• 제목/요약/키워드: Liquid Crystals

검색결과 442건 처리시간 0.034초

감광성 도판트를 이용한 풀컬러 구현 가능 반사형 콜레스테릭 액정 (Full Color Reflective Cholesteric Liquid Crystal using Photosensitive Chiral Dopant)

  • 박서규;김정수;조희석;권순범;유리레즈니코프
    • 한국전기전자재료학회논문지
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    • 제21권5호
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    • pp.474-480
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    • 2008
  • In order to make full color cholesteric displays, color filter-less R, G, B sub-pixel structured cholesteric LC cells have been studied. To make R, G, B colors, UV induced pitch variant chiral dopant was added to cholesteric LC mixtures. The concentration of the photo-sensitive chiral dopant was adjusted so that the initial state showed blue color and the color was changed from blue to green and red with increase of UV irradiation to the cholesteric cells. To prevent the mixing of R, G, B reflective sub-pixel liquid crystals, separation walls were formed using negative photo resister in boundary area between sub-pixels, Through the optimization of the material concentrations and UV irradiation condition, vivid R, G, B colors were achieved.

고굴절 네마틱 액정에서의 액정 디스플레이의 고속응답 특성 (Fast Response Characteristics in Liquid Crystal Display in the High birefringence nematic liquid crystal)

  • 김종환;황정연;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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    • pp.498-501
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    • 2003
  • We investigated response characteristics of twisted nematic (TN) cell with different nematic liquid crystals (NLCs) and cell gap d on a rubbed polyimide (PI) surface. High transmittance and fast response time of the TN cell on the rubbed PI surface were achieved by using high birefringence (${\Delta}n$) and low cell gap d. The transmittance and response time of the TN cell on the rubbed PI surface decreased with decreasing ${\Delta}nd$. The fast response time of TN cell using high birefringence with ${\Delta}nd=0.363$ on the rubbed PI surface was measured 5.1 ms.

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고전하밀도 양이온성폴리머와 Sodium dodecyl sulfate가 만드는 콤플렉스에 대한 비이온계면활성제의 영향 (The transformation of the complex of high charge density cationic polymer with sodium dodecyl sulfate into vesicles by nonionic surfactant)

  • 이정노;강계홍
    • 한국응용과학기술학회지
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    • 제25권2호
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    • pp.205-210
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    • 2008
  • The transformation of the liquid crystal complex made by binding of anionic surfactant, sodium dodecyl sulfate (SDS), into high charge density cationic polymer, the homopolymer of diallyldimethylammonium chloride (PDADMAC) was induced by adding of nonionic surfactants and investigated by means of microscopy and FE.SEM. Among nonionic surfactants in this experiments polyethylene glycol (3 mol) ether of lauryl alcohol (laureth-3) made variation in the complex. The laureth-3 transformed the complex into spherulite vesicle with the size of ca.$100{\mu}m$. This change increased the viscosity and the turbidity of the solution phase separated originally. Microscope showed that they are spherulite particles and polarized microscope suggested they are multi.lamellar liquid crystals. FE-SEM also proved that explicitly.

2-Dimensional colloidal micropatterning of cholesteric liquid crystal microcapsules for temperature-responsive color displays

  • Lee, Woo Jin;Kim, Bohyun;Han, Sang Woo;Seo, Minjeong;Choi, Song-Ee;Yang, Hakyeong;Kim, Shin-Hyun;Jeong, Sohee;Kim, Jin Woong
    • Journal of Industrial and Engineering Chemistry
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    • 제68권
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    • pp.393-398
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    • 2018
  • This work offers a promising approach for development of a temperature-responsive colorimetric display platform. For this purpose, uniform thermochromic microcapsules consisting of a cholesteric liquid crystal (CLC) core and a thin polyurethane shell layer were fabricated by conducting in-situ condensation polymerization at the interface of monodisperse CLC-in-water emulsion drops. Colloidal packing-driven microcapsule registry led to exact 2-dimensional positioning of CLC microcapsules into a holes-patterned flexible film stencil. Furthermore, we showed that the designated registry of different color types of CLC microcapsules on the stencil enabled development of a microwriting display technology capable of reversible text representation according to temperature change.

Molecular Dynamics Simulation Studies of a Model System for Liquid Crystals Consisting of Rodlike Molecules in NPT Ensemble

  • 이창준;심훈구;김운춘;이송희;박형숙
    • Bulletin of the Korean Chemical Society
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    • 제21권3호
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    • pp.310-316
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    • 2000
  • Molecular dynamics simulation studies for thermotropic liquid crystalline systems conposed of rodlike molecules with 6 Lennard-Jones interaction sites wre performed in NPT ensemble. Within the range of temperature studied, the system exhibited isotropic and smectic phase. For the characterization of the smectic phase, we examined the structure of the liquid crystalline phase via the radial distribution function, its longitudinal and transverse components to the director, and other orientational correlation function, its longitudinal and transverse components to the director, and other orientational correlation functions. In the smectic A phase, our results showed a large anisotropy in translational motion (i.e.,$D_⊥ >> D_∥$), and the decay of the collective orientational correlation function of rank two became slower than that of the single particle orientational correlation function of rank one. Comments on the spontaneous growth of orientational order directly from the isotropic phase are given.

나노 크기 칼슘-실리케이트-하이드레이트(C-S-H) 결정이 시멘트 수화에 미치는 영향 분석 (Effect of Nano-sized Calcium-silicate-hydrate (C-S-H) Crystals on Cement Hydration)

  • 김경태;우수지;유성원;최영철
    • 한국건설순환자원학회논문집
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    • 제11권2호
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    • pp.153-160
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    • 2023
  • 본 연구에서는 액상반응법을 이용하여 나노 크기의 C-S-H 결정을 합성하고 그 특성을 조사하였다. 합성한 C-S-H 결정을 현탁액 형태로 시멘트 복합체에 첨가하여 시멘트의 수화특성에 미치는 영향을 확인하였다. 최적 응집 형태의 나노 크기 C-S-H 결정을 도출하기 위해 화학혼화제의 양을 변수로 제조하였으며, SEM 사진 분석을 하였다. 합성된 C-S-H 결정외 유해물질을 제거하기 위해 세척 과정을 추가하였다. 세척과정을 거친 C-S-H 결정의 경우 유해물질의 농도가 낮아짐을 확인하였다. 합성된 C-S-H 현탁액은 세척 과정 유무에 따라 제조하였으며, 시멘트 중량대비 함유량을 주요 변수로 하여 시멘트 복합체를 제조하였다. 미소수화열 분석을 통해 C-S-H 결정이 시멘트의 초기 수화특성에 미치는 영향을 확인하였다. 또한, 모르타르 시험체를 제작하여 시간에 따른 압축강도를 측정하였다. 실험결과 나노 크기의 C-S-H 결정이 시멘트 페이스트 내에서 핵 생성처 역할을 하여 시멘트의 초기 수화를 촉진시키며, 초기 압축강도 또한 증가하는 것을 확인하였다.

액상 및 반고체배지 발효에 의한 Bacillus thuringiensis 살충제의 제조 (Formulations of Bacillus thuringiensis Insecticides by Liquid and Semi-Solid Fermentations.)

  • 이형환
    • 한국미생물·생명공학회지
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    • 제26권4호
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    • pp.369-372
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    • 1998
  • Microbial insecticide formulations were prepared by liquid and semi-solid fermentations using Bacillus thuringiensis subsp. kurstaki, HL-106 (BTK-HL106), B. thuringiensis subsp. israelensis HL-63 (BTI-HL63) and B. sphaericus 1593 (BS-1593) strains. The liquid fermentation medium contained molasses 2%, dextrose 1.5%, peptone 2%, D-xylose 0.025%, CaCl$_2$ 0.1%, K$_2$HPO$_4$ 0.1%, KH$_2$PO$_4$ 0.1%, MgSO$_4$$.$7H$_2$O 0.03%, FeSO$_4$$.$7H$_2$O 0.002%, ZnSO$_4$$.$7H$_2$O 0.02%. The composition of the semi-solid fermentation medium was rice bran 45.2%, zeolite 31%, yeast powder 0.02%, corn powder 5%, dextrose 3%, lime 0.3%, NaCl 0.06%, CaCl$_2$ 0.02%, and H$_2$O 15.42%. Insecticide formulations produced in the liquid fermentation named BTK-HL106, BTI-HL63 and BS-1593 pesticides and those in the semi-solid fermentation were designated as BTK-HL106-1, BTI-HL63-1 and BS-1593-1 pesticides, respectively. The number of spore (endotoxin crystals) was 2.65${\times}$10$\^$9/ spores per $m\ell$ in the BTK-HL106 and 3.5${\times}$10$\^$10/ in the BTK-HL106-1 3.8${\times}$10$\^$9/ spores in the BTI-HL63 and 7.0${\times}$10$\^$10/ in the BTI-HL63-1, and 7.5${\times}$10$\^$9/ in the BS-1593 and 1.4${\times}$10$\^$10/ in the BS-1593-1. The spores in the BS-1593 formulation was produced two times more than the other formulations. The spores in the BTI-HL63-1 were contained twice than those in the BTK-HL106-1, and five times than those in the BS-1593-1. The results indicated that spore (endotoxin crystals) productions in the semi-solid fermentation increased about ten times than those in the liquid fermentations. $LC_{50}$s of the BTI-HL63 and BS-1593 were 4.5 $\mu\textrm{g}$, and those of the BTI-HL63-1 and BS-1593-1 were 1.5 $\mu\textrm{g}$. $LC_{50}$ of the BTK-HL106 was 1.5 mg and that of the BTK-HL106-1 was 0.9 mg. The $LC_{50}$s of the formulations in the semi-solid fermentations showed about two to three times higher than those in the liquid fermentations.

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액상환원침전법 및 수열반응법을 이용한 주석산화물 결정 합성에 관한 연구 (A study on the synthesis of tin oxide crystalline by the liquid reduction precipitation method and hydrothermal process)

  • 박일정;김건홍;김대원;최희락;정항철
    • 한국결정성장학회지
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    • 제26권3호
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    • pp.95-100
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    • 2016
  • 본 연구에서는 염화주석, 하이드라진 그리고 수산화나트륨을 원료로 하여 용액환원침전법과 수열반응법을 이용하여 주석산화물 결정을 제조하여, 주요 실험 변수에 의한 결정상 및 형상을 XRD와 SEM을 이용하여 분석하였다. 원료의 몰 비에 따라 구형 및 판상의 주석산화물 결정을 얻을 수 있었으며, 그 결정상은 SnO, $Sn_6O_4(OH)_4$이었다. 그리고 수열반응법에 의하여 얻어진 결정 모양은 온도 조건에 따라 판상 및 꽃 모양의 SnO 결정이 얻어졌다.

양의 액정을 이용한 FFS모드에서 Splay Elastic Constant에 따른 전기-광학적 특성 연구 (Splay Elastic Constants Dependent Electro-Optic Characteristics of the Fringe Field Switching (FFS) Mode using the Liquid Crystal with Positive Dielectric Anisotropy)

  • 정준호;박지웅;안영주;김미영;이희규;이승은;이승희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.469-470
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    • 2008
  • We have studied electro-optic characteristics as a function of splay elastic constants ($K_{11}$) in the fringe-field switching (FFS) mode using the LC with positive dielectric anisotropy. When $K_{11}$ is increased from 7.7pN to 11.7pN, a maximum transmittance is slightly increased and rising time become a little bit fast. However, operating voltage and threshold voltage is independent. In opposition to rising time, decay time is not affected by $K_{11}$. We already know that $K_{11}$ affects tilt angle of liquid crystals. Therefore, on the occasion of high $K_{11}$, liquid crystals are mainly affected by twist deformation because the higher $K_{11}$, the less tilt angle. In the FFS device, high $K_{11}$ is favorable to reduce tilt angle in on state and thus improve rising response time.

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포토닉 밴드갭 광결정의 제작과 선형 및 비선형 광학 특성 연구 (Fabrication and Linear & Nonlinear Optical Characterization of Photonic Crystals)

  • Ha Na Yeong;U Yeon Gyeong;Hwang Ji-Su;Jang Hye-Jeong;Park Byeong-Ju;U Jeong-Won
    • 한국광학회:학술대회논문집
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    • 한국광학회 2002년도 하계학술발표회
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    • pp.162-163
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    • 2002
  • 1-D photonic band-gap structure is identified in a cholesteric liquid crystal system. The optical transmission spectrum is measured and compared with the theoretical analysis. Nonlinear transmission is measured near the band edge. Also 3-D photonic band-gap structures are fabricated from dielectric colloidal polystyrene beads through a centrifuge method. The fabricated photonic crystals exhibit opalescent colors under white light and show a clear diffraction peak dependent on the incident angle of the light beam. Also the scanning electron microscope image was taken to verify the face-centered cubic crystal structure. Bragg's law and Snell's law are employed to describe the position of angle resolved diffraction peaks. It was shown that the optically deduced effective refractive index and lattice constants were in good agreement with the crystal structure identified by scanning electron microscope.

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