• 제목/요약/키워드: Liquid forming

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Preparation of Porous Nanostructures Controlled by Electrospray

  • Nguyen, Dung The;Nah, In Wook;Kim, Kyo-Seon
    • Korean Chemical Engineering Research
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    • v.53 no.5
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    • pp.627-631
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    • 2015
  • Various solid structures were prepared by electrospray technique. In this process, liquid flows out from a capillary nozzle under a high electrical potential and is subjected to an electric field, which causes elongation of the meniscus to form a jet. In our study, by controlling the amount of polyvinyl pyrrolydone in precursor solution, the jet either disrupted into droplets for the formation of spherical particles or was stretched in the electric field for the formation of fibers. During the electrospray process, the ethanol solvent was evaporated and induced the solidification of precursors, forming solid particles. The evaporation of ethanol solvent also enhanced the mass transport of solutes from the inner core to the solid shell, which facilitated fabrication of porous and hollow structure. The network structures were also prepared by heating the collector.

Chitosan이 사과 겹무늬썩음병균 Botryosphaeria dothidea의 생육에 미치는 영향

  • 이승지;엄재열;이용현
    • Microbiology and Biotechnology Letters
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    • v.24 no.3
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    • pp.261-267
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    • 1996
  • To examine the potential utilization of chitosan, the biodegradable natural polymer, as a control agent of apple white rot caused by Botryosphaeria dothidea in a new control measure by coating it on the diseased branches, the various antifungal activities of chitosan was investigated. Chitosan showed significant inhibitory effect on the mycelial growth of B. dothidea, along with the morphological changes including hyphal swelling and ultrastructural changes on solid PDA medium. In liquid PD broth medium, the chitosan showed more significant effect on the growth of B. dothidea also forming cell clusters indicating affection on the hyphal extension. The growth of B. dothidea was inhibited more than 90% at the concentration of 1.0 mg/ml. Chitosan also detained the spore germination and induced the morphological change of germ tubes. Glucosamine, monomer of chitosan, did not affect on the growth of B. dothidea indicating the antifungal activity was caused by chitosan polymer.

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Preparation and Electrical Properties of PTCR Ceramic Materials (정저항요업체의 제조와 전기적 성질)

  • 정형진;윤상옥
    • Journal of the Korean Ceramic Society
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    • v.22 no.2
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    • pp.11-16
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    • 1985
  • The semiconducting ceramics having positive temperature coefficient of resistivity in he family of 0.25mol% $Sb_2O_3$ doped barium titanates were prepared with AST ($4Al_2O_3$.$9SiO_2$.$3TiO_2$) and $MnO_2$ as additives and these electrical properties were investigated. The PTCR characteristic in these ceramic materials was improved by the addition of AST and $MnO_2$ because the addition of AST decreased the room temperature resistivity and controlled grin size due to the formation of a liquid phase during sintering and the addition of $MnO_2$ improved by forming acceptor level on the intergranular layer. On dependence on the switching time as switching temperature was increased the initial power and switching time increased.

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Pulsed laser ablation of hydroxyapatite in ethanol

  • Lee, Jung-Il;Ryu, Jeong Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.5
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    • pp.219-223
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    • 2014
  • Pulsed laser ablation in liquid medium was successfully employed to synthesize hydroxyapatite colloidal nanoparticles. The crystalline phase, particle morphology, size distribution and microstructure of the hydroxyapatite nanoparticles were investigated in detail. The obtained hydroxyapatite nanoparticles had spherical shape with sizes ranging from 5 to 20 nm. The laser ablation and the nanoparticle forming process were discussed with explosive ejection mechanism by investigating change of surface morphology on target. The analytical results of XPS, FT-IR and Raman spectroscopy confirms that the stoichiometry and bonding properties of the hydroxyapatite nanoparticles are in good agreement with reported bulk hydroxyapatite materials.

A study on electrical and mechanical properties and press formability of a Cu/Ag composite sheet (Cu/Ag 복합판재의 전기/기계적 성질 및 프레스 성형성에 관한 연구)

  • Shin, Je-Sik
    • Design & Manufacturing
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    • v.6 no.1
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    • pp.95-100
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    • 2012
  • In this study, a novel Cu composite sheet with embedded high electric conduction path was developed as another alternative for the interconnect materials possessing high electrical conductivity as well as high strength. The Cu composite sheet was fabricated by forming Ag conduction paths not within the interior but on the surface of a high strength Cu substrate by damascene electroplating process. As a result, the electrical conductivity increased by 40% thanks to mesh type Ag conduction paths, while the ultimate tensile strength decreased by 20%. The interfacial fracture resistance of Cu composite sheet prepared by damascene electroplating increased by above 50 times compared to Cu composite sheet by conventional electroplating. For feasibility test for practical application, a leadframe for LED module was manufactured by a progressive blanking and piercing processes, and the blanked surface profile was evaluated as a function of the volume fraction of Ag conduction paths. As Ag conduction path became finer, pressing formability improved.

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Longitudinal Flow Path of Safranine in Populus tomentiglandulosa T. Lee

  • Choi, In-Sik;Ahmed, Sheikh Ali;Chun, Su-Kyoung
    • Journal of the Korea Furniture Society
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    • v.18 no.2
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    • pp.161-165
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    • 2007
  • An experiment was conducted to observe the safranine flow depth in longitudinal direction of Populus tomentiglandulosa. Longitudinal flow of safranine was considered from bottom to top end of the tree. Vessel and wood fiber were considered for the measurement of safranine flow depth. It was found that sapwood conducted safranine 12.25% higher in longitudinal direction compared with heartwood. Vessel was found the main avenue for safranine flow. Vessel conducted safranine 41.94% higher than that of wood fiber. Safranine penetrated through vessel and fiber forming a curved meniscus.

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A Numerical Study on the Solidification of Binary Mixture with Double-diffusive Convection in the Liquid (복합대류가 이원용액의 응고과정에 미치는 영향에 관한 수치적 연구)

  • Yoo, J.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.5 no.2
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    • pp.111-121
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    • 1993
  • Double-diffusive convection during solidification process of the binary mixture was studied numerically. Enthalpy method and finite element method were implemented in the analysis. Calculation carried out for $R{\alpha}_T=10^3-10^4$ and $R{\alpha}_T=0-10^5$. The results show that the variation of thermal Rayleigh number changes the fields of velocity, temperature and concentration, but the variation of solutal Rayleigh number gives little effects on those. In conclusion, concentration gradient can be negligible compared with temperature gradient in macroscopic point of view, although concentration gradient plays a role in forming dendrite.

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Forming of Compressor Piston Part of Metal Matrix Composites by Thixoforming Process (Thixoforming을 응용한 금속복합재료의 콤푸레서용 피스톤 제품의 성형)

  • 이동건;강충길
    • Transactions of Materials Processing
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    • v.10 no.3
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    • pp.223-234
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    • 2001
  • The characteristics of thixoforming process can decrease liquid segregation because of the improvement in fluidity in a globular microstructure state and utilizes flow without an air entrapment. Therefore, in order to obtain the sound parts of metal matrix composites by using thixoforming process which has co-existing solidus-liquidus phase, it is very important to design a die shape property and to obtain the fabrication conditions which affect the unifomity of the solid fraction on unfilling state and various defects throughout the fabricated parts. The die designs and fabrication conditions to obtain the good piston part are proposed for thixoforging process of metal matrix composites. When reheated metal matrix composites billets were transferred to the closed die gate, thixoforging were carried out under the various pressure(60, 80, 100MPa) with controled forging speed. The mechanical properties such as hardness and tensile strength for thixoforged parts have been investigated after T6 heat treatment.

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Effect of Glass Additions on the Adhesion and Electrical Conductivity of Photoimageable Silver Paste

  • Lee, Eun-Heay;Heo, Yu-Jin;Kim, Hyo-Tae;Kim, Jong-Hee
    • Journal of the Microelectronics and Packaging Society
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    • v.18 no.4
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    • pp.63-70
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    • 2011
  • Anorthite forming glass frits in amounts up to 25 vol% of the silver powder were added to improve the adhesion between the conductor pattern formed by thick film photoimageable process and the low temperature co-fired ceramics (LTCC) substrate. The sheet resistance of the conductor pattern was raised from 0.13 ${\Omega}/{\square}$ to 2.25 ${\Omega}/{\square}$ as the volume percentage of glass frit increased up to 25 vol%. The adhesion strength was improved with this glass frit increase, but it decreased when the glass content exceeded 20 vol% which are possibly attributed to the liquid pool effect and the reduced fracture toughness in the interface between conductor and LTCC layer. The shrinkage of the width of the conductor pattern decreased with the addition of glass contents.

Study for Local Glass Transition of Bulk Metallic Glasses using Atomic Strain (원자변형률을 이용한 비정질 금속의 천이온도에 관한 연구)

  • Park, Jun-Young
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.10 no.5
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    • pp.104-109
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    • 2011
  • Bulk metallic glasses (BMG) have been greatly improved by the advance of synthesis process during last three decades. It was also found that the Glass Forming Ability (GFA) strongly depends on the glass transition temperature. When the temperature approaches to a critical value, the crystals nucleation from the supercooled liquid can be suppressed so that bulk glass formation possible. Egami and others found that the local glass transition temperature depends on the volumetric strain of each atom and suggested the critical transition temperature. In this paper, we explore the strain dependency of local glass transition temperature using the atomic strain defined by the deformation tensor for the Voronoi polyhedra.