• Title/Summary/Keyword: Liquid blocking

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Sputtered ZTO as a blocking layer at conducting glass and $TiO_2$ Interfaces in Dye-Sensitized Solar Cells (GZO/ZTO 투명전극을 이용한 DSSC의 광전 변환 효율 특성)

  • Park, Jaeho;Lee, Kyungju;Song, Sangwoo;Jo, Seulki;Moon, Byungmoo
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.53.2-53.2
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    • 2011
  • Dye-sensitized solar cells(DSSCs) have been recognized as an alternative to the conventional p-n junction solar cells because of their simple fabrication process, low production cost, and transparency. A typical DSSC consists of a transparent conductive oxide (TCO) electrode, a dye-sensitized oxide semiconductor nanoparticle layer, liquid redox electrolyte, and a Pt-counter electrode. In dye-sensitized solar cells, charge recombination processes at interfaces between coducting glass, $TiO_2$, dye, and electrolyte play an important role in limiting the photon-to-electron conversion efficiency. A layer of ZTO thin film less than ~200nm in thickness, as a blocking layer, was deposited by DC magnetron sputtering method directly onto the anode electrode to be isolated from the electrolyte in dye-sensitized solar cells(DSCs). This is to prevent the electrons from back-transferring from the electrode to the electrolyte ($I^-/I_3^-$). The presented DSCs were fabricated with working electrode of Ga-doped ZnO glass coated with blocking ZTO layer, dye-attached nanoporous $TiO_2$ layer, gel electrolyte and counter electrode of Pt-deposited GZO glass. The effects of blocking layer were studied with respect to impedance and conversion efficiency of the cells.

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Design tables and charts for uniform and non-uniform tuned liquid column dampers in harmonic pitching motion

  • Wu, Jong-Cheng;Wang, Yen-Po;Chen, Yi-Hsuan
    • Smart Structures and Systems
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    • v.9 no.2
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    • pp.165-188
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    • 2012
  • In the first part of the paper, the optimal design parameters for tuned liquid column dampers (TLCD) in harmonic pitching motion were investigated. The configurations in design tables include uniform and non-uniform TLCDs with cross-sectional ratios of 0.3, 0.6, 1, 2 and 3 for the design in different situations. A closed-form solution of the structural response was used for performing numerical optimization. The results from optimization indicate that the optimal structural response always occurs when the two resonant peaks along the frequency axis are equal. The optimal frequency tuning ratio, optimal head loss coefficient, the corresponding response and other useful quantities are constructed in design tables as a guideline for practitioners. As the value of the head loss coefficient is only available through experiments, in the second part of the paper, the prediction of head loss coefficients in the form of a design chart are proposed based on a series of large scale tests in pitching base motions, aiming to ease the predicament of lacking the information of head loss for those who wishes to make designs without going through experimentation. A large extent of TLCDs with cross-sectional ratios of 0.3, 0.6, 1, 2 and 3 and orifice blocking ratios ranging from 0%, 20%, 40%, 60% to 80% were inspected by means of a closed-form solution under harmonic base motion for identification. For the convenience of practical use, the corresponding empirical formulas for predicting head loss coefficients of TLCDs in relation to the cross-sectional ratio and the orifice blocking ratio were also proposed. For supplemental information to horizontal base motion, the relation of head loss values versus blocking ratios and the corresponding empirical formulas were also presented in the end.

A Study on Characteristics of Urethane Polymer as Injection Material for Ground Improvement

  • Chun, Byung-Sik;Park, Heung-Kyu;Ryu, Dong-Sung
    • Geotechnical Engineering
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    • v.12 no.3
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    • pp.99-108
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    • 1996
  • The physical and chemical properties of polyurethane-yieding twofomponent liquid injection mixture and those of the resulting polyurethane solid foam for chemical grouting are investigated. The chemical experiments on the factors influencing the properties of polyurethane show that the behaviors of polyurethane-yielding liquid material and those of the produced polyurethane solid foam are greatly affected by the ground conditions such as temperature, water content and density of soil. The ground reinforcing and water -blocking effects of polyurethane grouting are examined through field case history of tunnel ericavati on of the subway under construction.

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Pulse Density Modulated ZVS High Frequency Inverter with Reverse Blocking Single Switch for Dielectric Barrier Discharge Lamp Dimming

  • Sugimura Hisayuki;Yasui Kenji;Omori Hideki;Lee Hyun-Woo;Nakaoka Mutsuo
    • Proceedings of the KIPE Conference
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    • 2006.06a
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    • pp.206-209
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    • 2006
  • At present, the cold cathode fluorescent lamp (CCFL) using mercury lamp has been generally used far liquid crystal backlight source of personal computer and car navigation and so on. This kind of lamp is more excellent on luminance performance and cost. However, the requirements of liquid crystal backlight due to a light source without mercury have been strongly increased from a viewpoint of the actual influence on environmental preservation and environmental recycling. As fluorescent lamp without mercury, Dielectric Barrier Discharge based rare gas fluorescent lamp (DBD-FL) using xenon (Xe) gas has been studied so far. This DBD lamp has no influence on the human body and environmental recycle. Its operating life is long because electrode is out. In this paper, the simulation and experimental results of soft switching high frequency inverter with reverse blocking single switch as a high frequency power supply circuit for DBD-FL using Xe gas are comparatively evaluated and discussed from a practical point of view.

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Development of a Denaturing High-Performance Liquid Chromatography (DHPLC) Assay to Detect Parasite Infection in Grass Shrimp Palaemonetes pugio

  • Cho, Sang-Man
    • Fisheries and Aquatic Sciences
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    • v.15 no.2
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    • pp.107-115
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    • 2012
  • In developing a useful tool to detect parasitic dynamics in an estuarine ecosystem, a denaturing high-performance liquid chromatography (DHPLC) assay was optimized by cloning plasmid DNA from the grass shrimp Palaemonetes pugio, and its two parasites, the trematode Microphallus turgidus and bopyrid isopod Probopyrus pandalicola. The optimal separation condition was an oven temperature of $57.9^{\circ}C$ and 62-68% of buffer B gradient at a flow rate of 0.45 mL/min. A peptide nucleic acid blocking probe was designed to clamp the amplification of the host gene, which increased the amplification efficiency of genes with low copy numbers. Using the DHPLC assay with wild-type genomic, the assay could detect GC Gram positive bacteria and the bopyrid isopod (P. pandalicola). Therefore, the DHPLC assay is an effective tool for surveying parasitic dynamics in an estuarine ecosystem.

Liquid Chromatographic Resolution of Racemic Drugs on Various $\alpha$-Arylalkylamine Derived Chiral Stationary Phases

  • Hyun, Myung-Ho;Pirkle, William H.
    • Bulletin of the Korean Chemical Society
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    • v.8 no.1
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    • pp.45-47
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    • 1987
  • After conversion to their 3,5-dinitrobenzoyl or 3,5-dinitroanilide derivatives, the enantiomers of a number of drugs may be chromatographically separated on various ${\alpha}$-arylalkylamine-derived chiral stationary phases (CSPs). While each CSP used in this study is useful, CSP 1 is best able to resolve the 3,5-dinitroanilide derivative of Ibuprofen while CSP 9 generally gives rather large ${\alpha}$ values for the resolution of 3,5-dinitrobenzoyl derivatives of the enantiomers of ${\beta}$-adrenergic blocking drugs.

Parallel 3-dimensional optical interconnections using liquid crystal devices for B-ISDN electronic switching systems

  • Jeon, Ho-In;Cho, Doo-Jin
    • Journal of the Optical Society of Korea
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    • v.1 no.1
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    • pp.52-59
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    • 1997
  • In this paper, we propose a system design for a parallel3-dimensional optical interconnection network utilizing variable grating mode liquid crystal devices (VGM LCD's) which are optical transducers capable of performing intensity-to-spatial-frequency conversion. The proposed system performs real-time, reconfigurable, but blocking and nonbroadcasting 3-dimensional optical interconnections. The operating principles of the 3-D optical interconnection network are described, and some of the fundamental limitations are addressed. The system presented in this paper can be directly used as a configuration of switching elements for the 2-D optical perfect-shuffle dynamic interconnection network, as well as for a B-ISDN photonic switching system.

Fundamental study on performance characteristics of a micro heat pipe with triangular cross section (삼각단면 극소히트파이프의 작동특성에 관한 기초 연구)

  • 문석환;김종오;김철주
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.2
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    • pp.176-184
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    • 1999
  • Numerical and experimental studies were performed to examine the characteristics of heat and mass transfer processes for a Micro Heat Pipe(MHP) with a triangular cross-section. Solutions on mass flow rate, pressure variation, and radius of meniscus were obtained using the mathematical model developed by Faghri and Khrustalev. To obtain an increase in capillary limitation, a triangular tube with curved walls was designed and fabricated. The measurement by microscope showed that the radius at corners of the tube was ranging between 0.03-0.05mm. Performance test for MHPs using the triangular tube with curved walls proved a substantial increasement in heat transport limitation, with 4.5W and 2.0W in case of using water and ethanol as a working fluid, respectively. In the previous study by Faghri a limitation of 0.5W was reported for a water MHP with a regular triangular tube.

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Liquid Phase Deposition of Transition Metal Ferrite Thin Films: Synthesis and Magnetic Properties

  • Caruntu Gabriel;O'Connor Charles J.
    • Journal of the Korean Ceramic Society
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    • v.43 no.11 s.294
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    • pp.703-709
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    • 2006
  • We report on the synthesis of highly uniform, single phase zinc and cobalt thin films prepared by the Liquid Phase Deposition (LPD) method. X-Ray diffraction, TGA and EDX measurements support the assumption that the as deposited films are constituted by a mixture of crystallized FeOOH and amorphous M(OH)$_2$ (M=Co, Zn) which is converted upon heat treatment in air at 600?C into the corresponding zinc ferrites. The films with adjustable chemical compositions are identified with a crystal structure as spinel-type and present a spherical or rod-like microstructure, depending on the both the nature and concentration of the divalent transition metal ions. Zinc ferrite thin films present a superparamagnetic behavior above blocking temperatures which decrease with increasing the Zn content and are ferromagnetic at 5 K with coercivities ranging between 797.8 and 948.5 Oe, whereas the cobalt ferrite films are ferromagnetic at room temperature with magnetic characteristics strongly dependent on the chemical composition.

Microfiltration of Chlorella sp.: Influence of material and membrane pore size

  • Ahmad, A.L.;Yasin, N.H. Mat;Derek, C.J.C.;Lim, J.K.
    • Membrane and Water Treatment
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    • v.4 no.2
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    • pp.143-155
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    • 2013
  • Four membranes were used to separate Chlorella sp. from their culture medium in cross-flow microfiltration (MF) experiments: cellulose acetate (CA), cellulose nitrate (CN), polypropylene (PP) and polyvinylidenefluoride (PVDF). It was found that the hydrophilic CA and CN membranes with a pore size of 1.2 ${\mu}m$ exhibited the best performances among all the membranes in terms of permeation flux. The hydrophobicity of each membrane material was determined by measuring the angle between the water (liquid) and membrane (solid). Contact angle measurements showed that deionized (DI) water had almost adsorbed onto the surfaces of the CA and CN membranes, which gave $0.00^{\circ}$ contact angle values. The PP and PVDF membranes were more hydrophobic, giving contact angle values of $95.97^{\circ}$ and $126.63^{\circ}$, respectively. Although the pure water flux increased with increasing pore diameter (0.8 < 1.2 < 3.0 ${\mu}m$) in hydrophilic CA and CN membranes, the best performance in term of filtration rate for filtering a microalgae suspension was attained by membranes with a pore size of 1.2 ${\mu}m$. The fouled membrane pore sizes and pore blocking were inspected using a scanning electron microscope (SEM). MF with large pore diameters was more sensitive to fouling that contributed to intermediate blocking, where the size of the membrane pores is almost equivalent to that of cells.