• 제목/요약/키워드: Liquid Crystal Mixture

검색결과 95건 처리시간 0.023초

에멀전 방식의 고분자 분산형 액정의 전기 광학 특성에 미치는 액적 크기 분포의 영향 (Droplet Size Distribution Effect on the Electro-Optical Properties of Emulsion Type Polymer Dispersed Liquid Crystal)

  • 유희상;오남석;김안;권순범
    • 한국전기전자재료학회논문지
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    • 제28권7호
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    • pp.439-445
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    • 2015
  • We established the emulsion method using membrane filter with precise control of LC droplet distribution in PDLC. PDLC cells with various LC droplet size distributions such as single droplet sizes of $1.0{\mu}m$, $1.9{\mu}m$ and $3.5{\mu}m$, the mixture of two different LC droplet sizes and the mixture of three different LC droplet sizes were fabricated and the electro-optical properties of the emulsion type PDLC cells with various droplet size distribution were investigated. In the appropriate droplet size range, the PDLCs with the single droplet sizes distributions have good electro optical properties than those with the mixture of three different LC droplet sizes. In addition, the PDLC cells with the mixture of two different LC droplet sizes have the better electro optical properties than those with single droplet sizes distribution. The PDLC cell with dual droplet size distribution of $1.0+1.9{\mu}m$ shown the best electro optical properties than the PDLC cells with other size distributions. This method enabled us to find the proper LC droplet size distribution for achieving both high transmittance and contrast ratio.

Electro-optical Characterization of Transmission Holographic PDLC with Surfactant

  • Woo, Ju-Yeon;Kim, Eun-Hee;Kim, Byung-Kyu
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.1204-1207
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    • 2004
  • The effects of surfactant on the electro-optic properties of holographic polymer dispersed liquid crystal(HPDLC) have been studied hoping to increase the diffraction efficiency and to reduce the anchoring energy at interfaces. Octanoic acid(OA) was used as sulfactant. The 2,2,2 trifluoroethyl acrylate(TFEA) was added to the monomer mixture to enhance the phase separation and improve optical properties. The morphology of holographic gratings was examined using scanning electron microscopy(SEM). Addition of surfactant was likely to reduce the surface anchoring of the nematic droplet with the polymer surface which favors lowering of the swiching field and to improve the optical qualities.

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매월장석광산(梅月長石鑛山)의 페그마타이트내(內) 유체포유물(流體包有物)과 그 성인(成因)에 관한 모델 연구 (Study on Fluid Inclusion and Genetic Modelling of Pegmatites at the Maewol Feldspar Mine)

  • 문건주
    • 자원환경지질
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    • 제21권4호
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    • pp.381-387
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    • 1988
  • Maewol Feldspar Mine produces feldspar ore from pegmatites. K-Rb Age of muscovite is 137.7Ma. Fluid inclusions in quartz crystal of the pegmatite show bimodal distribution of homogenization temperatures. The high homogenization temperatures range from 290 to $302^{\circ}C$ while low homogenization temperatures range from 157 to $195^{\circ}C$. Three phases liquid $CO_2$ bearing inclusions indicate $CO_2$ gases were abundantly mixed with granitic melt until the pegmatic magma melt cooled to $290^{\circ}C$. Low density of the magmatic melt relative to the same volume of granitic magma is due to mixture of volatiles(mainly $CO_2$ gases) with the melt and larger space and slow cooling allowed to grow crystals of the pegmatic magma.

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액정디스플레이 후판광원용 평판형 수은 형광램프의 2차원 시뮬레이션 연구 (Two-Dimensional Simulation of Hg Flat Fluorescent Lamps for an LCD Backlight unit)

  • 윤현진;이해준
    • 전기학회논문지
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    • 제56권7호
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    • pp.1275-1281
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    • 2007
  • The discharge phenomena in a flat fluorescent lamp for the backlight unit of liquid crystal displays are simulated by sung a two-dimensional fluid model. The numerical methods for the calculation of plasma dynamics and the radiation transport are introduced for the discharge simulation and for the transmission of the vacuum ultraviolet lights. The simulation results are presented to compare the luminance and the luminance efficacy with the variation of gas pressure, gas mixture ratio, driving voltage, and frequency.

Substrate bonding technique using the agar-epoxy composites for flexible LCD

  • Bae, Ji-Hong;Jang, Se-Jin;Choi, Hong;Kim, Sang-Il;Kim, Jae-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.733-736
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    • 2007
  • We have proposed novel bonding technique of substrates for developing the flexible LCD with high quality. The gel type mixture of agarose and UV curable epoxy developed to obtain tight bonding ability and enhanced electro-optical characteristic simultaneously. This technique can be used to roll-to-roll process for fabricating the flexible LCDs.

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스프레이 코팅법으로 제조된 CNT/PVDF 압전 복합막의 자기분극 메커니즘 (Self-poling Mechanism of CNT/PVDF Piezoelectric Composite Films Prepared by Spray Coating Method)

  • 이선우
    • 한국전기전자재료학회논문지
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    • 제26권7호
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    • pp.550-554
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    • 2013
  • Carbon nanotubes (CNT) / polyvinylidene fluoride (PVDF) piezoelectric composite films for nanogenerator devices were fabricated by spray coating method. When the CNT/PVDF mixture solution passes through the spray nozzle with small diameter by the compressed nitrogen gas, electric charges are generated in the liquid by a triboelectric effect. Then randomly distributed ${\beta}$ phase PVDF film could be re-oriented by the electric field resulting from the accumulated electrical charges, and might be resulted in extremely one-directionally aligned ${\beta}$ phase PVDF film without additional electric field for poling. X-ray diffraction patterns were used to investigate crystal structure of the CNT/PVDF composite films. It was confirmed that they revealed extremely large portion of the ${\beta}$ phase PVDF crystalline in the film. Therefore we could obtain the poled CNT/PVDF piezoelectric composite films by the spray coating method without additional poling process.

오존수를 이용한 감광막 제거 공정에 관한 연구 (A Study on Photoresist Strip Process using DIO3)

  • 채상훈;손영수
    • 한국전기전자재료학회논문지
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    • 제17권11호
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    • pp.1143-1148
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    • 2004
  • In this study, photoresist stripping in semiconductor or LCD (liquid crystal display) fabrication processes using DIO, was investigated. In order to obtain the high PR stripping efficiency of DIO. we have developed new ozone-generating system with high ozone concentration and ozone-resolving system with high contact ratio. In this study, we obtained ozone gas concentrations of 11 % by new ozone-generating system, ozone-resolving efficiency of 99.5 % and maximum solubility of 130 ppm in deionized water. We applied the newly designed equipments to photoresist stripping processes and obtained similar results to SPM(sulfuric-peroxide mixture) process characteristics.

The pH Effect on the Preparation of MFI Type Ferrisilicate Zeolites

  • 염영훈;남상성;김성보;이규완
    • Bulletin of the Korean Chemical Society
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    • 제20권7호
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    • pp.781-785
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    • 1999
  • Ferrisilicates with MFI type structure were hydrothermally synthesized. The structural environments of iron in the ferrisilicates were characterized by XRD, SEM, IR, EPR, and ammonia-TPD. It has been shown that pH of the final gel mixture during the synthesis affects the crystal size, morphology, chemical composition and catalyticactivity. The results of the lattice parameters, IR, and EPR indicate the existence of a framework iron and the content of framework iron depends on pH of the synthesis gel. Finally, the catalytic activity of these zeolites was examined for the cyclohexane oxidation to cyclohexanol and cyclohexanone in the liquid phase. The conversion of this reaction was increased with increasing iron content of the framework lattice positions.

접촉분해경유에 함유된 2,6-dimethylnaphthalene의 분리, 정제(I) -접촉분해경유에 함유된 dimethylnaphthalene이성체 혼합물의 농축- (Separation and Purification of 2,6-dimethylnaphthalene in the Light Cycle Oil(I) -Concentration of a mixture of dimethylnaphthalene isomers in the light cycle oil-)

  • 김수진;김상채;카와사키, 준지로
    • 공업화학
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    • 제7권1호
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    • pp.162-170
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    • 1996
  • 접촉분해경유(Light Cycle Oil : LCO)중에는 엔지니어링 플라스틱 및 고분자 액정 등의 기초 원료로서 각광 받고 있는 2,6-dimethylnaphthalene(2,6-DMNA)이 함유되어 있다. 본 연구는, LCO중에 함유된 2,6-DMNA의 분리, 정제를 위한 전처리조작으로서 LCO중에 함유된 dimethylnaphthalene(DMNA)이성체 혼합물의 농축을 추출-증류의 조합에 의해 실험적으로 검토했다. 또, LCO중에 함유된 DMNA이성체 혼합물의 농축에 대한 증류와 추출-증류의 조합을 비교, 검토하였다. Dimethylsulfoxide수용액을 용매로 사용한 회분병류 5회 평형추출로서 LCO중에 함유된 방향족 성분을 회수한 결과, 회수된 추출유중의 나프탈렌류 성분(탄소수 : 10-12)의 농도는 LCO중의 나프탈렌류 성분의 그것에 비해 높았으며, 나프탈렌류 성분의 수율은 탄소수가 작은 성분일수록 컸다. 5회 평형추출에 의한 DMNA이성체 혼합물의 회수율은 65wt%이었다. 추출유의 회분증류로서 얻어진 DMNA을 함유한 유출액을 재차 회분증류함으로서 60wt%의 고농도 DMNA이성체 혼합물을 함유한 유출액의 회수가 가능했다. LCO중에 함유된 DMNA이성체 혼합물의 농축에는 LCO의 직접증류보다 추출-증류의 조합이 더 효과적이었다.

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Rheological Behavior of Lyotropilc Solutions of Cellulose in the $NH_3/NH_4SCN$ Solvent System

  • Jo, Jae-Jeong;Cuculo, J.A.;Theil, M.H.
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1990년도 제2차 학술발표초록집
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    • pp.36-37
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    • 1990
  • In the past, facile dissolution of cellulose has been hampered by the lack of suitable nondegrading solvents. Recently, this problem has been solved in our laboratory by the discovery of an inexpensive, convenient solvent system, that is the mixture of $NH_3\;and\;NH_4SCN$, for cellulose. Also, the $cellulose/NH_3/NH_4SCN$ solution system has been found to form the anisotropic, i.e., liquid crystalline phase. It is believed that both the cholesterio and the nematic phase occur. This finding has prompted extensive on-going researoh on the formation of the liquid crystalline phase from an inexpensive natural source such as cellulose since the nematic phase is envisioned as an excellent precursor sources for products with desirable properties, for example, high modulus and high strength. This interest naturally leads to a desire to understand the theological properties of the nematic phase so that the transformation of the nematic phase to the solid state with desirable properties can be efficiently accomplished, ;From this point of view, the theological behavior of the $cellulose/NH3_/NH_4SCN$ system has been studied as a function of shear rate and shear stress over a wide range of solvent compositions, cellulose concentration, centrifugation and urea contents, Results indicate that the viscosity decreases with increasing shear rate. A marked shear thinning behavior and a quasi-Newtonian behavior were observed in the low shear rate region and in the high shear rate region, respectively for all solvent compositions. The $cellulose/NH_3/NH_4SCN$ solution system only exhibited the viscosity increase with increasing cellulose concentration and failed to show the viscosity drop generally observed at the point of incipience of liquid crystal formation, This may be due to the gel-like nature of the solution by the association of the rodlike molecules into bundles which may serve as crosslinking points giving the cellulose solution a network structure. Also, simply hydrogen bonding may be so restrictive of molecular mobility that a viscosity drop is blocked. In addition to the above results, yield stress and thixotropy were also observed in the $cellulose/NH_3/NB_4SCN$ solution system which are characteristics of liquid crystal and gel, The results of the effect of centrifugation on viscosity show that viscosity decreases by the application of centrifugation. This may be explained by the change of the piled polydomain structure to the dispersed polydomain structure due to the pressure gradient generated during centrifugation.ation.

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