has been used in preventive facility of treatment of $NH_3$ gas. However recently metallic Ralu-Pack 250YC. structured packing is usually being used in petrochemical production plant. This study is for the application the packing to the $NH_3$ gas treatment in wet scrubbing process. In Air/water system hydraulic pressure drop dependent of specific liquid load and gas capacity factor was continuous and parallel from graph. The tower height can be determuined by the number of transfer unit and the height of transfer unit influenced on liquid distribution.

• 설비공학논문집
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• 제11권6호
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• pp.824-834
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• 1999

Characteristics of two-phase flow and heat transfer were numerically investigated in a submerged gas injection system when temperature of the injected gas was different from that of the liquid. The Eulerian approach was used for both the continuous and dispersed phases. The turbulence in the liquid phase was modeled using the standard $k-\varepsilon$$\varepsilon$ turbulence model. The interphase friction and heat transfer coefficient were calculated from the correlations available in the literature. The turbulent dispersion of the phases was modeled by a "dispersion Prandtl number". In the case with heat transfer where the temperature of the injected gas is higher than the mean liquid temperature, the axial and the radial velocities are lower in comparison with the case of homogeneous temperatures. The results in the present research are of interest in the design and operation of a wide variety of material and chemical processes.

• Korean Chemical Engineering Research
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• 제52권4호
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• pp.516-521
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• 2014

고점성이며 낮은 표면장력 매체로 구성된 기포탑에서 축방향 국부 열전달 계수와 총괄 열전달 계수에 대해 고찰하였다. 기체공탑유속(0.02~0.10 m/s), 액체 점도($0.1{\sim}0.3Pa{\cdot}s$) 그리고 액체 표면장력($66.1{\sim}72.9{\times}10^{-3}N/m$)이 국부 및 총괄 열전달 계수에 미치는 영향을 검토하였다. 열전달 영역은 기포탑 내부 열원과 기포탑 간의 열전달계로 구성하였다. 즉, 기포탑의 중앙에 수직 열원을 설치하여 내부 열원으로 하였다. 열전달 계수는 주어진 운전조건에서 열원에 제공되는 열량과 내부 열원과 기포탑 간의 온도차를 연속적으로 측정하여 결정하였다. 국부 열전달 계수는 기체공탑유속이 증가함에 따라 증가하였으나 기체 분산판으로 부터의 축방향 거리가 증가함에 따라, 액체의 표면장력이 증가함에 따라 감소하였다. 총괄 열전달 계수는 기체공탑유속이 증가함에 따라 증가하였으나 액상의 점도와 표면장력이 증가함에 따라서는 감소하였다. 총괄 열전달 계수는 기체공탑유속, 액상의 점도와 표면장력의 함수로 상관계수 0.91의 상관식을 얻을 수 있었으며 넛셀 수, 레이놀즈 수, 플란틀 수 그리고 웨버 수의 함수로 상관계수 0.92의 상관식으로 나타낼 수 있었다. $$h=2502U^{0.236}_{G}{\mu}^{-0.250}_{L}{\sigma}^{-0.028}_L$$ $$Nu=325Re^{0.180}Pr^{-0.067}We^{0.028}$$.

• 폴리머
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• 제24권2호
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• pp.211-219
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• 2000

액정성을 가지는 플로렌계 발광고분자에 비버정성 플로렌계 발광고분자를 첨가한 블렌드를 제조하여 에너지전달 효과와 흡광 및 발광 이방성에 대하여 고찰하였다. 비액정성 고분자를 액정성 고분자에 0.5wt% 첨가하고 360nm로 여기한 결과, 420nm에서 관찰되었던 액정성 고분자의 발광피크는 거의 사라졌으며 대신 비액정성 고분자에 의한 480nm에서의 새로운 발광피크가 관찰되었다. 블렌드 시료의 480nm 발광은 비액정성 고분자가 2.0wt% 첨가되었을때 가장 강했으며, 발광강도는 블렌딩 이전의 각 고분자보다 13배 증자하였다. 블렌드내의 분자들을 마찰 폴리이미드 기판상에서 가열-냉각시켜 배향시키면 시료의 발광 이방성과 order parameter는 각각 2.0 및 0.25를 나타내었다. 시간 상관 단광자 계수법 (TCSPC)에 의해 고찰한 결과, 마찰 폴리이미드 기판상에서의 배향에 의해 두 발광고분자간의 에너지전달에 필요한 시간은 93 ps만큼 단축되며 에너지전달 효율은 9% 증가함을 알 수 있었다.