• Title/Summary/Keyword: Liquid hold up

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Modeling of Liquid Hold-up in Fixed-bed Reactor for Fischer-Tropsch Synthesis (고정층 Fischer-Tropsch 반응기의 액상 왁스 정체 현상 모델링)

  • Park, Chansaem;Jung, Ikhwan;Park, Seongho;Na, Jonggeol;Kshetrimayum, Krishnadash;Han, Chonghun;Lee, Jong Yeol;Jung, Jongtae
    • Journal of the Korean Institute of Gas
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    • v.18 no.4
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    • pp.63-67
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    • 2014
  • Fischer-Tropsch synthesis mainly produces a wax which is a viscous liquid for long carbon chain. When a catalytic fixed-bed reactor is used for Fischer-Tropsch synthesis, the wax generated on a catalyst surface can keep adsorbing on the catalyst surface. This liquid hold-up causes significant pressure drop and clogging problems through the reactor. Thus, the model for liquid hold-up is required to design the size of reactor and catalyst particles. In this study, the liquid hold-up model considering structural and operational conditions was proposed based on empirical equations for convective mass transfer between the syngas flow and the wax-adsorbed catalyst. The developed model was validated by comparing with the experimental data from Knochen's work (2010). The influence of reactor length and coross section on the wax hold-up in reactor were analyzed and the optimal reactor size were proposed.

Dynamic Behavior of an Internal Loop Reactor during Scale-up (내부순환반응기의 Scale-up에 따른 동력학적 특성의 변화)

  • 최윤찬;박영식
    • Journal of Environmental Science International
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    • v.6 no.1
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    • pp.25-31
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    • 1997
  • The variations of gas hold-up, overall volumetric oxygen mass transfer coefficients and liquid circulation velocity in an internal loop reactor were investigated to manifest scale-up effect. The relationship between superficial gas velocity and gas hold-up were found as Ugr = 0.045 $\varepsilon$r in the pilot-scale and Ugr = 0.056 $\varepsilon$r in the bench-scale reactor. The overall volumetric oxygen mass tractsfer coefficient, KLa was slightly increased in the pilot-scale than in the bench-scale reactor. Flow regime was changed from the bubble flow to the churn-turbulent flow when the superficial gas velocity reached to 3.5 - 4 cm/sec in the pilot-scale.

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Numerical Simulation of the Liquid Flow in the Lower Part of the Blast Furnace - A Cold Flow Case (고로하부 액체유동에 대한 수치해석 사례 - 냉간유동)

  • Jin, Hong-Jong;Choi, Sang-Min;Jung, Jin-Kyung
    • Journal of the Korean Society of Combustion
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    • v.13 no.2
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    • pp.33-41
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    • 2008
  • The high permeability of the gas in the molten iron of the dripping zone of the blast furnace is a major factor in achieving the stable operation of a furnace with high productivity. Basic studies of the liquid flow behavior in a packed bed are necessary to grasp the effect of various operational changes on conditions in the dropping zone. Molten iron and slag together playa critical role in the lower zone, transporting mass and energy, while impairing and redistributing the gas flow. In turn, molten iron and slag undergo physical and chemical changes, and are redistributed radially as they descend to the hearth. In this research, mathematical formulations are derived for the gas and the liquid. The solid phase is fixed with constant porosity. The information for the molten iron and slag includes the hold-up, velocity, pressure, and information related to the areas of interaction between the gas and the liquid, and the solid and the liquid. Predictable results include the velocity, pressure and temperature distribution. Additional parameters include the packed particle size and the air blast rate.

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A Study on the Mathematical Interpretation o Hydraulic Behaviour in Packing Tower (충전탑에서 수력학적 거동의 수학적 해석 연구)

  • 김석택
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.1
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    • pp.51-56
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    • 2001
  • This study was carried out to interpret mathematically hydraulic behaviour in packing tower which packed 50 mm plastic Hiflow-ring with a dimension of 300 mm wide and 1,400 mm high. In view of energy saving, the recent packing. 50 mm plastic Higlow-ring was superior to conventional packings because of low pressure drop in high loads. As relative error between numerically predicted and experimentally obtained values was less then 6% in the loading and flooding point, it found that therir results appeared to be adequate. Comparison of hose two values in both dry and wet packing conditions. relative errors amount to 3.96 and 5.6%, respectively. In order to evaluate the operating characteristics of packing, the type, size, and material for packings must be estimated in various system and loads. This study is able to calculated pressure drop, hold-up, gas and liquid loads using mathematical interpretation. For these calculation, the specific constants of each packings must be calculated first all. The method of mathematical interpretation in this study turned out to be superior to the existing methods because of reduced errors at loading and flooding point.

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A Study on Hydraulic Behavior and Mass Transfer by Absorption in Packing Tower (충전탑에서 흡수에 따른 물질전달과 수력학적 거동에 관한 연구)

  • 김석택
    • Journal of Environmental Science International
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    • v.9 no.5
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    • pp.393-396
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    • 2000
  • Packing tower has been used in the chemical industry and the protection of environment for a long time. In the view of environmental protection purification of exhaust gas can be performance effective by gas absorption in counter-current packing tower. In this study characteristics of hydraulic and mass transfer were investigated in D. $0.3m {\times} H. 1.4m$ packing tower with 50mn plastic Hiflow-ring. This study was carried out "Test systems were experimented in conditions of Air, $Air/H_2O. NH_3-Air/H_2O, NH_3-Air/H_2O-H_2SO_4$ and $SO_2-Air/H_2O-NaOH$ under steady state" The extent of test included dry and wetting pressure drop physical law separation efficiency and hold-up as function of gas and liquid load.quid load.

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A Study on Process Design of Hot Oil Flushing System Using Oil-Nitrogen Gas Mixing Fluid (오일-질소가스 혼합유체를 이용한 고온 오일플러싱 시스템 공정설계에 관한 연구)

  • Lee, Yoon-Ho;Choi, Bu-Hong
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.5
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    • pp.541-548
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    • 2017
  • A theoretical study on gas-liquid two-phase flow flushing systemnitrogen gas to the oil used for existing flushing equipment was conducted on the basis of ISO code so as to improve performance of existing high-temperature oil flushing equipment used in ocean plant facility drying field. For study, we analyzed process simulation results mixed fluid mixing ratio, temperature, Reynolds number and liquid hold up affectcleaning performance after designing oil-nitrogen gas mixture flushing system process. As a result, as the volume flow rate of mixed fluid increases with the tube diameter the volume fraction of the gas phase constant, the liquid fraction difference value at the inlet and outlet of horizontal hydraulic piping increases. It was found that the phase distribution between oil and nitrogen gas bubbles varies depending on the position the pipe lengthdirection. This change in phase distribution is expected to have a significant impact on the clean performance of an oil-nitrogen gas mixture flushing system.

Residence Time Distributions of Liquid pbase Flow and Mass Transfers in the Trickle Bed Reactor (점적상 반응기에서 액상흐름의 체류시간 분포 및 물질전달)

  • Kim, Ki-Chang
    • Journal of Industrial Technology
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    • v.6
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    • pp.19-31
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    • 1986
  • The residence time distribution of liquid flow in a 4.0cm diameter column packed with porous $Al_2O_3$ spheres of 0.37cm diameter were measured with pulse injections of a tracer under cocurrent trickling flow conditions. The mean residence time of liquid flow and liquid hold-up calculated by the transient curve of tracer were unaffected by gas flow rates under experimental ranges of liquid flow rates from 2.4 to $4.5(kg/m^2\;sec)$ and gas flow rates from 0 to $0.13(kg/m^2\;sec)$. The axial dispersion coefficient of liquid stream and apparent diffusivity of tracer in a micropore of solid particle were estimated from the response curve of tracer. The calculated Peclet No. were increased in ranges of 68-to 82 with a increasing of liquid mass velocity, and the external effective contacting efficiency between liquid and solid which can be expressed. by $(D_i)_{app}/D_i$ varied in ranges of 0.54 to 0.68 depending on the liquid flow rates. The gas to liquid(water) volumetric mass transfer coefficient were determined from desorption experiments with oxygen at $25^{\circ}C$ and 1 atm. The measured mass transfer coefficients were increased with liquid flow rates and the effect of gas flow rates on the mass transfer coefficient was insignificant.

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A Study on the Hydraulic Characteristics of Rashig Super-Ring Random Packing in a Counter-Current Packed Tower (역류식 충전탑에서 Raschig Super-ring Random Packing의 수력학적 특성에 대한 연구)

  • Kang, Sung Jin;Lim, Dong-Ha
    • Clean Technology
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    • v.26 no.2
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    • pp.102-108
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    • 2020
  • In recent years, packed column has been widely used in separation processes, such as absorption, desorption, distillation, and extraction, in the petrochemical, fine chemistry, and environmental industries. Packed column is used as a contacting facility for gas-liquid and liquid-liquid systems filled with random packed materials in the column. Packed column has various advantages such as low pressure drop, economical efficiency, thermally sensitive liquids, easy repairing restoration, and noxious gas treatment. The performance of a packed column is highly dependent on the maintenance of good gas and liquid distribution throughout a packed bed; thus, this is an important consideration in a design of packed column. In this study, hydraulic pressure drop, hold-up as a function of liquid load, and mass transfer in the air, air/water, and air-NH3/water systems were studied to find the geometrical characteristic for raschig super-ring experiment dry pressure drop. Based on the results, design factors and operating conditions to handle noxious gases were obtained. The dry pressure drop of the random packing raschig super-ring was linearly increased as a function of gas capacity factor with various liquid loads in the Air/Water system. This result is lower than that of 35 mm Pall-ring, which is most commonly used in the industrial field. Also, it can be found that the hydraulic pressure drop of raschig super-ring is consistently increased by gas capacity factor with various liquid loads. When gas capacity factor with various liquid loads is increased from 1.855 to 2.323 kg-1/2 m-1/2 S-1, hydraulic pressure drop increases around 17%. Finally, the liquid hold-up related to packing volume, which is a parameter of specific liquid load depending on gas capacity factor, shows consistent increase by around 3.84 kg-1/2 m-1/2 S-1 of the gas capacity factor. However, liquid hold-up significantly increases above it.

Dynamic Characteristics of External loop Air-Lift Reactor (외부 순환 공기리프트 반응기의 동특성)

  • 강귀현;김춘영정봉우
    • KSBB Journal
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    • v.7 no.1
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    • pp.59-65
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    • 1992
  • Hydrodynamics and mixing characteristics such as circulation time, mixing time, circulation velocity and axial dispersion coefficient were investigated using highly viscous pseudoplastic solutions of carboxymethyl cellulose(CMC) in an external circulation loop air-lift reactor with 13$\ell$ working volume. The superficial gas velocity was changed from 1.9 to 6.2cm/s and CMC concentration from 0 to 1.0wt%. The theoretical model based on the pressure balance is developed mathematically to predict liquid circulation velocity. Gas hold-up, circulation velocity and axial dispersion coefficient of liquid phase increased with increasing gas velocity and decreased slightly with increasing liquid viscosity. Mixing time and circulation time decreased with increasing gas velocity and increased with increasing liquid viscosity. Experimental data on liquid circulation velocity were in good agreement with the predicted values.

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EXPERIMENTAL AND ANALYTICAL STUDIES ON THE INSTABILITY IN THE LZCS FOR CANDU REACTORS

  • Ji, Joon-Suk;Lee, Kwang-Ho;Yun, Bum-Su;Cha, Jung-Hun;Kim, Sang-Nyung
    • Nuclear Engineering and Technology
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    • v.40 no.7
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    • pp.561-570
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    • 2008
  • When reactivity insertion such as refueling occurs in CANDU reactors, the power and the water levels are tilted in the upper outer zone of the LZCS (Liquid Zone Control System) and fluctuate unstably for a certain period of time (1-5 days). The instability described above is observed in most CANDU reactors in service around the world, but its root cause is unidentified and no solutions to this problem have been established. Therefore, this study attempted to prove experimentally and analytically that the root cause lies in the hold-up of light water on the top of the TSP (Tube Support Plate) due to the mismatch between net volumetric flow rate of light water and helium crossing the narrowed porous TSP installed within the LZCS compartment. Our method was to perform a hydrodynamic simulation of in/outflow of light water and helium. Two solutions for the aforementioned instability of LZCS are suggested. One is to regulate the compartment for both inflowing helium gas and outflowing light water; the other is to enlarge the flow paths of helium and light water within TSP. The former may be applicable to nuclear reactors in service and the latter to those planned for construction.