• Nuclear Engineering and Technology
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• v.53 no.12
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• pp.3952-3965
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• 2021

In this study, volcanic ash was used as raw material to prepare waste forms with different silicon/aluminum (Si/Al) molar ratios to immobilize sodium-salt waste (SSW) containing simulated ¹³⁷Cs. Effects of Si/Al molar ratios (3:1 and 2:1) and sodium salts on sintering behavior of waste forms and immobilization mechanism of Cs⁺ were investigated. Results indicated that the main mineral phase of sintered waste-form matrixes was albite, and the formation of major phases was found to depend on Si/Al molar ratios. Si/Al molar ratio of 2 was favorable for the formation of pollucite, and the formation and crystallization of mineral phases were also decided based on physicochemical characteristics of sodium salts. Furthermore, product consistency test results indicated that the immobilization of Cs⁺ was related to Si/Al molar ratio, types of sodium salts, and glassy phase. Waste forms with Si/Al molar ratio of 2 exhibited better ability to immobilize Cs⁺, whereas the influence of sodium salts and glassy phases on the immobilization of SSW showed more complicated relationship. In waste forms with Si/Al molar ratio of 2, Cs⁺ leaching concentrations of samples containing Na₂B₄O₇·10H₂O and NaOH were low. Na₂B₄O₇·10H₂O easily transformed into liquid phase during sintering to consequently achieve low temperature liquid-phase sintering, which is beneficial to avoid the volatilization of Cs⁺ at high temperature. Results clearly reveal that waste forms with Si/Al molar ratio of 2 and containing Na₂B₄O₇·10H₂O show excellent immobilization of Cs⁺.

• Journal of the Korean Society for Nondestructive Testing
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• v.26 no.1
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• pp.18-24
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• 2006

Reactor core and internal structures of a liquid metal reactor (LMR) can not be visually examined due to an opaque liquid sodium. The under-sodium viewing technique by using an ultrasonic wave should be applied far the visual inspection of reactor internals. In this study, an ultrasonic waveguide sensor with a strip plate has been developed for an application to the under-sodium viewing technique. The Lamb wave propagation of a waveguide sensor has been analyzed and the zero-order antisymmetric $A_0$ plate wave was selected as the application mode of the sensor. The $A_0$ plate wave can be propagated in the dispersive low frequency range by using a liquid wedge clamped to the waveguide. A new technique is presented which is capable of steering the radiation beam angle of a waveguide sensor without a mechanical movement of the sensor assembly The steering function of the ultrasonic radiation beam can be achieved by a frequency tuning method of the excitation pulse in the dispersive range of the $A_0$ mode. The technique provides an opportunity to overcome the scanning limitation of a waveguide sensor. The beam steering function has been evaluated by an experimental verification. The ultrasonic C-scanning experiments are performed in water and the feasibility of the ultrasonic waveguide sensor has been verified.

• Nuclear Engineering and Technology
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• v.52 no.7
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• pp.1380-1385
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• 2020

An annular linear induction electromagnetic pump (ALIP) which has a developed pressure of 0.76 bar and a flow rate of 100 L/min is designed to analysis end effect which is main problem to use ALIP in thermohydraulic system of the prototype generation-IV sodium-cooled fast reactor (PGSFR). Because there is no moving part which is directly in contact with the liquid, such as the impeller of a mechanical pump, an ALIP is one of the best options for transporting sodium, considering the high temperature and reactivity of liquid sodium. For the analysis of an ALIP, some of the most important characteristics are the electromagnetic properties such as the magnetic field, current density, and the Lorentz force. These electromagnetic properties not only affect the performance of an ALIP, but they additionally influence the end effect. The end effect is caused by distortion to the electromagnetic field at both ends of an ALIP, influencing both the flow stability and developed pressure. The electromagnetic field distribution in an ALIP is analyzed in this study by solving Maxwell's equations and using numerical analysis.

• Korean Journal of Metals and Materials
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• v.48 no.10
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• pp.914-921
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• 2010

Studies were carried out to assess the microstructural and mechanical properties of ferriticmartensitic steel under a flowing sodium environment. HT9 (12Cr-MoVW) and Gr.92 (9Cr-MoVNbW) steel were exposed to liquid sodium at $650^{\circ}C$ containing dissolved oxygen of 20 ppm for 2333 hours and evaluations of the microstructure as well as the mechanical properties of the microhardness and nanoindentation were carried out. The result showed that both HT9 and Gr.92 exhibited macroscopic weight loss caused by general corrosion as well as localized types such as intergranular corrosion and pitting. Decarburization at the steel surface took place as the test proceeded. As the Cr content increased, dissolution and decarburization were suppressed. Assessment of the actual cladding geometry revealed that an aging process rather than decarburization governed the mechanical properties, which resulted in a decrease of the microhardness and yield stress.

• Journal of Environmental Health Sciences
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• v.18 no.2
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• pp.52-56
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• 1992

The ability of chemicals, 10% sodium hypochlorite, 28% ammonium hydroxide, 5% sodium hydroxide, 5% sodium bicarbonate, 0.1% hydrochloric acid, 5% hydrogen peroxide, and 5% acetone, to destroy aflatoxins in laboratory waste water containing 3.26 ppb of B$_{1}$ 7.64 ppb of B$_{6}$3 ppb of G$_{1}$, and 11.39 ppb of G$_{2}$ with the total of 29.11 ppb was investigated. High performance liquid chromatograph (HPLC) was used for the separation and quantitation of aflatoxins. Treatment for 2 hours by the chemicals affected the destruction of aflatoxins and the most effective chemical was 10% sodium hypochlorite (p<0.05). Sodium hypochlorite concentrations more than 1% significantly reduced aflatoxin B$_{2}$, G$_{1}$, G$_{2}$ and total aflatoxins and more than 3% reduced B$_{1}$ (p<0.05). No further significant decreases were observed above the concentration of 5% for all 4 aflatoxins. Complete destruction of aflatoxins B$_{2}$, G_{1}$, and G$_{2}$ was achieved by 5% sodium hypochlorite at 48 hours and B$_{1}$ at 72 hours.

• Bulletin of the Korean Chemical Society
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• v.2 no.3
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• pp.90-96
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• 1981

The significant structure theory of liquids has been successfully applied to the sodium ammonia solution. In applying the theory to sodium ammonia solution, we assumed there were four species in solution, i.e., sodium cation, solvated electron, triple ion, and free electron and equilibria existed between them. Based on these assumptions, we set up the model explaining the anomalous properties of sodium ammonia solution. The partition function for sodium ammonia solution is composed of the partition functions for the above four species and also for the Debye-Huckel excess free energy term. Agreements between calculated and experimental values of the thermodynamic quantities, such as molar volume, vapor pressure, partial molar enthalpy and entropy, and chemical potential as well as viscosity are quite satisfactory.

• Analytical Science and Technology
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• v.32 no.4
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• pp.147-154
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• 2019

Ampicillin and Sulbactam (2:1, w/w) are combined in formulation to provide broader antibacterial action in treatment of many infections. The development of analytical method for simultaneouly determine these two compounds was difficult because of the differences in their chemical structures and ratio in the formulation. Current published methods still have some limitations. In this study, we developed an alternative high-performance liquid chromatography (HPLC) assay method for simultaneously determination of ampicillin sodium and sulbactam sodium in powder for injection. Method validation of HPLC method was conducted to determine linearity, precision, accuracy, system suitability, robustness. The linearity of the calibration curves in the desired concentration range was good ($r^2$> 0.9994). RSDs of intra-day and inter-day precision obtained were less than 2.00 %. Accuracy was obtained with the recoveries in range of 98.42 % and 101.36 %. As a result of system suitability, RSD of both retention time and the peak area obtained were not more than 1.0 %. The values of plate number were more than 7000 and symmetric factors obtained were 0.8. As intermediate-precision and robustness of the developed assay, it could be expected to become valuable tools for revising the Korean Pharmacopoeia (KP XI).

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.1
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• pp.99-112
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• 1997

Mixing process of impinging jets of liquid oxidizer and liquid fuel is simulated by using water and sodium carbonate (Na$_{2}$CO$_{3}$) solution. The shapes of liquid sheets are visualized and flowrate distributions are measured by collecting droplets using measuring cells. Mixing charateristics are studied by using acid-base titration. Stable liquid sheets are formed and two liquid jets are well mixed for symmetric impinging jets. Similarity in flowrate distribution for various measuring heights is observed. For asymmetric impinging jets, liquid sheets become unstable as the difference in the velocities of jets increases. In some extreme cases, liquid sheets are not formed and the jets are separated. Dimensionless variables are adopted demonstrating similarly in flowrate distribution. Mixing characteristics vary significantly with experiment conditions.

• Journal of Welding and Joining
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• v.35 no.1
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• pp.79-88
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• 2017

The effect of residual metallic sodium on the solidification cracking susceptibility of type 316FR stainless steel was investigated via transverse-Varestraint tests. And a solidification brittle temperature range (BTR) of type 316FR stainless steel was 37 K. However, the BTR expanded from 37 to 67 K, as the amount of metallic sodium at the specimen surface increased from 0 to $7.99mg/cm^2$. Microstructural observation of the weld metal suggested that metallic sodium existed in the weld metal, including in the cell boundaries, during welding solidification. Thermodynamic calculations suggested that sodium expanded the temperature range of solidliquid coexistence during welding solidification of the steel weld metal. Therefore, the increased solidification cracking susceptibility (i.e., expansion of the BTR) in the residual sodium environment was attributed to enhanced segregation of sodium during the welding solidification; this segregation, in turn, resulted in an expanded temperature range of solid-liquid coexistence.

• Journal of Mechanical Science and Technology
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• v.15 no.11
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• pp.1533-1540
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• 2001

A high-temperature sodium stainless steel heat pipe was fabricated and its performance has been investigated. The working fluid was sodium and it was sealed inside a straight tube container made of stainless steel. The amount of sodium occupied approximately 20% of the total volume of the heat pipe and its weight was 65.7gram. The length of a stainless steel container is 1002mm and its outside diameter is 25.4mm. Performance tests were carried out in a room air condition under a free convective environment and the measured temperatures are presented. The start-up behavior of the heat pipe from a frozen state was investigated for various heat input values between 600W and 1205W. In steady state, axial temperature distributions of a heat pipe were measured and its heat transfer rates were estimated in the range of vapor temperature from 50$0^{\circ}C$ to 63$0^{\circ}C$. It is found that there are small temperature differences in the vapor core along the axial direction of a sodium heat pipe for the high operating temperatures. But for the range of low operating temperatures there are large temperature drops along the vapor core region of a sodium heat pipe, because a small vapor pressure drop makes a large temperature drop. The transition temperature was reached more rapidly in the cases of high heat input rate for the sodium heat pipe.