• 제목/요약/키워드: Liquid Crystal Orientation

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Fast Abnormal Grain Growth Behavior and Electric Properties of Lead-Free Piezoelectric (K,Na)NbO3-Ba(Cu,Nb)O3 Grains through Transient Liquid Phase (과 액상 형성에 의한 비납계 압전 (Na,K)NbO3-Ba(Cu,Nb)O3 결정립의 비정상 성장 거동 및 전기적 특성)

  • Lim, Ji-Ho;Lee, Ju-Seung;Lee, SeungHee;Jung, Han-Bo;Park, Chun-kil;Ahn, Cheol-Woo;Yoo, Il-Ryeol;Cho, Kyung-Hoon;Jeong, Dae-Yong
    • Korean Journal of Materials Research
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    • 제29권4호
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    • pp.205-210
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    • 2019
  • $Pb(Zr,Ti)O_3$ (PZT) is used for the various piezoelectric devices owing to its high piezoelectric properties. However, lead (Pb), which is contained in PZT, causes various environment contaminations. $(K,Na)NbO_3$ (NKN) is the most well-known candidate for a lead-free composition to replace PZT. A single crystal has excellent piezoelectric-properties and its properties can be changed by changing the orientation direction. It is hard to fabricate a NKN single crystal due to the sodium and potassium. Thus, $(Na,K)NbO_3-Ba(Cu,Nb)O_3$ (NKN-BCuN) is chosen to fabricate the single crystal with relative ease. NKN-BCuN pellets consist of two parts, yellow single crystals and gray poly-crystals that contain copper. The area that has a large amount of copper particles may melt at low temperature but not the other areas. The liquid phase may be responsible for the abnormal grain growth in NKN-BCuN ceramics. The dielectric constant and tan ${\delta}$ are measured to be 684 and 0.036 at 1 kHz in NKN-BCuN, respectively. The coercive field and remnant polarization are 14 kV/cm and $20{\mu}C/cm^2$.

Liquid Crystal orientation on the NDLC Thin Film Deposited using physical deposition method (PVD방식을 이용한 NDLC 박막에서의 액정 배향 효과)

  • Lee, Won-Kyu;Oh, Byoung-Yun;Lim, Ji-Hun;Na, Hyun-Jae;Lee, Kang-Min;Park, Hong-Gyu;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.301-301
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    • 2008
  • Ion beam (IB)-induced alignment of inorganic materials has been investigated intensively as it provides controllability in a nonstop process for producing high-resolution displays[1][2]. LC orientation via ion-beam (IB) irradiation on the nitrogen doped diamond like carbon (NDLC) thin film deposited by physical deposition method-sputtering was embodied. The NDLC thin film that was deposited by sputter showed uniform LC alignment at the 1200eV of the ion beam intensity. The pretilt angle of LC on NDLC thin films was measured with various IB exposure time and angle. The maximum pretilt angle were showed with IB irradiation angle of $45^{\circ}$ and exposure time of 62.5 sec, respectively. To show NDLC thin film stability in high temperature, thermal stability test was proceeded. The uppermost of the thermal stability of NDLC thin film was $200^{\circ}C$. In this investigation, the electro-optical (EO) characteristics of LC on NDLC thin film were measured.

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Crystal Growth and Characterization of Metallurgical-grade Polycrystalline Silicon by the Bridgman Method (Bridgman법에 의한 금속급 다결정 Si의 결정성장 및 특성평가에 관한 연구)

  • Lee, Chang-Won;Kim, Kye-Soo;Hong, Chun-Pyo
    • Journal of Korea Foundry Society
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    • 제14권1호
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    • pp.28-34
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    • 1994
  • Metallurgical-grade polycrystalline silicon was directionally solidified at growth rates of $0.2{\sim}1.0mm/min$ by using split type, reusable graphite molds which were coated with $Si_3N_4$ powder. The resultant grain sizes of the silicon ingots and the shapes of the solid/liquid(S/L) interfaces were investigated. X-ray diffraction was used to determine the preferred orientation in each of the silicon ingots. The impurity content of the silicon was analyzed and the resistivities of the ingots were measured. During the growth of an ingot, the shape of the S/L interface was concave to the silicon melt, and the resistivity decreased. The presence of Al which can be acting as a carrier, is thought to be the main factor causing such a decrease in resistivity. When a growth rate of 0.2㎜/min was used, the preferred orientation was found to be (111).

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Thermotropic Liquid Crystal Polymer or Silica Nano-particle Filled Polyester Composite Fibers

  • Kim, Seong-Hun;Kim, Jun-Young;Ahn, Seon-Hoon
    • Proceedings of the Korean Fiber Society Conference
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.65-66
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    • 2003
  • Ternary blend fibers (TBFs) based on melt blends of PEN, PET, and TLCP were prepared by melt blending and spinning to achieve high performance fibers. The reinforcement effect and the TLCP fibrillar structure resulted in the improvement of mechanical properties for TBFs. Molecular orientation was an important factor in determining the tensile strength and modulus of TBFs. Another part of this research is silica nano-particle filled PEN composites were melt-blended to improve mechanical and physicalproperties, and processability. The tensile modulus and strength were improved adding silica nano-particles to the PEN. The decreased melt viscosity by the fumed silica resulted in the improvement of the processability. The fumed silica may act as a nucleating agent in the PEN matrix.

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Effects of Polarity of the Orientation Film for Electro-optical Characteristics on a-TN-LCD (배향막의 극성이 a-TN-LCD의 전기광학특성에 미치는 효과)

  • 서대식;이창훈;이보호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 한국전기전자재료학회 1997년도 춘계학술대회 논문집
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    • pp.27-30
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    • 1997
  • We investigated the electro-optical characteristics of amorphous (a) - twisted nematic (TN) - liquid crystal display (LCD) on polyimide (Pl) films with different polarity. It was found that the threshold voltage of a-TN-LCD is decreased with increasing the polarity of the Pl film. We considered that the threshold voltage in a-TN-LCD is affected to the surface anchoring strength with polarity of the Pl films. Also, we observed the response time of a-TN-LCD on medium polarity of the Pl film is fast compared to high polarity of the Pl film. Finally, we obtained that the viewing angle of a-TN-LCD are almost same on different polarity of the PI films.

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Study on Electro-opt ic Characteristics in the Optically Compensated Splay Cell with UV-curable Reactive Mesogen

  • Kim, Seong-Su;Jeon, Eun-Jeong;Lee, Myong-Hoon;Lee, Seung-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.327-329
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    • 2008
  • We have studied the optically compensated splay (OCS) mode using reactive mesogen monomer to reduce critical voltage, setting voltage and phase transition time from initial bend to splay state. The high pretilt angle from vertical alignment was formed through the polymerization of UV curable RM monomer at the surfaces. In this way, orientation of the LC with OCS can be achieved without setting voltage.

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Method for determining the orientation of extraordinary axis direction Twisted-Nematic Liquid Crystal Spatial Light Modulator (꼬인 네마틱 액정 공간 광 변조기의 이상 굴절 축 회전 방향 결정 방법)

  • 조규보;김수중
    • Proceedings of the Korea Society for Industrial Systems Conference
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    • 한국산업정보학회 2004년도 춘계학술대회 21세기 IT산업의 발전 전망
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    • pp.85-88
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    • 2004
  • 광 정보 처리 특성을 극대화하기 위해 실시간 동작이 가능한 공간 광 변조기를 사용하며 그중 액정 화면은 기존의 공간 광 변조기에 비해 가격이 저렴하고 특히 꼬인 네마틱 액정 화면 공간 광 변조기는 전기 신호에 따라 광을 변조 할 수 있다는 원리에 의해 여러 가지 이론과 설계 방법이 연구되었으며 기본 매개 변수들을 효과적으로 계산하는 방법이 계속 발표되었다. 본 논문에서는 원형 편광 된 광을 꼬인 네마틱 결정을 갖는 공간 광 변조기에 투사 시켜서 검광기에 통과한 세기 분포를 관찰하여 이상 굴절 축의 회전 방향을 결정하는 방법을 제안하였으며, 존스 행렬을 사용하여 수학적 타당성을 부여하였다.

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Deposition conditions of $YBa_{2}$$Cu_{3}$$O_{7-x}$ deposited by a MOCVD method for coated conductors (MOCVD 법에 의해 증착 된 coated conductor용 $YBa_{2}$$Cu_{3}$$O_{7-x}$의 증착조건)

  • 선종원;전병혁;김찬중
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 한국초전도저온공학회 2003년도 추계학술대회 논문집
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    • pp.83-86
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    • 2003
  • YBa$_2$Cu$_3$$O_{7-x}$ thin films for coated conductor application were deposited on a MgO single crystalline substrate by a metal organic chemical vapor deposition (MOCVD) system of a vertical type using a single liquid source. The film uniformity was enhanced by controlling the gas shower head structure, the distance between the shower head and substrate, and the rotation of the substrate. The source mole ratio of Y(thd)$_3$: Ba(thd)$_2$: Cu(thd)$_2$ was changed for obtaining stoichiometric film. The phase formation, crystal orientation, surface morphology and film composition were investigated with different source mole ratios, and the critical temperature (T$_{c}$) was measured.red.

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Detailed Investigation on Factors Governing Liquid Crystal Alignment on Rubbed Polystyrene Films

  • Hahm, Seok-Gyu;Lee, Taek-Joon;Lee, Seung-Woo;Yoon, Jin-Hwan;Kim, Gha-Hee;Chang, Tai-Hyun;Ree, Moon-Hor
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.899-902
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    • 2004
  • The molecular reorientations and surface morphologies of rubbed films formed from atactic polystyrene (PS) samples with various molecular weights were investigated in detail. Previously unknown surface topography features were newly discovered in rubbed films, depending on molecular weights: submicroscale groove-like meandering structures composed of fine-grooves like pebbles in tens nanometers are present, oriented perpendicular to the rubbing direction. The vinyl main chains, however, were preferentially reoriented along the rubbing direction and the planes of the phenyl side groups were preferentially reoriented perpendicular to the rubbing direction with para-directions that were positioned nearly normal to the film plane. Nematic liquid crystal (LC) molecules were found to always align on the rubbed PS surfaces along the orientation direction of the submicroscale grooves generated by rubbing.

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A study on the electrical and mechanical properties of PEMFC bipolar plate by thermoplastic composite injection molding process (열가소성 복합소재를 이용하여 사출성형 한 PEMFC용 bipolar plate의 전기전도도 및 기계적 특성 연구)

  • Yoon, Yong-Hun;Kim, Dong-Hak
    • Journal of the Korea Academia-Industrial cooperation Society
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    • 제12권4호
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    • pp.1999-2004
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    • 2011
  • This research aims to develop polymer composites which can be used for PEMFC bipolar plate by injection molding process. Considering the moldability and stiffness, we used LCP(Liquid crystal polymer) as base resin. In order to improve electrical conductivity and mechanical properties, we chose carbon black, and both synthetic graphite and expanded graphite. The composites with different recipe are prepared for injection molding of PEMFC bipolar plate and CAE(Computer Aided Engineering) analysis was performed to predict melt flow and fiber orientation We did successfully fabricate the ASTM specimens by injection molding, and measure the electrical conductivity of the samples by using four point probe device. We measured mechanical properties such as flexural strength, flexural modulus and Izod impact strength. Conclusively, the electrical conductivity increased with increasing additive concentration, but both flexural strength and Izod impact strength decreased due to the brittle nature of carbon-based additives.