• Title/Summary/Keyword: Liquid Exfoliation

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Enhanced Carbon Nanotube Dissolution for Electrically Conductive Films (전기전도성 필름제조를 위한 탄소나노튜브 용해도 향상)

  • Lee, Geon-Woong;Han, Dong-Hee;Park, Su-Dong;Kang, Dong-Pil;Kumar, Satish
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.65-66
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    • 2006
  • Solubility of single wall carbon nanotubes (SWNTs) has been determined in various dispersing media by using the solvent parameters such as Kamlet-Taft parameter and 3-dimensional parameters. Nitric acid-treated SWNTs exhibit significantly improved solubility in hydrogen bondable solvents as well as in solvent mixtures. The forming bucky gel with ionic liquid allows for the new group of dissolving solvent. The dissolution behavior of SWNTs provides a route for SWNT dispersion/exfoliation in preparing electrically conductive films such as transparent electrode.

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Fabrication of 6-superconducting layered HTS wire for high engineering critical current density

  • Kim, Gwantae;Ha, Hongsoo;Kim, Hosup;Oh, Sangsoo;Lee, Jaehun;Moon, Seunghyun
    • Progress in Superconductivity and Cryogenics
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    • v.23 no.4
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    • pp.10-13
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    • 2021
  • Recently, cable conductors composed of numerous coated conductors have been developed to transport huge current for large-scale applications, for example accelerators and fusion reactors. Various cable conductors such as CORC (Conductor on round core), Roebel Cable, and TSTC (Twisted stacked tape cable) have been designed and tested to apply for large-scale applications. But, these cable conductors cannot improve the engineering critical current density (Je) because they are made by simple stacking of coated conductors. In this study, multi-HTS (High temperature superconductor) layers on one substrate (MHOS) wire was fabricated to increase the engineering critical current density by using the exfoliation of superconducting layer from substrate and silver diffusion bonding method. By the repetition of these processes, the 10 m long 6-layer MHOS conductor was successfully fabricated without any intermediate layers like buffer or solder. 6-layer MHOS conductor exhibited a high critical current of 2,460A/12mm-w. and high engineering critical current density of 1,367A/mm2 at liquid nitrogen temperature.

Evaluation of the Properties of Wrapping Material of Steel Pipe for Water Supply (수도용 강관의 도복장 재료특성 평가에 관한 연구)

  • Lee, Hyun-Dong;Lee, Ji-Eun;Kwak, Phill-Jae
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.3
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    • pp.331-338
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    • 2008
  • Coal-tar enamel, blown asphalt and polyethylene have been used as wrapping materials of steel pipe in Korea. Currently, every manufacturer produces wrapped steel pipes with different materials and methods, and little research has been performed to get on wrapping methods and materials. In this research, properties of wrapping material of steel pipe used for water supply have been evaluated. All of the materials tested in this work were found to meet the standard. Among the wrapping materials of steel pipe tested, blown asphalt and coal-tar enamel were reasonable in price, and their mechanical properties were excellent. The quality of the wrapped steel pipes was being melted easily in organic solvent. When coated thick, the load of the steel pipes was higher than necessary. Tensile strength of cathode exfoliation and PE 3-layer wrapping method was excellent. The pulling intensity of T-Die PE 3-layer was stronger than PE fluidized in PE wrapping method. Cathode exfoliation area was smaller than PE fluidized. Mechanical property and thermo-property of T-Die PE 3-layer were excellent and its anti-chemical property was great. Liquid epoxy can change the property of coating materials depending on the hardening condition and resin selection. Polyurethane used in this test showed a less adhesive strength with steel pipes than epoxy. Moisture absorbance rate was higher than Epoxy's, however. To utilize polyurethane as wrapping materials, basic property of the matter should be improved followed by finding the best suited coating condition. The method of PE 3-layer by extrude method appeared to be the best in this study. However, identification of other wrapping materials requires further additional tests.

Characteristics of Graphene Production from Graphite using Plant Extracts (식물추출액을 이용한 흑연으로부터 그래핀 생산 특성)

  • Jeong, Yongjae;Ryu, Hojun;Choi, Chorong;An, Sanghyeon;Kim, Woojung;Kim, Dongho;Choi, Byeongseo;Salunke, Bipinchandra K.;Kim, Beom Soo
    • KSBB Journal
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    • v.31 no.4
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    • pp.208-213
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    • 2016
  • Recently, numerous studies have utilized graphene in biomedical applications such as drug delivery, cancer therapy, and bioimaging. In this study, graphene was eco-friendly prepared by liquid phase exfoliation of graphite using plant extracts in water. Initially, 12 different plants or plant parts were screened for the characteristic graphene peak at near 268 nm using UV-Vis spectrophotometric analyses. The ability to form stable black graphene dispersion was highest using Xanthium strumarium extract. Transmission electron microscopy images showed that about 5 layer-graphene was produced from 1 g/L of graphite, while more than 5 layers were formed from 2 g/L of graphite. The optimum X. strumarium concentration for graphene production was 2 g/100 mL.

Electrochemical Lithium Intercalation within Graphite from Ionic Liquids containing BDMI+ Cation (BDMI+ 양이온을 함유한 이온성 액체로부터 흑연으로의 전기화학적 리튬 삽입)

  • Lee, You-Shin;Jeong, Soon-Ki;Lee, Heon-Young;Kim, Chi-Su
    • Journal of the Korean Electrochemical Society
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    • v.13 no.3
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    • pp.186-192
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    • 2010
  • In situ electrochemical atomic force microscopy (ECAFM) observations of the surface of highly oriented pyrolytic graphite (HOPG) was performed before and after cyclic voltammetry in lithium bis(fluorosulfonyl)imide (LiTFSI) dissolved in 1-buthyl-2,3-dimethylimidazolium (BDMI)-TFSI to understand the interfacial reactions between graphite and BDMI-based ionic liquids. The formation of blisters and the exfoliation of graphene layers by the intercalation of $BDMI^+$ cations within HOPG were observed instead of reversible lithium intercalation and de-intercalation. On the other hand, lithium ions are reversibly intercalated into the HOPG and de-intercalatied from the HOPG without intercalation of the $BDMI^+$ cations in the presence of 15 wt% of 4.90 mol/$kg^{-1}$ LiTFSI dissolved in propylene carbonate (PC). ECAFM results revealed that the concentrated PC-based solution is a very effective additive for preventing $BDMI^+$ intercalation through the formation of solid electrolyte interface (SEI).