• Journal of Energy Engineering
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• v.29 no.3
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• pp.42-49
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• 2020

Precipitated Calcium Carbonate (PCC) can be utilized in energy-effective paper production. Limestone is a raw material for synthesizing PCC. Since the PCC production yield depends on the physicochemical properties of the limestone, a basic investigation of the raw limestone is required. This study provides a brief review of the origin of limestone, limestone distribution characteristics, and limestone deposits in Korea and Vietnam. Most limestones in Korea were formed in the Paleozoic era. On the other hand, limestones in Vietnam have various ages from the Precambrian to the Triassic. Limestone is the most largely produced mineral in Korea, but Vietnam has 5 times more amount of limestone reserves than Korea.

• Journal of the Korean earth science society
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• v.22 no.6
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• pp.558-570
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• 2001

The Middle Carboniferous Manhang and Geumcheon Formations exposed in the Taebaek area, Kangwondo, Korea consist of sandstones and shales with some intercalation of limestone beds. The limestones of the formations contain abundant conodonts and other fossils. The purpose of this study is (1) to investigate the conodont fauna, (2) to assign conodont biozones of the Manhang and Geumcheon Formations, and (3) to refine their geologic age more exactly. The conodonts of the Manhang and Geumcheon Formations are 6 genera distributed into 11 species. Conodonts found from limestones of the Manhang Formation are Idiognathodus delicatus, Hindeodus minutus, Streptognathodus sp., Diplognathodus coloradoensis, N. bothorops, and N. medexultimus. This conodont fauna can be assigned to the Neognathodus bothrops Zone. This conodont biozone indicates that the geologic age of the Manghang Formation is the Atokan stage of the Middle Carboniferous Period. Conodonts came from limestones of the Geumcheon Formation are Idiognathodus delicatus, N. medexultimus, N. roundyi, N. dilatus, Diplognathodus edentulus, Hindeodus minutus, Streptognathodus elegantulus, and Gondolella bella. These conodonts permit them to be assigned to the Neognathodus roundyi Zone. This Conodont biozone indicates that the geologic age of the Geumcheon Formation is the Desmoinesian stage of the Middle Carboniferous Period.

• Applied Chemistry for Engineering
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• v.17 no.1
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• pp.44-51
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• 2006

Effects of multiple-cycle operation and $SO_2$ concentration on $CO_2$ capture characteristics of three limestones were investigated in a fluidized bed reactor. For each of these sorbents, the measured $CO_2$ capture capacity decreased as the number of cycles increased and as the $SO_2$ concentration increased. On the other hand, the $SO_2$ capture increased with the increased number of cycles and the $SO_2$ concentration. The total calcium utilization decreased as the number of cycles increased, but the effect of $SO_2$ concentrations on the total calcium utilization depended on the type of limestone. For Strassburg limestone, the total calcium utillization decreased with increasing $SO_2$ concentration. However, for Luscar and Danyang limestones, the total calcium utilization was almost independent of $SO_2$ concentration for the range investigated. The results showed that $SO_2$ in flue gas reduced the $CO_2$ capture capacity of limestone and that the sulfation pattern affected the $CO_2$ capture capacity.

• Journal of the speleological society of Korea
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• no.5
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• pp.56-65
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• 1997

The cavernous rocks of New Zealand can be grouped broadly into two main geologic types-the massive, metamorphosed, Ordovician, Mt. Arthour Marble of north-west South Island, and the stratified, bioclastic, Tertiary Te Kuiti limestones of western regions of both islands. Although much cave exploration has been carried out in both these regions, the principal study so far has involved caves and karst in the central western portion of North Island near the well-known Waitomo Caves, where some 85km of caves have been surveyed during the past 12 years by members of New Zealand Speleolgical Society.

• Journal of Korean Society of Water and Wastewater
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• v.14 no.3
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• pp.271-280
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• 2000

This study was conducted to determine the applicable loading rate and to evaluate the possibility of using limestones as an alkalinity source for the removal of ${NO_3}^{-}-N$ remaining after denitrification/nitrification process with the down-flow sulfur packed bed reactor(SPBR). The pretreated sewage was fed to SPBR. Three SPBRs were filled with elemental sulfur particles and limestones and the volumetric ratios of sulfur to limestone were 0%, 12.5% and 25% for R-0%, R-12.5% and R-25%, respectively. The applicable loading rate was evaluated increasing flow rate with influent ${NO_3}^{-}-N$ concentration of 20 mg/L. For R-0% with external alkalinity supply, denitrification efficiency was greater than 96% up to loading rate of $354.8g\;{NO_3}^{-}-N/m^3{\cdot}day$, and corresponding EBCT was 1.4hr. For R-12.5% and R-25%, where alkalinity was supplied by the limestone filled in the reactor, denitrification efficiency was greater than 94% up to loading rate of $283.8g\;{NO_3}^{-}-N/m^3{\cdot}day$, and corresponding EBCT was 1.7hr. The slightly better performance of R-12.5 compared to R-25 suggests that the volumetric sulfur to limestone ratio of 12.5% was enough for the supply of alkalinity required for sulfur-utilizing denitrification. DO was appeared not showing inhibitory effect on sulfur-utilizing denitrification. The clogging of SPBR caused by the produced gas can effectively be eliminated by regular introduction of treated water in up-flow mode.

• Water for future
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• v.16 no.3
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• pp.171-179
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• 1983

In the Jeon Cheon Basin, unconsolidated alluvium and marine clay beds overlying Tertiary conglomerate and impermeable mudstone, and Cambro-Ordovician sedimentary rocks composed of mainly cavernous limestones, and age-unknowned crystalline rocks are occured. Most productive rock is Cambro-Ordovician limestones containing a lot of solution openings and secondary porosities and shows its transmissivity of 1836$m^2$/day and storativity of 1.47 $\times$ $10^{-3}$. The storage of deep seated groundwater in linestone aquifer is estimated about 1059 $\times$ $10^6$ metric tons, being equivalent to 6 years total precipitation of the basin. The safe yield of the groundwater to be abstracted from the aquifer is about 126,000 tons/day. To pump at least 100,000 tons/day of groundwater from the said aquifer, a well field comprising 34 deep wells ranging in depth from 80 to 100 meter and penetrating the cavernous limestone aquifer shall be established at middle and down stream area.

• Magazine of the Korea Concrete Institute
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• v.9 no.3
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• pp.119-126
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• 1997

Recently, duc to highly increased consumption of' ngg~.egatc>s f o ~ . construction. studies have focused on the effective utilization of rock wastes abandoned so far. This study was designed, firstly, to determine t,hc petrological, g'ochemical and mechanical cha~,acte~istics of' crushed limestone aggregates in thc Samhwa district for suitable construction aggregates and, secondly, to offer basic data for cff'ective utilization of low grade limestones. Results of' the petrographic st,udy indicates that the crushed limestone aggregates in the Samhwa district can bo separate4 into two groups, namely f'inc-grained and cowlxcgrained limestones. Dominantly distributed fine-grained limestone containing some dolomite has higher Mgo and $SiO_2$ contents compared to the coarse-graincd limestonr. It, can be classified as medium strength rock by the physical and mcxhanical pi.opertics. I3ased on the size of' mineral grains and chemical compositions, it is suggested that the crushed limestone aggregates in t,his study area would bctkr be u s ~ i for asphalt concr.ctt., road pavement, or railroad ballast materials than for cement concrete.

• Korean Chemical Engineering Research
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• v.57 no.6
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• pp.853-860
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• 2019

In order to meet more severe environmental regulations, oxy-fuel circulating fluidized bed(CFB) boilers or ultra supercritical CFB boilers, which are a kind of process in that solid particles moves similar to fluid, have been developed in the world. In CFB power generation processes, the method to reduce or remove sulfur dioxide is in-situ desulfurization reaction via limestone directly injected into CFB boilers. However, the desulfurization efficiencies have continuously changed because limestones injected into CFB boilers are affected by various operation conditions (Bed temperature, pressure, solid circulating rate, solid holdup, residence time, and so on). In this study, a prediction method with physical and chemical properties of limestone and operation conditions of CFB boiler for in-situ desulfurization reaction in CFB boilers has developed by integrating desulfurization kinetic equations and hydrodynamics equations for CFB previously published. In particular, the prediction equation for in-situ desulfurization was modified by using experimental results from desulfurization reactions of various domestic limestones.

• Economic and Environmental Geology
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• v.5 no.3
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• pp.145-150
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• 1972

This report is written for presenting a principal theme of study about. the origin of Sangdong ore deposit in details, being an aid to find new ore bodies, on the basis of mineralogical charactor and geological feature. Main vein in Sandgong mine has characteristic zonal distribution and localization of minerals. 3 kinds of minerals, that are quartz, hornblende, diopside, form systematically their each rich zones. Other minerals like plagioclase, native bismuth, sphene, molybdenite and wolframite are developed locally. According to the zonal distribution and localization of the minerals, the authors presume that mineralizing agents which changed interbedded limestones into ore bodies act and come up from non-exposed igneous body in the direction perpendicular to the platy main vein. That non-exposed igneous body, presumed, might be extended from the exposed igneous bodies in the southern part of Sangdong mine.

• Journal of the Korean Ceramic Society
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• v.19 no.1
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• pp.35-43
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• 1982

It was found that the burnability of raw mix and characteristics of clinker was affected by the difference in grades of limestones. The thermal decomposition temperature of raw mix which used low grade limestone was lower than that of high grade, and the fast formation of $C_2S$ was due to the rich content of calcite and quartz over critical grain size, which caused the bad effects in the burnability, but $C_3S$ was formed slowly. The structure of clinker had many pores, and the growth of clinker minerals was inferior.