• 한국대기환경학회지
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• 제21권3호
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• pp.285-293
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• 2005

This study was aimed at estimation of gas-particle partitioning of polychlorinated biphenyls (PCBs) in ambient air. The samples were collected at urban site in Japan from March 2002 to January 2003. The concentration of total PCBs (from 4 CB to 10 CB) and TEQ (Toxic equivalent) ranged from 62 to $247\;pg/m^3$ and from 2 to $14\;fgTEQ/m^3 $, respectively. The average contribution $(\%)$ of gas phase to total PCBs concentration was above $80\%$, which suggests that in the atmosphere PCBs predominantly existed in the gas phase. The weak correlations between total PCBs concentration and temperature was found. However this result was due to a typhoon during summer and raining during sampling period. The gas-particle partition coefficient (Kp) was obtained as a function of temperature. The partition ratio of gaseous and particulate phase PCBs can be estimated for an arbitrary temperature. The plot of gas/particle partition coefficient (log Kp) vs. sub-cooled liquid vapor pressure $(log\;P_L)$ had reasonable correlations for individual samples but the slope varied among the samples (coefficients of determination for log Kp versus log $P_L$ plot were> 0.76 $(p<0.0001)$, except for 3 samples). As a result, the variations in the slope among the sampling period may be due to change of temperature, raining during sampling period and wind in this study.

• 한국분무공학회지
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• 제10권4호
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• pp.47-53
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• 2005

This paper presents the effects of ambient pressure on atomization characteristics of high-Pressure injector in a direct injection gasoline engine both experimentally and numerically. The atomization characteristics such as mean droplet size, mean velocity, and velocity distribution were measured by phase Doppler particle analyzer. The spray development, spray penetration, and global spray structure were visualized using a shadowgraph technique. In order to investigate the atomization process numerically, the LISA-DDB hybrid model was utilized. This breakup model assumes that the primary breakup occurs when the amplitude of the unstable waves is equal to the radius of the ligament of liquid sheet near the nozzle and the droplet deformation induces the secondary breakup. The results provide the effect of ambient pressure on the macroscopic and microscopic behaviors such as spray development, spray penetration, mean droplet size, and mean velocity distribution. It is also revealed that the accuracy of prediction of LISA-DDB hybrid model is pretty good in terms of spray developing process, spray tip penetration, and SMD distribution.

• 한국자동차공학회논문집
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• 제2권6호
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• pp.102-109
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• 1994

As a fundamental study to apply high pressure injection system to direct injection diesel engine, fuel injection system and constant volume combustion chamber were made and the behaviors of evaporating spray with the variation of injection pressure and the ambient gas temperature were observed by using high speed camera, and the combusion characteristics with the variation of injection pressure and A/F ratio were analyzed. As injection pressure increases, spray tip penetration and spray angle increase and, as a results spray volume increases. This helps an uniform mixing of fuel and air. Spray liquid core length decreases as ambient gas temperature increases, while it decreases as injection pressure increases but the effect of ambient gas temperature is dorminant. As injection pressure increases, ignition delay is shortened and combustion rate being raised, maximum heat release rate increases. It become clear that High injection pressure has high level of potential to improve the performance of DI-diesel engine.

• 한국분무공학회지
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• 제21권1호
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• pp.29-36
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• 2016

The effect of high ambient temperature and pressure conditions on the combustion performance of n-butanol, n-heptane and its mixing fuel (BH 20) were studied in this work. To reveal this, the closed homogeneous reactor model applied and 1000-1200 K of the initial temperature, 20-30 atm of initial pressure and 1.0 of equivalence ratio were set to numerical analysis. It was found that the results of combustion temperature was increased and the ignition delay was decreased when the ambient conditions were elevated since the combustion reactivity increased at the high ambient conditions. On the contrary, under the low combustion temperature condition, the combustion pressure was more influenced by the ambient temperature in the same ambient conditions. In addition, the total mass and the mass density of tested fuels were influenced by the ambient pressure and temperature. Also, soot generation of mixing fuel was decreased than n-heptane fuel due to the oxygen content of n-butanol fuel.

• Bulletin of the Korean Chemical Society
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• 제35권3호
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• pp.865-870
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• 2014

Gold nanoparticles (AuNPs) were synthesized by laser (Nd:YAG, ${\lambda}$ = 1064 nm) ablation of a gold target immersed in various aqueous electrolyte solutions (7 mM of LiCl, NaCl, KCl, NaBr, and NaI) as well as in deionized water. The surface plasmon absorption and EDX of AuNPs so produced as well as their TEM images were analyzed to investigate the effects of ambient ions on the growth and aggregation of NPs. The size of AuNPs was reduced by laser ablation in the presence of chloride and bromide ions while it increased drastically when AuNPs were formed in iodide solution. Interestingly, triangular nanoplates were synthesized only in iodide solution. Surface chemistry on AuNPs in various electrolyte solutions was explored to elucidate the role of ions on the size and stability of AuNPs.

• 대한기계학회논문집B
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• 제27권9호
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• pp.1273-1281
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• 2003

The present study is mainly motivated to investigate the vaporization, auto-ignition, and combustion of liquid fuel spray injected into high pressure environment. The unsteady, multi-dimensional models were used for realistic simulation of spray as well as prediction of accurate ignition delay time. The Separated Flow (SF) model which considers the finite rate of transport between liquid and gas phases was employed to represent the interactions between spray and gas field. Among the SF models, the Discrete Droplet Model (DDM) which simulates the spray using finite number of representative samples of discrete droplets was adopted. The Eulerian-Lagrangian formulation was used to analyze the two-phase interactions. In order to predict an evaporation rate of droplet in high pressure environment, the high pressure vaporization model was applied using thermodynamic equilibrium and phase equilibrium at droplet surface. The high pressure effect as well as high temperature effect was considered in the calculation of liquid and gas properties. In case of vaporization, an interaction between droplets was studied through the simulation of spray. The interaction is shown up differently whether the ambient gas field is at normal pressure or high pressure. Also, the characteristics of spray behavior in high pressure environment were investigated through the comparison with normal ambient pressure case. In both cases, the spray behaviors are simulated through the distributions of temperature and reaction rate in gas field.

• 한국대기환경학회지
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• 제34권1호
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• pp.120-143
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• 2018

The analytical methods and their ambient levels of organic nitrogenous compounds such as nitrosamines, nitramines (nitroamines), imines, amides and nitro-polycyclic aromatic hydrocarbons (nitro-PAHs) in the atmosphere are summarized and discussed. Sampling for the analysis of organic nitrogenous compounds was mostly conducted using high volume air sampler. The direct liquid extraction (DLE) using sonification and the pressurized liquid extraction (PLE) using the accelerated solvent extraction (ASE) have been frequently employed for the extraction of organic nitrogenous compounds in the atmospheric samples. After extraction, clean-up via filtration and the solid phase extraction (SPE) and concentrations using nitrogen and rotary evaporator have been generally conducted but in some studies the clean-up and concentration steps have been omitted to prevent the loss of analyte and improve the recovery rate of the analytical procedure. Instrumental analysis was mainly carried out using gas chromatography (GC) or the high performance liquid chromatography (HPLC) coupled with the single quadrupole mass spectrometer or tandem mass spectrometer in the electron ionization (EI), positive chemical ionization (PCI) and negative chemical ionization (NCI) mode and analysis sensitivity of nitrosamines and nitramines were higher in NCI mode. Desirable sampling and analysis methods for analyzing particulate organic nitrogenous compounds are suggested.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2008년도 동계학술발표대회 논문집
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• pp.324-329
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• 2008

The liquid cooling effect of a natural convection type radiator by using the PCM has been investigated experimentally. The radiator size is $423{\times}295{\times}83$ mm and PCM container size is $398{\times}270{\times}26$ mm. The objective is elapsed time higher than maximum time to reach for maximum operating temperature of a general liquid cooling radiator. This study, in order to study on the effects of the phase-change phenomenon, carried out the various mass flow rate, input electric power, ambient and melting point of three type PCM. For the above experimental parameter, the melting time was performed about 180/250/560 min at input power 150 W and ambient $30^{\circ}C$ from using the three type PCM(PCM_S1/S2/S3) respectively. Furthermore, the effects of the thermal dissipation was decreased higher input power than lower input power at heating block and melting time of PCM. However, the effects of mass flow rate did not nearly affect of the thermal performance especially.

• International Journal of Automotive Technology
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• 제2권3호
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• pp.103-107
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• 2001

Many researches on pressure-swirl injectors due to the variety of application have been conducted on the effects of nozzle design, operating conditions, properties of liquid and ambient conditions on the flow and spray characteristics. The breakup length of conical emulsified fuel sheet resulting from pressure-swirl atomizer using in the oil burner was investigated with the digital image processing method with neat light oil and emulsion with water content of lotto% and the surfactant content of 1-3%. The injection pressure ranged from 0.1 to 1.2 MPa was selected. The various regimes for the stage of spray development within the experimental conditions selected in this study is newly suggested in terms of Ohnesorge number and injection pressure. The breakup length for both criteria show the same tendency even though the random nature of perforation and disintegration process of liquid sheet. The stage of spray development is widely different with the physical properties of liquid atomized, mainly viscosity of liquid. The breakup length decreases smoothly with increase in the injection pressure for the lower viscous liquid.

• 한국가시화정보학회지
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• 제9권1호
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• pp.55-60
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• 2011

Pulsed supersonic liquid jets injected into an ambient air are empirically studied by using a high pressure ballistic range system. Ballistic range systems which are configured with high-pressure tube, pump tube, launch tube and liquid storage nozzle. Experimental studies are conducted to use with various impact nozzle geometry. Supersonic liquid jets are generated by an impact of high speed of the projectile. High speed liquid jets are injected with M = 3.2 which pressure is 1.19 GPa. Multiple jets which accompany with shock wave and pressure wave in front of the jet were observed. The shock-wave affects significantly atomization process for each spray droplets. As decreasing orifice diameter, the averaged SMD of spray jets had the decreasing tendency.