• Journal of the Mineralogical Society of Korea
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• v.7 no.1
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• pp.1-13
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• 1994

The industrial minerals play an important role in mining sector. More than 70 % of total mineral production come from industrial mineral sector. This paper reviews geological occurrence of kaolin, pyrophyllite and limestone, and current demand-supply status of major industrial minerals in the Republic of Korea. The kaolin is mainly distributed in the Kyeongsang province, formed by deep weathering of Precambrian anorthosite on mountainside of gentle slope. The pyrophyllite mainly occurs in the Kyeongsang and Chulla provinces, formed by hydrothermal alteration of late Cretaceous andesitic and rhyolitic rocks. Pyrophyllite comprises massive and lenticular bodies and contains minor amounts of kaolin, alunite and pyrite, in some places andalusite and illite. The limestone(Great Limestone Series of Cambrian age) is distributed widely in the Kwangwon and Chungcheong provinces. The limestone bodies are approzimately 70 km long and 3 km wide, elongated NE-ward, and show high grade of CaO content. In 1992, the self-sufficiency ratio of 44 nonfuel (metallic and non-metallic) minerals was no more than 30 percent. However, the ratio of 27 industrial minerals (non-metallic) represents high value of about 72 percent. The export/productjon ratio of the industrial minerals shows decreasing patterns from 12.2 % in 1983 to 4.2 % in 1992. Also the import/production ratio shows rapidly decreasing pattern from 84 % in 1983 to 38.2 % in 1992.

• Resources Recycling
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• v.24 no.1
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• pp.12-20
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• 2015

In this study, change of hydration property with contents and type of gypsum in ternary natural hydraulic lime containing blast furnace slag and gypsum was investigated. Anhydrite, hemihydrate and dihydrate were added 3 % and 10 %, respectively in natural hydraulic lime adding blast furnace slag 20 %. Hydration and physical behavior due to solubility and reactivity of different types of gypsum were analyzed in early hydration. As a result of analysis of hydration properties, in all samples, hydrates such as ettringite and C-S-H were produced in early hydration, and amount of hydrates with increase of hydration time was increased. In the case of compressive strength, when contents of gypsum are 3 %, it was higher compressive strength than other specimens. At hydration 28 days, for addition of anhydrite and hemihydrate, compressive strength was more than adding dihydrate.

• Tunnel and Underground Space
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• v.28 no.5
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• pp.457-475
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• 2018

For increase of reality in numerical analysis, a blasting vibration waveform obtained from field blast operations has been directly used for input parameters of dynamic analysis in the form of vibration velocity. A numerical model was built considering the geological characteristics of underground limestone opening as well as the mining stages in this opening, and the effect of blast operations on stability of underground limestone opening was investigated by dynamic numerical analysis. The adequacy of applying the real vibration waveform to dynamic analysis has been approved from the preliminary analysis, and the dynamic numerical analysis results show that the continuous mining operation can cause the collapse of roof in openings and the active yield zone around openings. Therefore, the additional reinforcements should be applied for ensuring the stability of underground limestone openings.

• Economic and Environmental Geology
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• v.31 no.4
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• pp.277-290
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• 1998

The purpose of this research is to investigate the dispersion pattern of gold during skarnization and genesis of gold mineralization in the Sangdong skarn deposits. The Sangdong scheelite orebodies are embedded in the Cambrian Pungchon Limestone and limestone interbedded in the Myobong Slate of the Cambrian age. The tungsten deposits are classified as the Hangingwall Orebody, the Main Orebody and the Footwall Orebody as their stratigraphic locations. Recently, the Sangdong granite of the Cretaceous age (85 Ma) were found by underground exploratory drillings below the orebodies. In geochemisty, the W, Mo, Bi and F concentrations in the granite are significantly higher than those in the Cretaceous granitoids in southern Korea. Highest gold contents are associated with quartz-hornblende skarn in the Main Orebody and pyroxene-hornblende skarn in the Hangingwall Orebody. Also Au contents are closely related to Bi contents. This could be inferred that Au skarns formed from solutions under reduced environment at a temperature of $270^{\circ}C$. According to the multiple regression analysis, the variation of Au contents in the Main Orebody can be explained (87.5%) by Ag, As, Bi, Sb, Pb, Cu. Judging from the mineralogical, chemical and isotope studies, the genetic model of the deposits can be suggested as follows. The primitive Sangdong magma was enriched in W, Mo, Au, Bi and volatiles (metal-carriers such as $H_2O$, $CO_2$ and F). During the upward movement of hydrothermal ore solution, the temperature was decreased, and W deposits were formed at limestone (in the Myobong Slate and Pungchon Limestone). In addition, meteoric water influx gave rise to the retrogressive alterations and maximum solubility of gold, and consequently higher grade of Au mineralization was deposited.

• The Journal of Engineering Geology
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• v.25 no.2
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• pp.251-263
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• 2015

Geological mapping, borehole drilling, electrical resistivity, and seismic tomography surveys were conducted in order to map underground cavities and better understand the mechanisms driving subsidence in a limestone region in Korea. Limestone outcrops in the study area generally alternate between calcite-rich and calcite-poor rock. The results reveal that in areas experiencing subsidence, cavities occur mainly around soil-rock boundaries at depths of 7~14 m. These results are based on comparative analyses of electrical resistivity, seismic tomography, and borehole logging data. The volumes of the cavities are relatively small in a range of 558~835 ㎥ and they have a shape typical of suffosion sinkholes, which are typically found where sandy soils overlie bedrock cavities.

• Resources Recycling
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• v.27 no.1
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• pp.3-13
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• 2018

3D printing, also known as Additive Manufacturing (AM), is being positioned as a new business model of revolutionizing paradigms of existing industries. Launched in early 2000, 3D printing technology for architecture has also advanced rapidly in association with machinery and electronics technologies mostly in the United States and Europe. However, 3D printing systems for architecture require different mechanical characteristics from those of cement/concrete raw materials used in existing construction methods. Accordingly, in order to increase utilization of raw materials produced in the cement and resource recycling industry, it is necessary to develop materials processing and utilization technology, to secure new property evaluation and testing methods, and to secure database related to environmental stability for a long period which aims to reflect characteristics of an architectural 3D printing technology.

• Tunnel and Underground Space
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• v.14 no.4
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• pp.261-268
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• 2004

The main objectives of this study are to investigate the anisotropic characteristics of rocks and to evaluate the relationships between physical properties. A series of experiments were performed in three mutually perpendicular directions for three rock types, which are granite, granitic gneiss and limestone. The relationships of measured physical properties were evaluated. The results of ultrasonic wave velocity measurement show that granite of three rock types gives the largest directional difference, and that the wave velocity in a plane parallel to a transversely isotropic one is dominantly faster than that in a subvertical or vertical plane. It implies that ultrasonic wave velocity for rock could be used as a useful tool for estimating the degree of anisotropy. The ratio of uniaxial compressive strength to Brazilian tensile strength ranges approximately from 13 to 16 for granite. from 8 to 9 for granite gneiss, and from 9 to 18 for limestone. The directional differences for granite and granitic gneiss are very small, and on the other hand, is relatively large for limestone. It is suggested that strength of rock makes quite difference depending on the rock types and loading directions, especially for the anisotropic rocks such as transversely isotropic or orthotropic rocks. The ratio of uniaxial compressive strength to point load strength index ranges from 18 to 20 for granite, from 17 to 19 for granitic gneiss, and from 21 to 24 for limestone. These results show that point load strength index makes also a difference depending on rock types and directions. Therefore. it should be noted that the ratio of uniaxial compressive strength to point load strength index could be applied to all rock types. Uniaxial compressive strength shows relatively good relationship with point load strength index, Schmidt hammer rebound value, and tensile strength. In particulat, point load strength index is shown to be the best comparative relationship. It is indicated that point load test is the most useful tool to estimate an uniaxial compressive strength indirectly.

• Tunnel and Underground Space
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• v.28 no.4
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• pp.358-371
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• 2018

The stability of openings in the underground mine is major concern in the operation of mines that must ensure productivity and safety. Among many rock conditions affecting cavities stability, the width and height of the opening is an important design factor. In this paper, we consider to determine the maximum unsupported span of a opening in a limestone mine by using the Q system among several rock classification schemes. In order to determine the span of the unsupported opening in the limestone mine, rock mass classifications were carried out at over 200 sites in the underground limestone mines. The relationships by using the Q system and the stability graph proposed by Mathews to determine the maximum span of the unsupported opening were derived and compared. We propose a new classification method that combines GSI and RMR rock classification systems to make it easy to use in a field.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.09a
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• pp.71-74
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• 2001

AMB(Acid Mine Drainage), characterized as high concentration of metal & sulfate ions and low pH(2.0~4.0), is the world-wide problem wherever there is or has been mining activities. Though limestone has been generally used to neutralize AMD, There are metal hydroxide precipitation on the surface of limestone and excessive alkalinity formation which exceeds the regulation. In this research, concrete-recycled fine aggregate is selected for alternative neutralizing agent. Because fine recycled aggregate had more ANP than others in the preliminary research, the purpose of this research is to apply fine aggregate for AMD neutralization. Three columns packed with fine aggregates(2.5mm$O_3$) of it is calculated as 0.09(C-1), approximated 10% purity of limestone. Comparing with values of other columns(C-2: 0.01 and C-3: 0.01), there is variation of porosity and residence time induced from the precipitation of metal hydroxide. Consequently, 8 hours of HRT is enough to create adequate alkalinity and the function which could expect the variation of porosity(n) and residence time( $t_{R}$) should be applied to develop design function.lied to develop design function.

• Composites Research
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• v.29 no.6
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• pp.328-335
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• 2016

The purpose of this study is to develop fiber reinforced cement matrix composite (ECC) produced with limestone powder in order to achieve high ductility of the composite, and to evaluate flexural performance of structural members made with ECC. Four kinds of mixture proportions were determined on the basis of the micromechanics and a steady state cracking theory considering the matrix fracture toughness and fiber-matrix interfacial characteristics. The mechanical properties of ECC, represented by strain-hardening behavior in uniaxial tension, were investigated. Also, strength property of the composite was experimentally evaluated. Two structural members made with ECC were produced and tested. Test results were compared with those of conventional concrete structural members. Increased limestone powder contents of ECC provides higher ductility of the composites while generally resulting in a lower strength property. ECC structural members exhibited higher flexural ductility, higher flexural load-carrying capacity and tighter crack width compared to conventional structural members.