• Title/Summary/Keyword: Liquid glass

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Supercooled Liquid, Glass and Glass Transition (과냉각 액체, 유리 그리고 유리 전이)

  • Kim, Hack-Jin
    • Journal of the Korean Chemical Society
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    • v.53 no.2
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    • pp.99-110
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    • 2009
  • Characteristics of supercooled liquid and glass, which are the states involved in glass transition, are reviewed. These states are non-equilibrium states, therefore, the glass transition is different from the usual phase transitions. Theories of glass transition and related experimental methods are briefly summarized.

Dielectric Properties of Liquid Crystalline Polymer (고분자액정의 유전특성)

  • Kang, Dae-Ha;Lee, Jae-Hoon;Park, Sang-Ho;Choi, Phil-Soo
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1266-1267
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    • 2008
  • Liquid crystalline polymer BB-3(1-methyl) takes two kinds of glass phases which are liquid crystalline glass and liquid glass below the glass temperature. This study is aimed to analyze the phase transitions of those samples with variation of temperature. For the analyzing temperature dispersion of dielectric constants was measured and the results were analyzed.

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A STUDY ON BONDING STRENGTH OF DENTAL AMALGAM TO GLASS IONOMER CEMENT FOLLOWING SURFACE TREATMENT (글라스아이오노머 시멘트 표면 처리에 따른 치과용 아말감의 전단 결합 강도에 관한 연구)

  • Shin, Young-Joo;Choi, Ho-Young
    • Restorative Dentistry and Endodontics
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    • v.19 no.1
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    • pp.217-230
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    • 1994
  • The purpose of this study was to assess the 24-hour shear bond strength of amalgam to glass ionomer cement, using five different intermediaries. The intermediaries used in this study were Scotchbond 2 (light curing dentin adhesive), Panavia (resin cement), liquid' of glass ionomer cement (chemical curing & light curing), and uncured mixture of light curing glass ionomer cement. This study was operated with 48 specimens devided into 6 groups. The experimental groups are as follows: Group 1 : Bonded Amalgam to chemical curing glass ionomer cement with liquid of chemical curing glass ionomer. Group 2 : Bonded Amalgam to light curing glass ionomer cement with liquid of chemical curing glass ionomer. Group 3: Bonded Amalgam to light curing glass ionomer cement with resin cement. Group 4: Bonded Amalgam to light curing glass ionomer cement with light curing dentin adhesive. Group 5: Bonded Amdlgam to light curing glass ionomer cement with liquid of light curing glass ionomer. Group 6: Bonded Amalgam to light curing glass ionomer cement with uncured mixture of light curing glass ionomer cement. 30 minutes after amalgam condensation, all specimens were stored for 24 hours in water at $37^{\circ}C$ and tested with Instron (1122). The following results obtained: 1. The shear bond strength of group 6 was higher than those of the other groups (46.7 kgf/$cm^2$, p<0.05). 2. The shear bond strength of resin cement intermediary group was lower than that of the group using uncured mixture of light curing glass ionomer cement. 3. The results of group 1 and group 2 were different, even though the inter-me diaries used were same. 4. Intermediary of Group 5 did not show complete set in Scanning Electromicroscopic examination. 5. Light-curing dentin adhesive did not show any bonding ability to amalgam.

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Characterization of the Oxide Layer Formed on the Cu-Zr Based Metallic Glass during Continuous Heating

  • Lim, Ka-Ram;Kim, Won-Tae;Kim, Do-Hyang
    • Applied Microscopy
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    • v.42 no.3
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    • pp.174-178
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    • 2012
  • In the present study, the oxidation behavior of $Cu_{50}Zr_{50}$ and $Cu_{46}Zr_{46}Al_8$ metallic glasses has been investigated using transmission electron microscopy with a particular attention on the oxidation behavior in the supercooled liquid state. Identification of the oxidation product after continuous heating treatment shows that in $Cu_{50}Zr_{50}$ metallic glass, $ZrO_2$ with the monoclinic structure forms on the supercooled liquid as well as on the crystallized matrix. On the contrary, in $Cu_{46}Zr_{46}Al_8$ metallic glass, $ZrO_2$ with the tetragonal structure forms on the supercooled liquid, but that with the monoclinic structure forms on the crystallized matrix. The result indicates that the $Cu_{50}Zr_{50}$ metallic glass exhibits far better oxidation resistance in the supercooled liquid state than the $Cu_{46}Zr_{46}Al_8$ metallic glass.

Laser bonding using liquid glass (유리액를 이용한 레이저 선택 접합)

  • Kim, Joo-Han;Lee, Jae-Hoon;Kim, Hyang-Tae
    • Laser Solutions
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    • v.11 no.3
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    • pp.1-4
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    • 2008
  • A selective laser micro bonding process using liquid glass (methylsilsesquioxane) was developed and the results are analysed. The liquid glass can be solidified with Nd:YAG laser irradiation and it can be applied for joining two glass substrates. A bonding thickness of a few micrometers can be achieved. The appropriate laser power density (or this process is around 40-60 $kW/cm^2$ and its bonding force is 1000-1200 $gf/mm^2$. This process can be applied for bonding micro devices such as micro bio-sensors or display products. Its advantages and limitations are presented and discussed.

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Transverse permeability measurement of a circular braided preform in liquid composite molding

  • Chae, Hee-Sook;Song, Young-Seok;Youn, Jae-Ryoun
    • Korea-Australia Rheology Journal
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    • v.19 no.1
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    • pp.17-25
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    • 2007
  • In liquid composite molding (LCM), composites are produced by impregnation of a dry preform with liquid resin. The resin flow through the preform is usually described by Darcy's law and the permeability tensor must be obtained for filling analysis. While the resin flow in the thickness direction can be neglected for thin parts, the resin flow in the transverse direction is important for thicker parts. However, the transverse permeability of the preform has not been investigated frequently. In this study, the transverse permeability was measured experimentally for five different fiber preforms. In order to verify the experimental results, the measured transverse permeability was compared with numerical results. Five different fiber mats were used in this study: glass fiber woven fabric, aramid fiber woven fabric, glass fiber random mat, glass fiber braided preform, and glass/aramid hybrid braided preform. The anisotropic braided preforms were manufactured by using a three dimensional braiding machine. The pressure was measured at the inlet and outlet positions with pressure transducers.

Development of glass bulb for sprinkler head system (스프링클러용 유리발브의 개발)

  • Kim, Byung-Cheol;Joung, Hoon-Choul;Seo, Yo-Won;Myung, Young-Sup
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2008.04a
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    • pp.144-147
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    • 2008
  • A glass bulb is the most reliable and simplest device for a fire sprinkler head system. We had developed an accurate glass bulb. The glass bulb is composed with a glass ampoule, liquid filled within the ampoule and an air bubble in the liquid. The first step of the development was to establish a stable mass production system for uniform glass ampoule. The second step is to optimize the composition of the liquid and the size of the bubble. It was also a difficult problem to devise manufacturing process to form uniform bubble size. The final step for the development is to control the mechanics for glass breaking by surface treatment for the glass bulb.

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Electro-Optical Performances of Flexible Liquid Crystal Display on Twisted Nematic Mode according to Cell Gap (셀갭 변화에 따른 Flexible 기판 TN-LCD의 전기광학특성)

  • Kang, Hee-Jin;Hwang, Jeoung-Yeon;Lee, Whee-Won;Kim, Jong-Hwan;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.289-290
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    • 2005
  • We have investigated the electro-optical (EO) performances of the flexible liquid crystal display (LCD) on twisted nematic (TN) mode according to variation of cell gap in comparison with glass LCD. There were four kinds of cells which were having cell gaps of 3$\mu$m, 4$\mu$m and 5$\mu$m, especially the lowest 2$\mu$m on flexible and glass substrates separately. The EO performances of the flexible cells on the rubbed potyimide (PI) were almost the same those of glass cells. The response time of flexible cells was shorter than that of glass cells but the alignment of liquid crystal (LC) of flexible cells was weaker than that of glass cells. The residual DC of flexible cells was on the increase like that of glass cells in compliance with lowering cell gap.

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Effect of Alloying Elements on the Glass Forming Ability of Zr-Ti-Cu-Ni-X Alloys (Zr-Ti-Cu-Ni-X계 합금의 첨가원소에 따른 비정질 형성능)

  • Choi, Chul-Jin
    • Journal of Korea Foundry Society
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    • v.21 no.5
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    • pp.286-289
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    • 2001
  • The glass formation behavior was investigated in the melt spun Zr-Ti-Cu-Ni-X (X=B, P and Si) ribbons. The magnitude of supercooled liquid region of Zr-Ti-Cu-Ni alloy increased with an addition of alloying element. The glass transition temperature and the crystallization temperature increased and the magnitude of supercooled liquid region decreased with increasing the content of alloying elements. The largest supercooled liquid region was observed in the Si containing alloy. This is believed to be due to the dense atom packing with the optimum atomic size ratio of constituent elements.

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Fabrication of Metallic Glass/metallic Glass Composites by Spark Plasma Sintering (방전플라즈마 소결법에 의한 비정질/비정질 복합재의 제조)

  • Lee, Jin-Kyu
    • Journal of Powder Materials
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    • v.14 no.6
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    • pp.405-409
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    • 2007
  • The Cu-based bulk metallic glass (BMG) composites containing Zr-based metallic glass phase have been consolidated by spark plasma sintering using the mixture of Cu-based and Zr-based metallic glass powders in their overlapped supercooled liquid region. The Zr-based metallic glass phases are well distributed homogeneously in the Cu-based metallic glass matrix after consolidation process. The successful consolidation of BMG composites with dual amorphous phases was corresponding to the sound viscous flow of the two kinds of metallic glass powders in their overlapped supercooled liquid region.