• Resources Recycling
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• v.1 no.1
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• pp.23-28
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• 1992

The process for recovery of acids and valuable metals such as nickel and chromium from the stainless-steel pickling acids has been developed vased on the use of solvent extraction technique. Until now, several processes for the treatment of waste acids were already developed in such countries as Japan, Swden and Canada. Those methods are, however, forcussed on the recovery of acids from them discarding the metals included in them as the hydroxides sludge. In the present work, the recovery of nickel and chromium in addition to nitric acid and hydrofluoric acid has been aimed so as to recycle them to the stainless-steel pickling lines and also to minimize the amount of sludge generated during the treatment of waste acids. The establishment of the process to recover the acids has been carried out based on the solvent extraction with TBP. The iron was eliminated from the waste solutions by precipitating in the form of hydroxide through the adjustment of pH with calcined limestone and the selective extration of chromium and nickel from the resultant solutions has been conducted by using D2EHPA as extractant.

• Resources Recycling
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• v.5 no.1
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• pp.3-8
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• 1996

CZS(2Ca0 , SiO\ulcorner) phase of cement clinkcr was obtaincd by melting mixcd four indnstrial wasles of limestone sludge, waste Foundry sand, coal lly ash fiorn power plants and chernicas glasses. The effect ot mixing ratio of four rvastc mater~als ou the composnlg phascs in melled slag was investigated. Thc mixed wastes were meltcd to slag by heat under a constant basicity at 1370C. The shg consisted of p -CIS and C,AS(2CaO - A I P , . SiO,). The ratio of two phases was varied with mixing ~atioo f the waste materials. In order Lo increasc the amount ot j -C2S phase, the coal fly ash content should be reduced, while amount of the chemical glass be increased. The coal fly ash contcnt was the most imporlant factor in controlling phases of thc melted-slag.

• Tunnel and Underground Space
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• v.30 no.1
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• pp.87-97
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• 2020

Fracture toughness of rock is a constant that can indicate the initiation and propagation of cracks due to blasting, excavation, etc. Scaled model tests have been applied to the behavior of tunnels and the stability of limestone mines. Through the scaled model, damaged zone evaluation due to blasting is also carried out, and the scale factor is not applied to the failure-related factors. In this study, DCT (diametral compression test) and finite element method ATENA2D numerical analysis results were compared to determine whether the scale factor could be applied to the fracture toughness of rock. The theoretical values of the scale factor applied to the fracture toughness of the rock and the DCT test results and the numerical results are 0.21~0.46, 0.40, and 0.99MPa ${\sqrt{m}}$ respectively, so these three values should be considered when determining scale factor. It is necessary to derive a suitable scale factor in consideration of the length, time, and mass to which the scale factor is applied, as well as the values of the scale factor of major design factors such as uniaxial compressive strength and density.

• International Journal of Highway Engineering
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• v.9 no.4
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• pp.205-213
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• 2007

Strength relationships are presented through experimental data from the concrete strength tests in this study. Various strength tests such as the compressive, flexural, and splitting tensile strength and the modulus of elasticity are included. An experimental work was performed to determine the various strength characteristics for various mix designs. Three different coarse aggregates such as granite, limestone, sandstone were used and included were fine aggregates such as natural sand, washed sand and crushed sand. Also included was cement amount as experimental variable. It was confirmed that each strength value with respect to curing time is to follow a typical strength development curve. With this somewhat reliable test results various strength relationships such as flexural strength-compressive strength, splitting tensile strength-compressive strength, modulus of elasticity-compressive strength, splitting tensile strength-flexural strength were analyzed through statistics. Experimental data were well fitted to the 0.5-power relationship of flexural strength and compressive strength which has been commonly accepted. The splitting tensile strength is expected to be best in the linear relationship from the flexural strength data. Finally splitting tensile strength was found to be proportional to the 0.87 power of the cylindrical compressive strength.

• Korean Journal of Soil Science and Fertilizer
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• v.46 no.2
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• pp.73-80
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• 2013

Due to the fact that possible risk associated with soil-crop-food chain transfer, metal contamination in croplands has become a major topic of wide concern. Accumulation of toxic metals in edible parts of crops grown in contaminated soils has been reported from number of crops including rice, soybean, wheat, maize, and vegetables. Therefore, in order to ensure food safety, measures are needed to be taken in mitigating metal pollution and subsequent uptake by crop plants. Present paper critically reviewed some of the cost effective remediation techniques used in minimizing metal uptake by crops grown in contaminated soils. Liming with different materials such as limestone ($CaCO_3$), burnt lime (CaO), slaked lime [$Ca(OH)_2$], dolomite [$CaMg(CO_3)_2$], and slag ($CaSiO_3$) has been widely used because they could elevate soil pH rendering metals less-bioavailable for plant uptake. Zn fertilization, use of organic amendments, crop rotation and water management are among the other techniques successfully employed in reducing metal uptake by crop plants. However, irrespectively the mitigating measure used, heterogeneous accumulation of metals in different crop species is often reported. The inconsistency might be attributed to the genetic makeup of the crops for selective uptake, their morphological characteristics, position of edible parts on the plants in respect of their distance from roots, crop management practices, the season and to the soil characteristics. However, a sound conclusion in this regard can only be made when more scientific evidence is available on case-specific researches, in particular from long-term field trials which included risks and benefits analysis also for various remediation practices.

• Conservation Science in Museum
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• v.18
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• pp.93-114
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• 2017

This paper reviewed a total of eight sites in Vietnam inscribed on UNESCO's World Heritage List. The sites include the five cultural heritage sites(the Central Sector of the Imperial Citadel of Thang Long, Citadel of the Ho Dynasty, My Son Sanctuary, Hoi An Ancient Town, and Complex of Hué Monuments), two natural heritage sites (Ha Long Bay and Phong Nha-Ke Bang National Park), and one mixed heritage site (Trang An Landscape Complex). All these sites are situated in the northern and central areas of the country, and no inscribed site exists in the south. The two natural heritage sites and the Trang An Landscape Complex, a mixed heritage site, feature a typical Karst topographic landscape with limestone caves, cliffs, stalactites, and underwater rivers. The four cultural heritage sites as well as Hoa Lu of the Trang An Landscape Complex mainly consist of remains of the citadels of the capitals of ancient Vietnamese dynasties from the northern region. Due to the complex political situation in the aftermath of the long Vietnam War and the subsequent unification of the country, the Vietnamese government has been giving priority for inscription on the World Heritage List to sites with historical legitimacy in the northern region. It is hoped that the Vietnamese government will pursue more integrated cultural policies in the future that can help reduce north-south regional disparities.

• Resources Recycling
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• v.13 no.4
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• pp.3-10
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• 2004

The intension of this study is to produce ordinary portland cement using ash, both bottom ash and fly ash, obtained from municipal solid waste incineration ash (MSWI). We used limestone, waste molding sand, shale, slag from converting furnaces and fly ash as main raw materials and mixed them, setting the lime saturation factor (LSF) within 91.0, the silica modulus (SM) within 2.40, and iron modulus (IM) within 1.80. We conducted tests adding bottom ash alone 1, 2 and 3％ by weight, respectively, and a mixture of bottom ash 0.9％ and fly ash 0.1 ％ by weight. The result of analysis on clinker shows that the more ash is added, the lower the burnability index (B.I.) falls, lowering the mineral evolution of calcium silicate accordingly. From the measurement of compressive strength we have learned that the more ash is used, the lower the strength becomes.

• Proceedings of the Zoological Society Korea Conference
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• 1999.10b
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• pp.150.2-150
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• 1999

To investigate the weathering soil buffering capacities of the artificial acidic precipitation, the weathering soils and their leachate solutions were sampled from the host rocks(granite;GR, rhyolite;RH, gabbro;GA, basalt;BA, two serpentinite;SE1, SE2 and limestone;LI) and analyzed for pH and chemical properties. 1n the soil pH of the GR and RH ,the acidic rocks, were 5.02 and 5.95, respectively. And the GA and BA, basic rocks, were 6.52 and 7.57. The SE1 and SE2 were 8.90 and 8.89. While the LI was 7.84. These results means the typical soil pH properties by host rocks. After the artificial acidic precipitation input 5OOml, the average changes of soil leachate solutions treated by pH levels(pH 5.0, 4.0 and 3.0), were pH 5.73, 5.00 and 4.40. in GR soil, and pH 6.19, 5.99 and 5.57 in RH. GA were pH 6.31, 6.04 and 5.86, BA were pH 7.05, 6.85 and 6.56 and SE1 were pH 8.31, 8.26 and 7.71. SE2 were pH 8.29, 8.24 and 7.96. LI were pH 7.55, 7.46 and 6.79. The soil leachate pHs from volcanic rocks were higher than those from the plutonic rocks and GR soils showed greater response than other soils. With increasing 100ml input-solution, the soil leachate pHs were mainly decreased. Cation concentrations, CEC, EC and total nitrogen concentrations of RH and BA soils, the volcanic rocks, were higher than those of GR and GA soil, the plutonic rocks. On the contrary, Al concentrations of the GR and GA soils were higher than those of RH and BA soils, partly because of high quartz content in GR and Al content in the biotite and plagioclase in GA.

• Korean Journal of Soil Science and Fertilizer
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• v.48 no.1
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• pp.64-71
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• 2015

Soil contamination with arsenic and heavy metals is a worldwide problem. Main objective of this research was to evaluated effects of reducing heavy metal leaching under reduced soil condition amended with industrial by-products. The contaminated soil was amended with 3% (w/w) of limestone (Ls), steel slag (SS) and acid mine drainage sludge (AMDS). Synthetic acid rain ($H_2SO_4:HNO_3=6:4$, pH 5.5 fixed) was used for feeding solution with flow rate of $0.78{\sim}0.88mL\;min^{-1}$. Results showed that similar pH and EC of leachate was observed in all treatments regardless of applied industrial by-products. However, arsenic concentration of leachate increased when industrial by-products were mixed. Meanwhile, concentration of heavy metal in the leachate decreased from 11.3 to 4.59 mg for Cd, from 92.3 to 7.93 mg for Pb, and from 11,716 to 1,788 mg for Zn via immobilization in soil with AMDS amended, respectively. Overall, application of industrial by-products can be an environmentally-friendly way to remediate soil and(or) leachate contaminated with metal(loid)s in metal mine site.

• Korean Journal of Agricultural Science
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• v.46 no.1
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• pp.205-217
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• 2019

The aim of this study was to identify land resources because food production and supply in North Korea have been at risk due to variations in its seasonal climate. More than three-fifths of the soils are locally derived from the weathering of granitic rocks or various kinds of schists developed from crystalline rocks. Well-developed reddish brown soils derived from limestone are found in the North Hwanghae province and in the southern part of the South Pyeongan province. Additionally, a narrow strip of similarly fertile land runs through the eastern seaboard of the Hamgyong and Kangwon Provinces. The loss of clay particles and organic matter are major causes of degradation in the soil physical and chemical properties in North Korea. 75% of the areas converted from forests became croplands, and 69% of the land converted to croplands came from forests. The net forest loss was quite small from the 1990s to the 2000s. However, deforestation in areas with a slightly lower elevation and gentler slope between 1997 and 2014 led to severe soil erosion resulting in a drastic change in the physical and chemical properties of the soil which influenced cropland stability and productivity. Therefore, the drastic changes in land cover as well as in the physical and chemical properties of the soil caused by various geographical features have seriously influenced the productivity of crops in North Korea.