• Tribology and Lubricants
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• v.36 no.3
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• pp.161-167
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• 2020

Petroleum is the most used energy source in Korea with a usage rate of 39.5% among the available 1st energy source. The price of liquid petroleum products in Korea includes a lot of tax such as transportation·environment·energy tax. Thus, illegal production and distribution of liquid petroleum is widespread because of its huge price difference, including its tax-free nature, from that of the normal product. Generally, illegal petroleum product is produced by illegally mixing liquid petroleum with other similar petroleum alternatives. In such case, it is easy to distinguish whether the product is illegal by analyzing its physical properties and typical components. However, if one the components of original petroleum product is added to illegal petroleum, distinguishing between the two petroleum products will be difficult. In this research, we inspect illegally produced gasoline, which is mixed with methyl tertiary butyl ether (MTBE) as an octane booster. This illegal gasoline shows a high octane number and oxygen content. Further, we analyze the different types of green dyes used in illegal gasoline through high performance liquid chromatography (HPLC). We conduct component analyses on the simulated sample obtained from premium gasoline and MTBE. Finally, the illegal gasoline is defined as premium gasoline with 10% MTBE. The findings of this study suggest that illegal petroleum can be identified through an analytic method of components and simulated samples.

• Tribology and Lubricants
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• v.37 no.6
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• pp.232-239
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• 2021

Petroleum is the most consumed energy source in Korea with a usage rate of 38.7% among the available primary energy sources. The price of liquid petroleum products in Korea includes taxes such as transportation·environment·energy tax. Thus, illegal production and distribution of liquid petroleum is widespread because of its huge price difference from that of the normal product and its tax-free nature. Generally, the illegal petroleum product is produced by mixing liquid petroleum with other similar petroleum alternatives. The two kinds of gasoline, common gasoline and premium gasoline, are being distributed in Korea. The premium gasoline is often adulterated with cheaper common gasoline that lowers the octane number of gasoline. It is possible to distinguish them with their color difference, green and yellow for different grade gasoline. However, when small volume of common gasoline is added to premium gasoline, it is difficult to determine whether premium gasoline contained common grade or not. In this study, we inspect gasoline, which is illegally produced by mixing common gasoline to premium gasoline. When the ratio of mixing common gasoline is increased, premium gasoline shows decreasing absorbance at 600 nm and 650 nm under UV-Vis spectrometer. Moreover, the detected intensity (mV·s) of green dye in high performance liquid chromatography (HPLC) was decreased by common gasoline under 0.99 correlation value. The more the common gasoline is mixed, the more olefin and naphthene are detected by gas chromatography. In addition, trimethyl pentane as octane improver, paraffin and toluene are decreased by common gasoline mixing. The findings of this study suggests that illegal petroleum can be identified by analysis of components and simulated samples.

• Journal of the Korean Institute of Gas
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• v.19 no.5
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• pp.98-103
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• 2015

Liquefied petroleum gas can be charged up to 85% of cylinder volume by enforcement regulations of safety control and business of liquefied petroleum gas act. The charged mass by enforcement regulations is considered by liquid expansion of internal liquefied petroleum gas at $65^{\circ}C$. But the temperature of liquid would not be suspended under $65^{\circ}C$ in a cylinder or portable vessel at certain situation. In the thermodynamics view point, the cylinder can be exposed to high pressure by liquid expansion. Consequently, it can be possible to potential risk such as physical explosion. Hence, this paper will offer a method of estimated internal pressure by liquid expansion at critical state in the closed system. Also, the structural factor which is given rise to volume increasement of cylinder is offered by experiment. This paper is expected as crucial reference for a cylinder design of liquefied petroleum gas.

• Journal of the Korean Society of Safety
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• v.15 no.2
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• pp.59-62
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• 2000

Almost accidents related with gas have started with the leakage of LPG(Liquefied Petroleum Gas) in the open air. But experimental data of LPG leak jet are difficult to find because the safety of experiment is hard to secure and its phenomenon is not steady but transitional. This study is focused on the phenomena of injection jet of liquid butane to the open air. Simple experiment shows that only liquid butane jet in the open air is possible due to the slow vaporization because of low temperature difference between the liquid and air and low vapor pressure of liquid butane. Comparing with the water, 25~40% more liquid butane flow through the tube under the same pressure difference driving.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.6
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• pp.30-37
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• 2007

The injection and spray characteristics of top-feed type injector was investigated under liquid phase injection fueled with liquefied petroleum gas (LPG). Different pressures and temperatures of fuel injection system were tested to identify the injection characteristics after hot soaking. MIE-scattering technique was used for verification of successful liquid phase injection after hot soaking. In case of bottom-feed type injector, the injection was accomplished at every experimental condition. In case of top-feed type injector, when the pressure of LPG was over 1.2 MPa, the injection was not executed. However, under the pressure were 1.2 MPa, the liquid phase injection after hot soaking was accomplished. The engine with top-feed type fuel injection equipment was restarted successfully after hot soaking.

• Earthquakes and Structures
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• v.13 no.1
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• pp.67-77
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• 2017

Oil storage tanks are vital life-line structures, suffered significant damages during past earthquakes. In this study, a numerical model for an unanchored vertical vaulted-type tank was established by ANSYS software, including the tank-liquid coupling, nonlinear uplift and slip effect between the tank bottom and foundation. Four actual earthquakes recorded at different soil sites were selected as input to study the dynamic characteristics of the tank by nonlinear time-history dynamic analysis, including the elephant-foot buckling, the liquid sloshing, the uplift and slip at the bottom. The results demonstrate that, obvious elephant-foot deformation and buckling failure occurred near the bottom of the tank wall under the seismic input of Class-I and Class-IV sites. The local buckling failure appeared at the location close to the elephant-foot because the axial compressive stress exceeded the allowable critical stress. Under the seismic input of Class-IV site, significant nonlinear uplift and slip occurred at the tank bottom. Large amplitude vertical sloshing with a long period occurred on the free surface of the liquid under the seismic wave record at Class-III site. The seismic properties of the storage tank were affected by site class and should be considered in the seismic design of large tanks. Effective measures should be taken to reduce the seismic response of storage tanks, and ensure the safety of tanks.

• Journal of the Korean Applied Science and Technology
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• v.35 no.2
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• pp.540-559
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• 2018

The utilization of sewage sludge for liquid biofuel production is considered as a approach for achieving better energy security, sustainable productivity and economical raw material. Thermochemical technologies of sewage sludge into energy and fuel has been considered as one of the most effective process. Generally, sewage sludge contains more than 80% of moisture, has high metal contents and 14 ~ 20 MJ/kg of calorific value. This paper reviews the technologies of converting sewage sludge to liquid biofuel via three main thermochemical conversion processes namely pyrolysis, transesterification and supercritical. The fuel properties of liquid fuels produced by different technologies from sewage sludge and definition in relevant laws for liquid biofuels in Korea are also discussed.

• Journal of Energy Engineering
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• v.14 no.3 s.43
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• pp.187-193
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• 2005

In this study, the performance and emission characteristics of a liquefied petroleum gas (LPG) engine converted from a diesel engine were examined by using mixer system and liquid propane injection (LPi) system. A compression ratio of 21 for the base diesel engine, was modified to 8, 8.5, 9 and 9.5. The engine performance and emissions characteristics are analyzed by investigating engine power, brake mean effective pressure (BMEP), brake specific fuel consumption (BSFC), volumetric efficienry, CO, THC and NOx. Experimental results showed that the LPi system generated higher power and lower emissions than the conventional mixer fuel supply method.

• Tribology and Lubricants
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• v.26 no.3
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• pp.190-198
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• 2010

GTL(gas-to-liquid) fuel produced by the Fischer-Tropsch process using carbon monoxide(CO) and hydrogen(H2) is expected to be one of the environmental friendly fuel for alternative and blended to petrodiesel. But GTL have poor lubricity due to paraffin as main component of GTL which is not involve polar materials. In this paper, we had investigated the lubricity improvement of GTL fuels with various lubricants using HFRR(high frequency reciprocating rig).

• Journal of Energy Engineering
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• v.24 no.4
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• pp.33-41
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• 2015

Dimethyl ether (DME) can be used as a clean diesel alternative fuel due to the high cetane number and low emission, it can also be applied to automotive fuel as a blended liquefied petroleum gas (LPG) because physical properties are similar to those of LPG. In this study, feasibility test of LPG vehicle using blended DME-LPG fuel was investigated. Three types of fuel supply such as LPLi (Liquid phase LPG injection), LPGi (Liquid phase gas injection) and mixer type were selected to consider the LPG fuel-injection system. The performance characteristics of LPG vehicle were examined by using LPG and blended DME-LPG fuel in order to compare the exhaust emissions (CO, THC, $NO_X$) and fuel economy. The emissions and fuel economy of DME-LPG blend fuel were comparable to those of LPG with increasing driving distance.