• Title/Summary/Keyword: Liquid Crystals

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Developing 500 MHz NB 19F-13C Double Resonance Solid-State NMR Probe for in-situ Analysis of Liquid Crystal Display Panels

  • Choi, Sung-Sub;Jung, Ji-Ho;Park, Yu-Geun;Park, Tae-Joon;Park, Gregory Hyung-Jin;Kim, Yong-Ae
    • Bulletin of the Korean Chemical Society
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    • v.33 no.5
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    • pp.1577-1580
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    • 2012
  • The orientational and dynamic behavior of liquid crystal molecules on the alignment layer surfaces of liquid crystal display (LCD) devices is crucial to their performance, but there are only a few methods of experimentally elucidating the interactions between the liquid crystals and the alignment layers. Inspired by the natural and technical similarities between membrane proteins in lipid bilayers and liquid crystals in LCDs, we employed solid-state NMR methodologies originally developed for the study of membrane proteins in lipid bilayers for the in-situ analysis of liquid crystal display panels. In this article, we present a home-built 500 MHz narrowbore (NB) The orientational and dynamic behavior of liquid crystal molecules on the alignment layer surfaces of liquid crystal display (LCD) devices is crucial to their performance, but there are only a few methods of experimentally elucidating the interactions between the liquid crystals and the alignment layers. Inspired by the natural and technical similarities between membrane proteins in lipid bilayers and liquid crystals in LCDs, we employed solid-state NMR methodologies originally developed for the study of membrane proteins in lipid bilayers for the in-situ analysis of liquid crystal display panels. In this article, we present a home-built 500 MHz narrowbore (NB) $^{19}F-^{13}C$ double resonance solid-state NMR probe with a flat-square coil and the first application of this probe for the in-situ analysis of LCD panel samples. double resonance solid-state NMR probe with a flat-square coil and the first application of this probe for the in-situ analysis of LCD panel samples.

Alignment of Nematic Liquid Crystals on Polyimide Surface Bombarded by $Ar^+$ Beam

  • Gwag, Jin-Seog;Lee, Seo-Hern;Park, Kyoung-Ho;Park, Won-Sang;Han, Kwan-Yougn;Yoon, Tae-Hoon;Kim, Jae-Chang;Kim, Hee;Cho, Seong-Jin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.409-412
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    • 2002
  • We found that polyimide surfaces bombarded by a low energy argon ion beam align liquid crystals. The pretilt angle of the liquid crystals is controlled by ion beam parameters, such as the energy of the incident ions, the angle of incidence, exposure time and current density. The alignment direction of liquid crystal on substrates corresponded to ion beam direction. By argon ion beam the pretilt angle of the liquid crystals was controlled between $0.5^{\circ}$ and $4^{\circ}$for SE-3140 under the proper conditons. By the atomic force microscope (AFM), polyimide surfaces before and after bombarded by ion beam are compared.

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Thermal and Electro-Optic Properties of a Side Chain Liquid Crystalline Polysilozanes cotaining a Low Molecuar Weight LIquid Crystal

  • Lee, Tae-Jeong;Kim, Eun-Yeong;Huh, Jae-Ho;Wang, Young-Soo;Kim, Han-Do
    • Proceedings of the Korean Fiber Society Conference
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    • 1997.10a
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    • pp.32-35
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    • 1997
  • Aggregation states ans electro-optic properties of a binary mixture by mixing a side chain type liquid crystalline polymer(LCP) and a low molecular weight liquid crystal(LMLC) have been studied. Side chain liquid crystalline polysiloxanes were synthesized from allyl bromide, p-hydroxy benzoic acid, p-cyanophenol, p-methoxyphenol and polysiloxanes. Low molecular weight liquid crystals were synthesized from allyl bromide, p-hydroxy benzoic acid and 4-cyano 4'-hydroxy biphenyl. And then, their properties were compared with blended liquid crystals. The thermal properties of the blended liquid crystals were evaluated using differential scanning calorimetry. The phase behavior of blended sample with temperature were also observed polarized microscope with hot stage. Thus, it seemed to us that a study of LC polysiloxanes with LMLC would be useful, especially in view of the fact that, systematic investigations have been carried out on the effects of changes in LCP/LMLC binary system on the properties of this relatively new type of liquid crystal.

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Cell thickness dependence of liquid crystal parameters

  • Sood, Nitin;Khosla, Samriti;Singh, Darshan;Bawa, S.S.
    • Journal of Information Display
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    • v.13 no.1
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    • pp.31-36
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    • 2012
  • Ferroelectric liquid crystal parameters, spontaneous polarization, and transition temperature were studied as a function of cell thickness. These parameters were found to increase with increasing cell thickness, but an exception was observed for the transition temperature in the case of a thin cell. A simple Landau model is presented to interpret the theoretical and experimental observations. The anomalous behavior is attributed to the electroclinic effect and is explained using the Landau model.

A Study of Thermotropic Liquid Crystal as a Potential Lubricant (액정의 윤활제 응용가능성 연구)

  • 안영재
    • Tribology and Lubricants
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    • v.4 no.1
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    • pp.30-35
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    • 1988
  • Liquid crystals have some tribologically favorable lameliar structure. The Performance of ther mottopic liquid crystal was investigated under elastohydrodynamic condition in terms of traction and film thickness. It exhibited low traction and very thin film thickness, which were almost constant over the entire speed range measured. It was also found to have sealing effect like grease. This work has shown that there exists "potential" for using liquid crystals as lubricants.

Carbon-Nanotube Doping in Liquid Crystals of Display Interest

  • Lee, Wei;Chen, Hui-Yu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.303-306
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    • 2007
  • Recent studies in the literature have shown that it is possible to overcome the limitations of the physical properties of liquid crystals by the doping of carbon nanotubes. Although still in its infancy, the potential of such a new approach for opportunities in display applications should not go unnoticed.

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Electro-optic Behavior of Photonic Crystals with Nematic Liquid-Crystal (액정을 이용한 광자결정의 형성과 전기광학 효과)

  • Kwon, Jang-Un;Han, Soon-Ku;Kang, Dae-Seung
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1933-1935
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    • 2002
  • In this paper, we present a study of the structure and electro-optic behavior of hybrid liquid-crystal-silica sphere composite photonic crystals, formed by filling the (26% by volume) void space of fee (face centered cubic) silica opals infiltrated with a nematic liquid crystal. Three dimensional photonic crystals of visible range were fabricated via a self assembly method of silica spheres of submicron diameter. The expected fee structure was confirmed by scanning electron microscopy (SEM) of the dehydrated crystal with glass removed. The photonic crystal exhibited significant electric-field-induced shift of the optical Bragg reflection peak when the liquid crystal has the long molecular axis oriented parallel to the sphere surfaces.

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Photo-alignment of Low-molecular Mass Nematic Liquid Crystals on Photochemically Bifunctional Chalcone-epoxy Film by Irradiation of a Linearly Polarized UV Light

  • Choi, Dong-Hoon;Cha, Young-Kwan
    • Bulletin of the Korean Chemical Society
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    • v.23 no.4
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    • pp.587-592
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    • 2002
  • Photocrosslinkable chalcone-epoxy compound comprising 1,3-bis-(4-hydroxy-phenyl)-propenone was synthe-sized for fabricating the photo-alignment layer of liquid crystals. Chalcone group was introduced into the main chain unit of the epoxy oligomer. We observed a photodimerization behavior and an optical anisotropy of this material by irradiation of a linearly polarized UV(LP-UV) light. With a trace amount of cationic photoinitiator (TRS-HFA), polymerization of epoxy groups was also conducted at the similar wavelength range used for photodimerization. Linearly polarized UV irradiation on the chalcone-epoxy films with cationic photoinitiator induced optical anisotropy of the film and the resultant film can be used for alignment layers for low molecular weight nematic liquid crystals.

Improvement of Accuracy in Evaluating Hue Change Time in the Hue Detection Based Transient Liquid Crystals Technique (색상 검출방식의 천이 액정법에서 색상 변화 시간 산정의 정확도 향상)

  • Shin, So-Min;Jeon, Chang-Soo;Jung, Yong-Wun;Kwak, Jae-Su
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.11
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    • pp.918-925
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    • 2007
  • In this paper, different criteria fur determining hue change time in the hue detection based transient liquid crystals technique were compared. Results showed that methods utilizing threshold of intensity or saturation gave many missing points and quality of the calculated results were strongly depends on the value of threshold. Wider bandwidth in the hue bandwidth method showed better distribution of calculated hue change time, but induced ambiguity in the hue change time. In the time-hue curve fitting method, the distribution of evaluated hue change time was smooth and reasonable, and, by the nature of curve fitting, the noise effect on the hue was successfully considered in calculating of the hue change time. Compared to other methods, it is expected that the time-hue curve fitting method would provide better and accurate hue change time in the hue detection based transient liquid crystals technique.