• Title/Summary/Keyword: Liquid Sheet Thickness

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Optimization of Electro-Optical Properties of Acrylate-based Polymer-Dispersed Liquid Crystals for use in Transparent Conductive ZITO/Ag/ZITO Multilayer Films (투명 전도성 ZITO/Ag/ZITO 다층막 필름 적용을 위한 아크릴레이트 기반 고분자분산액정의 전기광학적 특성 최적화)

  • Cho, Jung-Dae;Kim, Yang-Bae;Heo, Gi-Seok;Kim, Eun-Mi;Hong, Jin-Who
    • Applied Chemistry for Engineering
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    • v.31 no.3
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    • pp.291-298
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    • 2020
  • ZITO/Ag/ZITO multilayer transparent electrodes at room temperature on glass substrates were prepared using RF/DC magnetron sputtering. Transparent conductive films with a sheet resistance of 9.4 Ω/㎡ and a transmittance of 83.2% at 550 nm were obtained for the multilayer structure comprising ZITO/Ag/ZITO (100/8/42 nm). The sheet resistance and transmittance of ZITO/Ag/ZITO multilayer films meant that they would be highly applicable for use in polymer-dispersed liquid crystal (PDLC)-based smart windows due to the ability to effectively block infrared rays (heat rays) and thereby act as an energy-saving smart glass. Effects of the thickness of the PDLC layer and the intensity of ultraviolet light (UV) on electro-optical properties, photopolymerization kinetics, and morphologies of difunctional urethane acrylate-based PDLC systems were investigated using new transparent conducting electrodes. A PDLC cell photo-cured using UV at an intensity of 2.0 mW/c㎡ with a 15 ㎛-thick PDLC layer showed outstanding off-state opacity, good on-state transmittance, and favorable driving voltage. Also, the PDLC-based smart window optimized in this study formed liquid crystal droplets with a favorable microstructure, having an average size range of 2~5 ㎛ for scattering light efficiently, which could contribute to its superior final performance.

A Study of Electro-Optical Properties of Polyester Acrylate-Based Polymer-Dispersed Liquid Crystals Using TIZO/Ag/TIZO Multilayer Transparent Electrodes (TIZO/Ag/TIZO 다층막 투명전극을 이용한 폴리에스터 아크릴레이트 기반 고분자분산액정의 전기광학적 특성 연구)

  • Cho, Jung-Dae;Heo, Gi-Seok;Hong, Jin-Who
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.50-57
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    • 2022
  • Ti-In-Zn-O (TIZO)/Ag/TIZO multilayer transparent electrodes were prepared on glass substrates at room temperature using RF/DC magnetron sputtering. Obtained multilayer structure comprising TIZO/Ag/TIZO (10 nm/10 nm/40 nm) with the total thickness of 60 nm showed a transmittance of 86.5% at 650 nm and a sheet resistance of 8.1 Ω/□. The multilayer films were expected to be applicable for use in energy-saving smart window based on polymer-dispersed liquid crystal (PDLC) because of their transmittance properties to effectively block infrared rays (heat rays). We investigated the effects of the content ratio of prepolymer, the thickness of the PDLC coating layer, and the ultraviolet (UV) light intensity on electro-optical properties, and the surface morphology of polyester acrylate-based PDLC systems using new TIZO/Ag/TIZO transparent conducting electrodes. A PDLC cell with a thickness of 15 ㎛ PDLC layer photocured at an UV intensity of 1.5 mW/cm2 exhibited good driving voltage, favorable on-state transmittance, and excellent off-haze. The LC droplets formed on the surface of the polymer matrix of the PDLC composite had a size range of 1 to 3 ㎛ capable of efficiently scattering incident light. Also, the PDLC-based smart window manufactured using TIZO/Ag/TIZO multi-layered transparent electrodes in this study exhibited a light brown, which will have an advantage in terms of aesthetics.

Silicone Rubber Membrane Bioreactors for Bacterial Cellulose Production

  • Onodera, Masayuki;Harashima, Ikuro;Toda, Kiyoshi;Asakura, Tomoko
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.5
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    • pp.289-294
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    • 2002
  • Cellulose production by Acetobacter pasteurianus was investigated in static culture using four bioreactors with silicone rubber membrane submerged in the medium. The shape of the membrane was flat sheet, flat sack, tube and cylindrical balloon. Production rate of cellulose as well as its yield on consumed glucose by the bacteria grown on the flat type membranes was approximately ten-fold greater than those on the non-flat ones in spite of the same membrane thickness. The membrane reactor using flat sacks of silicone rubber membrane as support of bacterial pellicle can supply greater ratio of surface to volume than a conventional liquid surface culture and is promising for industrial production of bacterial cellulose in large scale.

Simulation of the paper drying using CFD field Model (CFD를 이용한 종이건조의 전산모사)

  • Im, Jeong-Hun;Lee, Seong-Cheol
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2004.04a
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    • pp.127-139
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    • 2004
  • The process of papermaking involves water removal on the paper machine wire, in the press section and in the dryer section. In the dryer section, liquid water in the wet web is removed mainly by evaporation. In conventional machine this is achieved by passing the web over a number of steam heated dryer rolls. A drying process of paper on a heated cylinder roll calculated based on a 1-dimensional model which concerns unsteady heat and mass transfer in the direction of paper thickness. In this study, Prediction of moisture contents average paper sheet temperature and volume fraction along a series of cylinder. Independently, developed models is compared using the same reference data. The model is implemented in CFD code, FLUENT, using user-define-function(UDFs).

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Preparation and characterization of high transmittance and low resistance index matched transparent conducting oxide coated glass for liquid crystal on silicon panel

  • Jang, Chang-Young;Paik, Woo-Sung;Choi, Bum-Ho;Kim, Young-Back;Lee, Jong-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1415-1417
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    • 2009
  • High transmittance and low resistance index matched transparent conducting oxide (IMTCO) coated glass was prepared and characterized. IMTCO was deposited by RF magnetron sputtering with the thickness of 15nm and 90nm thick anti-reflection layer was evaporated. To modify surface to hydrophilic, in-situ plasma treatment was also performed. IMTCO coated glass exhibited 96.6% of transmittance in the wavelength range of 400~700nm which is relatively high value compared to commercially available IMTCO glass. The sheet resistance uniformity was measured to be 1.53%.

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Quantification of Crystallinity Change in Celluloses during Refining

  • Kim, Chul-Hwan;Yang, Jae-Kyung;Park, Jong-Yawl
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.5
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    • pp.8-13
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    • 2000
  • X-ray diffraction technique was used to quantify change of cellulose crystallinity during refining. XRD data confirmed that fiber wall delamination was caused by the structural conversion of celluloses which occurred in a liquid medium during refining. The quantified crystallinity of celluloses in pulp fibers was closely associated with the change of fiber wall delamination, which was defined by measurement of fiber wall thickness. In particular, it was well recognized that low intensity beating showed a better response in the change of crystallinity than high intensity one. The decrease o cellulose crystallinity during refining considerably enhanced the improvement of interfiber bonding ability of a dried sheet.

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Dynamics and Instability of a Polymeric Paint in Roll Coating Process for Automotive Pre-coating Application (자동차 선도장을 위한 롤코팅 공정에서 고분자 도료의 동적 거동 및 불안정성)

  • Kim, Jin-Ho;Lee, In-Jun;Noh, Seung-Man;Kang, Choong-Yeol;Nam, Joon-Hyun;Jung, Hyun-Wook;Park, Jong-Myung
    • Polymer(Korea)
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    • v.35 no.6
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    • pp.574-579
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    • 2011
  • 3-Roll coating process as a key application technology for manufacturing automotive pre-painted metal-sheets has been studied. The 3-Roll coating system for this study consists of pick-up roll for picking up and distributing coating liquid from the reservoir, metering roll to properly meter coating liquid in metering gap regime, and applicator roll for directly transferring liquid into metal-sheet surface. Flow dynamics and operable coating windows of a polymeric paint (primer) with shear-thinning rheological property have been correlated with processing parameters such as speed ratio and metering gap between pick-up and metering rolls. In the uniform coating regime, dry coating thickness increased with increasing metering gap or decreasing speed ratio. Ribbing and cascade instabilities were observed in low speed and high speed ratio conditions, respectively. It is revealed that lower speed ratio makes severity and wavelength of the ribbing increase, aggravating flow instability in coating systems.

Investigating the Effect of Homogenization Heat Treatment on the Microstructure and Texture of Magnesium Alloy Sheet Manufactured via Twin Roll Casting (트윈롤 주조법으로 제조된 마그네슘합금 판재의 균질화 열처리에 따른 미세조직 및 집합조직 발달)

  • Lee, Hee Jae;Park, No Jin
    • Journal of the Korean Society for Heat Treatment
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    • v.34 no.3
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    • pp.122-129
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    • 2021
  • This study focuses on the microstructural development of 99% magnesium alloy sheet manufactured using twin roll casting (TRC) process. Herein, a plate with a thickness of 5 mm was manufactured using the TRC process, homogenization heat treatment was performed at 400℃ for 2-32 h, and finally, the change in microstructure was evaluated via optical microscopy and textural analysis. The results suggest that the plate manufactured using the TRC process was not destroyed and was successfully rolled into a plate. Microscopic observation suggested that the dendritic cast structure was arranged along the rolling direction. And the central layer of the rolled plate, where was present in a liquid state at the beginning of rolling, solidified later during the TRC process to form central segregation. The initial cast structure and inhomogeneous structure of the plate were recrystallized by homogenization heat treatment for only 2 h, and it was confirmed that the segregated part of the central layer became homogeneous and recrystallization occurred. Grain growth occurred as the heat treatment time increased, and secondary recrystallization occurred, wherein only some grains were grown. The textural analysis, which was conducted via X-ray diffraction, confirmed that the relatively weak basal plane texture developed using the TRC process was formed into a random texture after heat treatment.

Recent Developments in Agricultural Sprays : Review

  • No, S. Y.
    • Agricultural and Biosystems Engineering
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    • v.3 no.1
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    • pp.44-54
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    • 2002
  • A brief review of current status in the field of agricultural spray and future research challenges are presented. Researches on the pesticides sprays, pollen sprays, postharvest sprays, and biological control agent sprays among the various applications of agricultural spray were selected and reviewed. In the agrochemical sprays, the techniques to increase the deposition such as electrospray and reduce the drift such as introductions of drift retardants and of mechanical means are reviewed. The introduction of mechanical means includes low drift, air-assisted, air inclusion, shield or shroud assisted and pulse flow nozzles. For flat fan nozzles, the data of breakup length and thickness of liquid sheet are essential to understand the atomization processes and develop the transport model to target In the air-assisted spray technology to reduce drift, further works on the effect of application height on drift and air assistance on droplet size should be followed. In addition, methods for quantifying the included air in the air inclusion techniques are required. The atomization characteristics of biopesticides spray are not being elucidated and the formulations of biopesticides should be taken into account the spray characteristics of existing nozzle and sprayer. A few researches on the droplet size of fallout can be found in the literature. A combined technology with electrostatic method into one of method for the reduction of drift may be an effective strategy for increasing deposition and reducing drift. Only an integrated approach involving all stakeholders such as engineers, chemists, and biologists, etc. can result in improved application of agricultural spray.

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Fabrication of a Transparent Electrode for a Flexible Organic Solar Cell in Atomic Layer Deposition (ALD 공정을 이용한 플렉시블 유기태양전지용 투명전극 형성)

  • Song, Gen-Soo;Kim, Hyoung-Tae;Yoo, Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.121.2-121.2
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    • 2011
  • Aluminum-doped Zinc Oxide (AZO) is considered as an excellent candidate to replace Indium Tin Oxide (ITO), which is widely used as transparent conductive oxide (TCO) for electronic devices such as liquid crystal displays (LCDs), organic light emitting diodes (OLEDs) and organic solar cells (OSCs). In the present study, AZO thin film was applied to the transparent electrode of a channel-shaped flexible organic solar cell using a low-temperature selective-area atomic layer deposition (ALD) process. AZO thin films were deposited on Poly-Ethylene-Naphthalate (PEN) substrates with Di-Ethyl-Zinc (DEZ) and Tri-Methyl-Aluminum (TMA) as precursors and $H_2O$ as an oxidant for the atomic layer deposition at the deposition temperature of $130^{\circ}C$. The pulse time of TMA, DEZ and $H_2O$, and purge time were 0.1 second and 20 second, respectively. The electrical and optical properties of the AZO films were characterized as a function of film thickness. The 300 nm-thick AZO film grown on a PEN substrate exhibited sheet resistance of $87{\Omega}$/square and optical transmittance of 84.3% at a wavelength between 400 and 800 nm.

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