• Title/Summary/Keyword: Limiting diffusion

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Product Phase Control During Interdiffusion Reactions (상호 확산 반응 중의 생성상 제어)

  • Park, Joon-Sik;Kim, Ji-Hoon;Perepezko, John R.
    • Journal of Korea Foundry Society
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    • v.26 no.1
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    • pp.27-33
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    • 2006
  • Phase evolutions involving nucleation stages together with diffusional growth have been examined in order to provide a guideline for determining rate limiting stages during phase evolutions. In multiphase materials systems in coatings, composites or multilayered structures, diffusion treatments often result in the development of metastable/intermediate phases at the reaction interfaces. The development of metastable phases during solid state interdiffusion demonstrates that the nucleation reaction can be one controlling factor. Also, the concentration gradient and the relative magnitudes of the component diffusivities provide a basis for a phase selection and the application of a kinetic bias strategy in the phase selection. For multicomponent alloy systems, the identification of the operative diffusion pathway is central to control phase formation. Experimental access to the nucleation and growth stage is discussed in thin film multi layers and bulk samples.

CHANGE POINT TEST FOR DISPERSION PARAMETER BASED ON DISCRETELY OBSERVED SAMPLE FROM SDE MODELS

  • Lee, Sang-Yeol
    • Bulletin of the Korean Mathematical Society
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    • v.48 no.4
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    • pp.839-845
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    • 2011
  • In this paper, we consider the cusum of squares test for the dispersion parameter in stochastic differential equation models. It is shown that the test has a limiting distribution of the sup of a Brownian bridge, unaffected by the drift parameter estimation. A simulation result is provided for illustration.

Cusum of squares test for discretely observed sample from multidimensional di usion processes

  • Na, Ok-Young;Ko, Bang-Won;Lee, Sang-Yeol
    • Journal of the Korean Data and Information Science Society
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    • v.21 no.3
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    • pp.547-554
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    • 2010
  • In this paper, we extend the work by Lee et al. (2010) to multidimensional di usion processes. A test statistic analogous to the one-dimensional case is proposed to inves-tigate the joint stability of covariance matrix parameters and, under certain regularity conditions, is shown to have a limiting distribution of the sup of a multidimensional Brownian bridge. A simulation result is provided for illustration.

An Electrochemical Evaluation on the Corrosion Resistance of a Al Alloy (주조용 Al합금의 내식성에 관한 전기화학적 평가)

  • Youn Dae-Hyun;Lee Myung-Hoon;Kim Ki-Joon;Moon Kyung-Man
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.5
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    • pp.495-501
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    • 2005
  • Al is a active metal that owes its resistance to a thin, protective, barrier oxide surface layer, which is stable in air and neutral aqueous solution. Thus Al alloys are widely used in architectural trim. cold & hot-water storage vessels and piping. However Al and most of its alloy may corrode with some forms such as pitting corrosion, intergranular corrosion and galvanic corrosion in the case of exposure to various industrial and marine atmosphere. Therefore a correct evaluation of corrosion resistance for their Al and Al alloys may be more important in a economical point of view. In this study. a relative evaluation of corrosion resistance for three kinds of Al alloys such as ALDC2, ALDC3, and ALDC8 series was carried out with electrochemical method. There is a tendency that corrosion potential is shifted to positive or negative direction by alloying components regardless of corrosion resistance. Moreover the data of corrosion properties obtained from cathodic Polarization curve, cyclic voltammogram and AC. DC impedance respectively showed a good correspondence each other against the corrosion resistance but variation of corrosion potential. passivity current density of anodic polarization curve and corrosion current density by Tafel extrapolation and Stern-Geary method didn't correspond with not only each other but also considerably the data of corrosion properties discussed above. Therefore it is suggested that an optimum electrochemical evaluation for corrosion resistance of Al alloy is to calculate the diffusion limiting current density of cathodic polarization curve, impedance of AC or DC and polarization resistance of cyclic voltammogram.

A Study on the Development of Low Reynolds Number k-$\varepsilon$ Turbulence Model (저레이놀즈수 k-$\varepsilon$난류모형 개선에 관한 연구)

  • 김명호;신종근;최영돈
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.10
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    • pp.1940-1954
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    • 1992
  • Fine grid computations were attempted to analyze the turbulent flows in the near wall low Reynolds number region and the numerical analyses were incorporated by a finite-volume discretization with full find grid system and low Reynolds number k-.epsilon. model was employed in this region. For the improvement of low Reynolds number k-.epsilon. model, modification coefficient of eddy viscosity $f_{\mu}$ was derived as a function of turbulent Reynolds number $R_{+}$ and nondimensional length $y^{+}$ from the concept of two length scales of dissipation rate of turbulent kinetic energy. The modification coefficient $f_{\epsilon}$ in .epsilon. transport equation was also derived theoretically. In the turbulent kinetic energy equation, pressure diffusion term was added in order to consider low Reynolds number region effect. The main characteristics of this low Reynolds number k-.epsilon. model were founded as : (1) In high Reynolds number region, the present model has limiting behavior which approaches to the high Reynolds number model. (2) Present low Reynolds number k-.epsilon. model dose not need additional empirical constants for the transport equations of turbulent kinetic energy and dissipation of turbulent kinetic energy in order to consider wall effect. Present low Reynolds number turbulence model was tested in the pipe flow and obtained improved results in velocity profiles and Reynolds stress distributions compared with those from other k-.epsilon. models.s.s.

Effects of Ethanol on the Fluidity of Plasma Membrane Vesicles Isolated from Cultured Mouse Myeloma Cell Line Sp2/0-Ag14 (Ethanol이 배양된 Mouse Myeloma Cell Line Sp2/0-Ag14로부터 분리한 형질막의 유동성에 미치는 영향)

  • Yun, Il;Chung, In-Kyo;Park, Yeong-Min;Kim, Jin-Bom;Yu, Seoung-Ho;Kang, Jung-Sook
    • The Korean Journal of Pharmacology
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    • v.29 no.1
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    • pp.149-156
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    • 1993
  • Intramolecular excimerization of 1,3-di(1-pyrenyl)propane (Py-3-Py) and fluorescence polarization of 1,6-diphenyl-1,3,5-hexatriene (DPH) were used to examine the effects of ethanol on the rate and range of lateral diffusion of bulk bilayer structures of plasma membrane vesicles isolated from cultured mouse myeloma cell line Sp2/0-Ag14 (Sp2/0-PMV). In a concentration-dependent manner, ethanol increased the excimer to monomer fluorescence intensity ratio (I'/I) of Py-3-Py in the Sp2/0-PMV and decreased the anisotropy (r), limiting anisotropy $(r_{\infty})$, and order parameter (S) of DPH in the Sp2/0-PMV. This indicates that ethanol increased both the lateral and rotational diffusion of the probes in the Sp2/0-PMV. Selective quenching of DPH by trinitrophenyl groups was utilized to examine the transbilayer asymmetric rotational diffusion of the Sp2/0-PMV. The anisotropy (r), limiting anisotropy $(r_{\infty})$, and order parameter (S) of DPH in the inner monolayer were 0.022, 0.029, and 0.063, respectively, greater than calculated for the outer monolayer of the Sp2/0-PMV. Selective quenching of DPH by trinitrophenyl groups was also utilized to examine the transbilayer asymmetric effects of ethanol on the range of rotational diffusion of the Sp2/0-PMV. Ethanol had a greater fluidizing effect on the outer monolayer as compared to the inner monolayer of the Sp2/0-PMV. It has been proven that ethanol exhibits a selective rather than nonselective fluidizing effect within transbilayer domains of the Sp2/0-PMV.

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A Study on Voluntary Acceptance and Diffusion of Game Shut-Down Policy Based on Excellence Theory and Psychological Reactance Theory (게임 셧다운제도의 자발적 수용 및 확산방안에 관한 연구 : 우수성 이론과 심리적 반발이론을 중심으로)

  • Park, Chan-Uk;Lee, Sin-Bok
    • Journal of Information Technology Services
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    • v.11 no.2
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    • pp.93-106
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    • 2012
  • Recently, a Game Shut-down policy, partially limiting the time for the use of online game service, has been implemented in order to protect the youth from the excessive use of games by limiting their access to games in the late hours, based on the serious side effects of online games on the youth. However, the effectiveness of a Game Shut-down policy becomes a social issue. Thus, this study aims to investigate the alternative policies through the levels of the communications suggested by the theory of excellence, for the successful implementation of the policy. As a result of the study, the government and students, the recipient of those policies, need to strengthen their two-way communication in respect of the Game Shut-down policy, breaking from the existing views on the perception. The problem is that the current government's way of the communication for the Game Shut-down policy is one-way and it is aiming at achieving the objectives only. Thus, the communication in this manner will cause the side effect. 'the opportunistic violation of the system in the future', even if the students seemingly accept the system. Two-way communication will enhance the motivation for the voluntary acceptance of the system and lower the motivation for the opportunistic violation of the system. Thus, the government needs to strengthen two-way communication in the future.

Fuzzy Logic based Propagation Limiting Method for message routing in Wireless Sensor Networks (무선 센서 네트워크에서 메시지 라우팅을 위한 퍼지로직 기반의 전달 영역 제한 기법)

  • Chi, Sang-Hoon;Cho, Tae-Ho
    • Proceedings of the Korea Society for Simulation Conference
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    • 2005.11a
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    • pp.8-12
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    • 2005
  • 최근 마이크로 센서와 무선 통신 기술의 진보는 센서 네트워크의 발전을 가능하게 하였다. 이와 같은 사실은 무선 센서 네트워크를 위한 수많은 라우팅 프로토콜의 개발로 이어졌으며, 다양한 구조의 알고리즘들이 제안되었다. 특히, 디렉티드 디퓨젼(Directed Diffusion; DD)은 데이터 중심 기반의 라우팅 알고리즘으로 속성 칼 쌍을 이용하여 통신하는 센서 네트워크의 한 패러다임이라고 할 수 있다. 그러나 기존의 DD에서는 작업을 요청하는 질의 메시지(interest message)가 전체 센서 네트워크에 플러딩(flooding)되는데, 이러한 과정은 에너지 소비 측면에서 볼 때 매우 비효율적이라고 할 수 있다. 이와 같은 문제를 해결하기 위하여 본 논문에서는 센서 노드의 에너지와 밀도 정보를 고려한 임계값을 이용하여 데이터의 전송 지역을 제한함으로서, 네트워크의 에너지 소비를 줄일 수 있는 새로운 메시지 전달영역 제한기법(propagation limiting method; PLM)을 제안한다. 퍼지 규칙 기반 시스템은 센서 필드에 배치된 노드들의 에너지와 밀도 정보를 입력 파라미터로 사용하여 메시지 라우팅을 위한 임계값 결정에 사용된다 본 연구에서 제안된 기법을 사용하여 센서 네트워크의 에너지 소비를 실험한 결과 기존에 제안되었던 알고리즘들에 비해 상대적으로 높은 효율성을 나타내었으며, 전체적으로 네트워크의 수명도 연장할 수 있었다.

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Diffusion Coefficient of Ag(I) ion in the Concentrated Nitric Acid Solution (고농도 질산용액에서 Ag(I) 이온의 확산계수 측정)

  • Park Sang Yoon;Choi Wang Kyu;Lee Kune Woo;Moon Jei Kwon;Oh Won Zin
    • Journal of the Korean Electrochemical Society
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    • v.2 no.2
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    • pp.93-97
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    • 1999
  • From the anodic peak currents of cyclic voltammograms for Ag(I)/Ag(II) couple obtained with the variation of nitric acid concentration, Ag(I) concentration and solution temperature at a Pt electrode in concentrated nitric acid solutions, the diffusion coefficients of Ag(I) ion were evaluated to estimate the limiting current density of Ag(II)-mediated electrochemical oxidation (MEO) process, which has been effectively used for the complete destruction of hazardous organic materials. The results showed that, due to the water decomposition reaction which occurred simultaneously with the Ag(I) ion oxidation, background subtractions for the cyclic voltammograms were required to estimate the correct peak currents. The empirical relationship for the diffusion coefficient of Ag(I) was suggested as a function of solution viscosity and temperature.

Scale Formation in the Concentrate Compartment of an Electrodialysis Stack During Desalination of Brackish Water (염수의 탈염을 위한 전기투석 농축실에서의 스케일 형성)

  • Moon Seung-Hyeon;Yang Jung-Hoon;Yeon Kyeong-Ho
    • Membrane Journal
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    • v.15 no.2
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    • pp.175-186
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    • 2005
  • An electrodialysis process was operated for a long period to investigate the scale formation on the membrane surface. During the desalination process, concentration of $Ca^{2+}$ and $SO_4^{2-}$ ions increased continuously in the concentrate compartment and eventually caused precipitation on the cation exchange membrane (Neosepta CMX) surface. During the initial scale formation, the performance of the process and membrane characteristics did not show significant changes, except the decrease in limiting current density of the CMX membrane occurring due to increase in the salt concentration in the concentrate compartment. Eventually, the limiting current density of the fouled CMX membrane dropped significantly to $300\;A/m^2$ as water dissociation occurred in the CMX membrane. It was concluded that the fouling was caused mainly by the scale formation on the cation exchange membrane surface in the concentrate and consequent water dissociation. Also the scale formation was reasonably predicted by the solubility of $CaSO_4$.