• Tribology and Lubricants
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• 제36권3호
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• pp.161-167
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• 2020

Petroleum is the most used energy source in Korea with a usage rate of 39.5% among the available 1st energy source. The price of liquid petroleum products in Korea includes a lot of tax such as transportation·environment·energy tax. Thus, illegal production and distribution of liquid petroleum is widespread because of its huge price difference, including its tax-free nature, from that of the normal product. Generally, illegal petroleum product is produced by illegally mixing liquid petroleum with other similar petroleum alternatives. In such case, it is easy to distinguish whether the product is illegal by analyzing its physical properties and typical components. However, if one the components of original petroleum product is added to illegal petroleum, distinguishing between the two petroleum products will be difficult. In this research, we inspect illegally produced gasoline, which is mixed with methyl tertiary butyl ether (MTBE) as an octane booster. This illegal gasoline shows a high octane number and oxygen content. Further, we analyze the different types of green dyes used in illegal gasoline through high performance liquid chromatography (HPLC). We conduct component analyses on the simulated sample obtained from premium gasoline and MTBE. Finally, the illegal gasoline is defined as premium gasoline with 10% MTBE. The findings of this study suggest that illegal petroleum can be identified through an analytic method of components and simulated samples.

• Tribology and Lubricants
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• 제37권6호
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• pp.232-239
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• 2021

Petroleum is the most consumed energy source in Korea with a usage rate of 38.7% among the available primary energy sources. The price of liquid petroleum products in Korea includes taxes such as transportation·environment·energy tax. Thus, illegal production and distribution of liquid petroleum is widespread because of its huge price difference from that of the normal product and its tax-free nature. Generally, the illegal petroleum product is produced by mixing liquid petroleum with other similar petroleum alternatives. The two kinds of gasoline, common gasoline and premium gasoline, are being distributed in Korea. The premium gasoline is often adulterated with cheaper common gasoline that lowers the octane number of gasoline. It is possible to distinguish them with their color difference, green and yellow for different grade gasoline. However, when small volume of common gasoline is added to premium gasoline, it is difficult to determine whether premium gasoline contained common grade or not. In this study, we inspect gasoline, which is illegally produced by mixing common gasoline to premium gasoline. When the ratio of mixing common gasoline is increased, premium gasoline shows decreasing absorbance at 600 nm and 650 nm under UV-Vis spectrometer. Moreover, the detected intensity (mV·s) of green dye in high performance liquid chromatography (HPLC) was decreased by common gasoline under 0.99 correlation value. The more the common gasoline is mixed, the more olefin and naphthene are detected by gas chromatography. In addition, trimethyl pentane as octane improver, paraffin and toluene are decreased by common gasoline mixing. The findings of this study suggests that illegal petroleum can be identified by analysis of components and simulated samples.

• 한국가스학회지
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• 제19권5호
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• pp.98-103
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• 2015

현행 액화석유가스의 안전관리 및 사업법의 시행규칙에 의거하면 액화 가스는 용기 체적의 85%까지 충전하도록 되어있다. 이에 상당하는 충전량은 $65^{\circ}C$를 기준으로 내부에 액체의 열팽창을 고려한 수치이다. 하지만 소형 또는 이동이 용이한 용기가 특정 상황에서는 용기 내부 액체의 온도가 $65^{\circ}C$ 미만을 유지한다고 단정 지을 수 없다. 열역학적 관점에서 액 팽창은 용기 재료의 강성만으로 제어하기 어려운 요소이며, 결국 파열 등의 사고를 유발 할 수 있는 잠재적인 위험 요인이 된다. 따라서 본 논문에서는 밀폐계에서 임계상태 액체 프로판의 열 팽창량을 추정하는 방법과 추정 된 결과를 제시 할 것이며, 내압 변화에 따른 용기의 체적 증가를 유도하는 구조적 요소를 실험적으로 제안할 것이다. 본 논문을 통해 제시된 결과는 향후 액화가스의 압력용기 설계에 있어 중요한 기초 자료가 될 것으로 사료된다.

• 한국안전학회지
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• 제15권2호
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• pp.59-62
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• 2000

Almost accidents related with gas have started with the leakage of LPG(Liquefied Petroleum Gas) in the open air. But experimental data of LPG leak jet are difficult to find because the safety of experiment is hard to secure and its phenomenon is not steady but transitional. This study is focused on the phenomena of injection jet of liquid butane to the open air. Simple experiment shows that only liquid butane jet in the open air is possible due to the slow vaporization because of low temperature difference between the liquid and air and low vapor pressure of liquid butane. Comparing with the water, 25~40% more liquid butane flow through the tube under the same pressure difference driving.

• 한국자동차공학회논문집
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• 제15권6호
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• pp.30-37
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• 2007

The injection and spray characteristics of top-feed type injector was investigated under liquid phase injection fueled with liquefied petroleum gas (LPG). Different pressures and temperatures of fuel injection system were tested to identify the injection characteristics after hot soaking. MIE-scattering technique was used for verification of successful liquid phase injection after hot soaking. In case of bottom-feed type injector, the injection was accomplished at every experimental condition. In case of top-feed type injector, when the pressure of LPG was over 1.2 MPa, the injection was not executed. However, under the pressure were 1.2 MPa, the liquid phase injection after hot soaking was accomplished. The engine with top-feed type fuel injection equipment was restarted successfully after hot soaking.

• Earthquakes and Structures
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• 제13권1호
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• pp.67-77
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• 2017

Oil storage tanks are vital life-line structures, suffered significant damages during past earthquakes. In this study, a numerical model for an unanchored vertical vaulted-type tank was established by ANSYS software, including the tank-liquid coupling, nonlinear uplift and slip effect between the tank bottom and foundation. Four actual earthquakes recorded at different soil sites were selected as input to study the dynamic characteristics of the tank by nonlinear time-history dynamic analysis, including the elephant-foot buckling, the liquid sloshing, the uplift and slip at the bottom. The results demonstrate that, obvious elephant-foot deformation and buckling failure occurred near the bottom of the tank wall under the seismic input of Class-I and Class-IV sites. The local buckling failure appeared at the location close to the elephant-foot because the axial compressive stress exceeded the allowable critical stress. Under the seismic input of Class-IV site, significant nonlinear uplift and slip occurred at the tank bottom. Large amplitude vertical sloshing with a long period occurred on the free surface of the liquid under the seismic wave record at Class-III site. The seismic properties of the storage tank were affected by site class and should be considered in the seismic design of large tanks. Effective measures should be taken to reduce the seismic response of storage tanks, and ensure the safety of tanks.

• 한국응용과학기술학회지
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• 제35권2호
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• pp.540-559
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• 2018

액상 바이오연료를 생산할 수 있는 하수슬러지는 자국의 에너지 안보와 지속가능한 생산이 가능하고 경제적인 원료로 여겨지고 있다. 열화학적 기술은 하수슬러지를 에너지화, 연료화할 수 있는 가장 효과적인 방법이다. 일반적으로 하수슬러지는 수분 함량이 80% 이상으로 높은 금속 함량과 14 ~ 20 MJ/kg의 발열량을 갖고 있다. 본 논문에서는 하수슬러지를 활용한 액상 바이오연료를 생산하는 열분해 반응, 전이에스테르화 반응, 초임계 반응 기술에 대해 살펴보고자 한다. 또한, 하수슬러지 유래 액상 바이오연료의 연료적 특성과 액상 바이오연료와 관련한 국내 법에 대해 검토하였다.

• 에너지공학
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• 제14권3호
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• pp.187-193
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• 2005

In this study, the performance and emission characteristics of a liquefied petroleum gas (LPG) engine converted from a diesel engine were examined by using mixer system and liquid propane injection (LPi) system. A compression ratio of 21 for the base diesel engine, was modified to 8, 8.5, 9 and 9.5. The engine performance and emissions characteristics are analyzed by investigating engine power, brake mean effective pressure (BMEP), brake specific fuel consumption (BSFC), volumetric efficienry, CO, THC and NOx. Experimental results showed that the LPi system generated higher power and lower emissions than the conventional mixer fuel supply method.

• Tribology and Lubricants
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• 제26권3호
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• pp.190-198
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• 2010

GTL(gas-to-liquid) fuel produced by the Fischer-Tropsch process using carbon monoxide(CO) and hydrogen(H2) is expected to be one of the environmental friendly fuel for alternative and blended to petrodiesel. But GTL have poor lubricity due to paraffin as main component of GTL which is not involve polar materials. In this paper, we had investigated the lubricity improvement of GTL fuels with various lubricants using HFRR(high frequency reciprocating rig).

• 에너지공학
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• 제24권4호
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• pp.33-41
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• 2015

DME는 높은 세탄가와 낮은 배출가스로 인하여 청정 디젤엔진 대체연료로 사용될 수 있고, LPG와 물리적 특성이 유사하기 때문에 혼합사용이 가능하다. 본 연구에서는 DME-LPG 혼합연료를 LPG 차량 연료에 적용한 실증평가를 수행하였다. 평가 차량으로는 LPG 연료 공급방식별로 액상연료공급방식(LPLi), 기상연료공급방식(LPGi), 분배식펌프 방식(Mixer type)의 LPG 자동차를 선택하였다. 배출가스(CO, THC, $NO_X$)와 연료소비효율에 대한 영향을 비교하기 위하여 LPG와 DME-LPG 혼합연료에 대한 성능평가를 수행하였다. 차량의 주행거리가 증가함에 따라 DME-LPG 혼합연료를 사용한 차량의 배출가스와 연료소비효율은 LPG 연료를 사용한 경우와 비교해서 동등한 수준으로 평가되었다.