• 제목/요약/키워드: Limestone

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이산화탄소 반응경화 시멘트 제조 및 경화특성 연구 (Manufacturing Properties and Hardening Characteristic of CO2 Reactive Hardening Cement)

  • 문기연;김병렬;이승한;최문관;조계홍;조진상
    • 자원리싸이클링
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    • 제31권6호
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    • pp.52-59
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    • 2022
  • 이산화탄소 반응경화 시멘트(Calcium silicate based cement, CSC)는 제조 전 공정에서 보통 포틀랜드 시멘트 대비 최대 70% 가량의 CO2 감축을 기대할 수 있는 저탄소 시멘트로 해외 선진국가에서는 이미 상용화 단계에 도달하였으나 국내에서는 제조특성 및 기초물성연구가 시작되고 있는 단계이다. 이에 본 연구에서는 국내산 원료물질을 활용한 CSC 제조 가능성을 검토하고, 제조한 CSC의 기초물성평가를 통해 CSC의 국산화 가능성을 조사하고자 하였다. 실험결과, 국내산 고품위 석회석과 실리카흄을 활용해 제조한 CSC의 주요광물상은 CS, C3S2, C2S 및 미반응 SiO2로 이론적인 CSC 주요광물상과 유사한 특성을 나타내며, 국내산 원료물질을 활용한 CSC 제조가능성을 확인할 수 있었다. 제조한 CSC의 경화특성 조사를 위해 양생분위기에 따른 광물상 변화특성을 조사하였으며, TG/DSC 열분석결과, 탄산화양생을 실시한 샘플에서만 탄산화반응 결과생성물로서 다량의 CaCO3가 생성된 것을 확인할 수 있었다. 이러한 특성은 압축강도에서 뚜렷한 차이를 나타내었는데, 습윤양생 시 재령 7일 기준 압축강도 1MPa 이하로 수화반응 및 탄산화반응에 의한 물성발현이 거의 없는 반면에 탄산화 양생 시 재령 7일 기준 압축강도 56MPa 이상으로 조기강도 특성이 우수한 것을 확인할 수 있었다.

Predicting blast-induced ground vibrations at limestone quarry from artificial neural network optimized by randomized and grid search cross-validation, and comparative analyses with blast vibration predictor models

  • Salman Ihsan;Shahab Saqib;Hafiz Muhammad Awais Rashid;Fawad S. Niazi;Mohsin Usman Qureshi
    • Geomechanics and Engineering
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    • 제35권2호
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    • pp.121-133
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    • 2023
  • The demand for cement and limestone crushed materials has increased many folds due to the tremendous increase in construction activities in Pakistan during the past few decades. The number of cement production industries has increased correspondingly, and so the rock-blasting operations at the limestone quarry sites. However, the safety procedures warranted at these sites for the blast-induced ground vibrations (BIGV) have not been adequately developed and/or implemented. Proper prediction and monitoring of BIGV are necessary to ensure the safety of structures in the vicinity of these quarry sites. In this paper, an attempt has been made to predict BIGV using artificial neural network (ANN) at three selected limestone quarries of Pakistan. The ANN has been developed in Python using Keras with sequential model and dense layers. The hyper parameters and neurons in each of the activation layers has been optimized using randomized and grid search method. The input parameters for the model include distance, a maximum charge per delay (MCPD), depth of hole, burden, spacing, and number of blast holes, whereas, peak particle velocity (PPV) is taken as the only output parameter. A total of 110 blast vibrations datasets were recorded from three different limestone quarries. The dataset has been divided into 85% for neural network training, and 15% for testing of the network. A five-layer ANN is trained with Rectified Linear Unit (ReLU) activation function, Adam optimization algorithm with a learning rate of 0.001, and batch size of 32 with the topology of 6-32-32-256-1. The blast datasets were utilized to compare the performance of ANN, multivariate regression analysis (MVRA), and empirical predictors. The performance was evaluated using the coefficient of determination (R2), mean absolute error (MAE), mean squared error (MSE), mean absolute percentage error (MAPE), and root mean squared error (RMSE)for predicted and measured PPV. To determine the relative influence of each parameter on the PPV, sensitivity analyses were performed for all input parameters. The analyses reveal that ANN performs superior than MVRA and other empirical predictors, andthat83% PPV is affected by distance and MCPD while hole depth, number of blast holes, burden and spacing contribute for the remaining 17%. This research provides valuable insights into improving safety measures and ensuring the structural integrity of buildings near limestone quarry sites.

매스콘크리트 벽체에서 콘크리트 응결 특성과 측압과의 관계 (Relation of Concrete Setting Characteristic and Lateral Pressure in Mass Concrete Wall)

  • 박찬규;유재현;백승준;정재홍;진용만
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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    • pp.935-938
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    • 2001
  • This paper reports the relation of concrete setting characteristic and lateral pressure in mass concrete wall such as side wall of LNG underground storage tank. In order to estimate the lateral pressure, initial setting time of low heat cement concrete with type of mineral admixture was measured for three concrete mixtures(W/P=41.6%) containing limestone powder, fly ash, and slag powder. As a result, the lateral pressure of the concrete containing limestone powder was the smallest than those of other concretes as well as the initial setting time.

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단양 석회석 광산터널의 암반 평가 및 안정성 연구 (Study on the stability of tunnel and rock mass classification in Danyang limestone quarry)

  • 신희순
    • 터널과지하공간
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    • 제6권2호
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    • pp.131-143
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    • 1996
  • In-situ survey and laboratory rock test were carried out for rating rock mass around the tunnel that some failures had been occurred in Danyang limestone quarry. For rating rock mass, several methods such as RMR, Q-system, rock strength etc. were applied. The stability analysis on tunnel was evaluated by numerical method FLAC. And The block theory using streographic projection was also applied for stability analysis. The 3-4 major discontinuity sets are distributed in rock mass around tunnel.

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국산 천연원료를 사용한 규탄석-탄장석계 광물 합성에 관한 연구 (The Study on Wollastonite-Anorthite Synthesis from Domestic Raw Materials)

  • 안영필;정복환;김성일;최롱
    • 한국세라믹학회지
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    • 제14권3호
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    • pp.157-162
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    • 1977
  • The synthesized wollastonite-anorthites by using Korean agalmatolite and limestone are studied. Batch compositions were prepared by the ratio of limestone 4 mole to agalmatolite 1 mole. Optimum temp. for the synthesis of wollastonite-anorthite was around $1,250^{\circ}C$.

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석회석 미분말을 활용한 고유동 콘크리트의 자기수축 특성 (Characteristic on Autogenous Shrinkage of High Fluidity Concrete Using Limestone Powder)

  • 최연왕;정재권;문재흠;문대중;박만석;최병걸
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
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    • pp.385-386
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    • 2010
  • 본 논문은 석회석 미분말을 활용한 고유동 콘크리트의 유동 특성 및 자기수축량을 통하여 자기수축 특성을 알아보았다.

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Canterbury Hill Cave, Collingwood

  • Cody, Ashley
    • 동굴
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    • 제7호
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    • pp.9-10
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    • 1998
  • This is but a brief description of a cave which, although well known to local inhabitants, appears to be unknown to the N.Z.S.S. It is reputed to be one of several caves in this region, but we have so far been unable to continue our prospecting here as fully as is needed. The cave is in no way unique nor of an outstanding nature; being within an isolated remnant of a much younger limestone which appears to have once extensively overlain the old Paleozoic basement rocks of the Aorere valley region. It seems probable that it is in the same limestone as the well-known Te Anaroa tourist cave, at Rockville near Collingwood, and that of the Brown River caves south of Bainham.(omitted)

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Effects and control of blast vibrations in the vicinity of the limestone quarry

  • Kumar L. Ajay
    • 한국지구물리탐사학회:학술대회논문집
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    • 한국지구물리탐사학회 2003년도 Proceedings of the international symposium on the fusion technology
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    • pp.83-87
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    • 2003
  • Experimental blast studies were carried out in a limestone quarry to study the effects of blasting on structures. To have an in-depth understanding of the possible relation between parameters like vibrations, frequency and scale distance and ten trial blast were conducted. 29 monitoring stations were located in such a pattern to give a true representation of blast induced vibrations for the entire mining in this area. The vibrations were monitored in the vicinity of structures surrounding the quarry in the direction towards the village, road, railway line, office building, etc. Scale distances were determined to identify the maximum charge permissible to cause damage to structures.

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온달 동굴수에 관한 연구 (A Study on the Groundwater of Ondal Limestone Cave)

  • 김추윤
    • 동굴
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    • 제61호
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    • pp.47-64
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    • 2000
  • The Ondal cave, as limestone cave, located in 37$^{\circ}$ 03'N, 128$^{\circ}$ 29'E and in Ha-ri, Yongchun-myeon, Banyans-gun, Chungchongbuk-do. This study analyzed the groundwater of Ondal Cave with 44 items. On investigation almost of items were low and only germs were high than a base numerical value, this is supposedly caused by tourist entrance. For the better management of the Ondal cave the preventing is required.

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대규모 사면의 붕괴사례 (Case Study on Large Cutting Slope Failure)

  • 박영목
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2002년도 가을 학술발표회 논문집
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    • pp.27-43
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    • 2002
  • This paper described two case studies on large scale failure of cutting slope. The kind of rock in both sites predominated limestone and shale respectively. These cutting slopes located in northern area of Gyongbug Province are composed of very complicated and various rock mass. Geological characteristics, causes of failure, proceeding of security diagnose, maintenance method etc. of two sites were carried out to check the cutting slope stability and to provide reasonable maintenance method. This paper may provide the useful data for engineers related with design and construction of large cutting slope.

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