• Journal of the Mineralogical Society of Korea
• /
• v.28 no.3
• /
• pp.279-292
• /
• 2015

New occurrences of large-scaled Zn-Pb deposits are recently found in the Danjang-myeon, Milyang. They are skarn-type deposits which replaced the intercalated limestone beds in the Jeonggaksan Formation. This study aims at characterizing occurrences, mineralogy, and chemistry of Zn-Pb ores and skarn minerals. Skarn orebodies are mainly found in 3 areas, named Gukjeon-ri, Gorye-ri, and Gucheon-ri orebodies, where sphalerite found as main ore mineral in 200-300 m in height and amount of galena increases as altitude does. Ores are dark grey to dark green in color and closely related with clinopyroxene zone. They occur with hedenbergite, grossular, actinolite, epidote, and small amounts of axinite, calcite, and quartz. Main ore mineral is sphalerite which includes tiny spotted grains of galena and chalcopyrite and becomes rich in grade in association with clinopyroxene and epidote. FeS contents in sphalerite show relatively wide range between 1.53 and 23.07 mole%, whose contents intend to increase towards biotite granite known as ore-related igneous rocks. CdS contents are in the range of 0.22-0.93 mole%, showing decrease tendency from southwest (Gukjeon-ri) to northeast (Gucheon-ri). Zn-Pb deposits developed in Danjang-myeon reveal decrease in temperature with increase of altitude, leading to gradual changes in compositions of ore and skarn minerals.

• Journal of the Korea Institute of Building Construction
• /
• v.20 no.2
• /
• pp.123-128
• /
• 2020

γ-dicalcium silicate(γ-C₂S) is known as a polymorphism of belite. Due to its high CO₂ fixing capacity and the production process with low CO₂ emission, γ-C₂S has attracted more attention of researchers. For the further development of γ-C₂S applications in construction industry, this study aims to investigate the method for synthesizing high purity of γ-C₂S. The influence of raw materials and calcination temperatures on the purity of γ-C₂S was evaluated. Several Ca bearing materials were selected as the calcium source, the materials which's main component is SiO₂ were used as the silicon source. Raw materials were mixed and calcined under different temperatures. The results revealed that the highest purity could be obtained using Ca(OH)₂ and SiO₂ powder as raw materials. In addition, a relatively economic synthesis method using natural mineral materials-limestone and silica sand as raw materials were developed for the practical application. The purity of synthetic γ-C₂S was recorded up to 77.6%.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.19 no.9
• /
• pp.355-361
• /
• 2018

Mining is important as a national key industry that supplies energy and raw materials that are the basis for industrial development. On the other hand, mine development is necessarily accompanied by mineralization, for example, ground subsidence, heavy metal pollution, and water pollution. The mine hazard has a large range of damage, and it takes much time and cost to recover. In addition, there is a need for systematic mining management in order to prevent damages from occurring continuously. In this study, the present status of domestic mining industry and geospatial information construction technology for mining management were investigated. 95% of the mines surveyed were nonmetallic, and limestone mines accounted for 67%, and the constructed mine spatial information is not constructed with 3D geospatial information due to 2D current status, section, and geological map. Considering the results of the survey and analysis of 3D laser scanner and characteristics of Korean mine, handheld scanner is considered to be the most suitable method for constructing mine geospatial information. In addition, the data acquired through the 3D laser scanner can effectively visualize the object, and it can contribute to the systematic management of mining because it can be used for various purposes such as generation of drawings and calculation of volume.

• Economic and Environmental Geology
• /
• v.38 no.3 s.172
• /
• pp.237-245
• /
• 2005

The batch tests were performed to evaluate the applicability of the permeable reactive barrier (PRB) to in-situ treatment of groundwater with high concentration of heavy metals. The lead\chates used in this study were collected from waste rock dump of the Imgy mine, and have a low pH and high metal concentration. The acidity loading was 65kg as $CaCO_3/day$, metal loading of Fe+Al+Mn was 11.6kg/day. This type of water could be treated with biological-mediated sulfate reduction using the organic carbon mixture as a reactive media. The batch tests were carried out with five mixtures that were composed with different mixing ratios of mushroom compost, pine-tree bark, and limestone cheep. Results indicated that the PRB could reduce the acidity loading $CaCO_3/day$ to 12.3kg and reduce the metal loading to 3.3kg/day. Considering about the low pH and high metal loading, the contaminated water may be ameliorated by passing it through the buffering PRB composed with inorganic carbonate materials and then through the PRB composed with the organic carbon mixture which can induce sulfate reduction.

• Analytical Science and Technology
• /
• v.13 no.2
• /
• pp.158-165
• /
• 2000

The purity of gypsum and quantitation of impurities of flue gas gypsum will not only play an important role in deciding of the optimal condition during a trial run of FGD (flue gas desulfurization), but also can be utilized in quality control of gypsum. The purity of gypsum can be determined from combined water, sulfur trioxide and calcium concentration. We found that the thermal analysis by TGA (thermogravimetric analysis) was the most accurate and convenient method to determine the purity of gypsum. This method will be done in a hour and the results were reproducible. On the other hand, the best way of the analysis of impurities in gypsum was fusion method using $LiBO_2$ as a fusion agent. We also determined the amount of $CO_2$ gas to analyze magnesium carbonate and calcium carbonate contents. The analyses of combined water by TGA, fusion method followed by ICP-AES (inductively coupled plasmaatomic emission spectroscopy) and determination of $CO_2$ amount can lead to more accurate and convenient method for gypsum analysis.

• Tunnel and Underground Space
• /
• v.15 no.6 s.59
• /
• pp.425-431
• /
• 2005

A series of geotechnical surveys and in-situ tests were carried out to evaluate the stability of underground mine cave in an abandoned coal mine. After the closure of the mine, the underground mine drifts have been utilized for a tourist route since 1999. The dimension of the main cave is 5m width, 3m height and 230m length. The surrounding rock mass of the cave is consist of black shale, coal and limestone. Also, the main cave is intersected by two fault zone. Detailed field investigations including Rock Mass Rating(RMR), Geological Strength Index(GSI) and Q classification were performed to evaluate the stability of the main cave and to examine the necessity of reinforcement. Based on the results of rock mass classification and numerical analysis, suitable support design was recommended for the main cave. RMR and Q values of the rock masses were classified in the range of fair to good. According to the support categories proposed by Grimstad & Barton(1993), these classes fall in the reinforcement category of the Type 3 to Type 1. A Type 3 reinforcement category signifies systematic bolting and no support is necessary for the Type 1 case. From the result of numerical analysis, it was inferred that additional support on the several unstable blocks is required to ensure stability of the cave.

• Tunnel and Underground Space
• /
• v.28 no.1
• /
• pp.38-58
• /
• 2018

The ventilation system plays a crucial role in underground mine safety. The main objective of the ventilation system is to supply sufficient air to dilute the contaminated air at working places and consequently provide tenable environment during the normal operation, while it also should be capable of controlling the fire propagation and facilitate rescue conditions in case of fire in mines. In this study, a smoke control fan was developed for the auxiliary ventilation as well as the fire smoke exhaust. It works as a free-standing auxiliary fan without tubing to dilute or exhaust the contaminated air from the working places. At the same time, it can be employed to extract the fire smoke. This paper aims to examine the smoke control efficiency of the fan when combined with the current ventilation system in mines. A series of the site experiments and numerical simulations were made to evaluate the fan performance in blind entry development sites. The tracer gas method with SF6 was applied to investigate the contaminant behavior at the study sites. The results of the site study at a large-opening limestone mine were compared with the CFD analysis results with respect to the airflow pattern and the gas concentration. This study shows that in blind development entry, the most polluted and risky place, the smoke fan can exhaust toxic gases or fire smoke effectively if it is properly combined with an additional common auxiliary fan. The venturi effect for smoke exhaust from the blind entry was also observed by the numerical analysis. The overall smoke control efficiency was found to be dependent on the fan location and operating method.

• Journal of the Mineralogical Society of Korea
• /
• v.2 no.2
• /
• pp.90-99
• /
• 1989

Manganese deposits ar the Dongnam mine occur as vein in the Pungchon limestone of Ordovician age. Manganese ore veins consist of the hydrothermal manganese carbonate ores in the deeper part and the supergene manganese oxide ores in the shallow part. Manganese carbonate ores consist mainly of rhodochrosite, with minor amount of proxmangite, garnet, calcite, quartz, pyrite, galena and sphalerite. Manganese oxide ores consist of rancieite, buserite, birnessite, vernadite, todorokite, pydrolusite, nsutite, hydrohetaerosite and goethite. Manganese oxide minerals were formed in the following sequences; 1) rhodochrosite ${\rightarrow}$ vernadite ${\rightarrow}$ birnessite ${\rightarrow}$ nsutite ${\rightarrow}$ pyrolusite, 2) pyroxmangite ${\rightarrow}$ birnessite, 3) Buserite ${\rightarrow}$ ransieite. Todorokite, buserite and hydrohetaerolite were precipitated from solution in the later stage. The natural analogue of synthetic buserite has been discovered from the mine. It has been disclosed that buserite transforms to rancicite by dehydration, and that distinction between buserite and todorokite is possible by X-ray diffraction studies combined with dehydration experiment. Minerals identified from the mine have been characterized using various methods including polarizing microscopy, X-ray diffraction, thermal analysis, infrared spectroscopy, X-ray diffraction, thermal analysis, infrared spectroscopy, elecrton microscopy and dehydration experiment.

• Journal of the Mineralogical Society of Korea
• /
• v.20 no.1 s.51
• /
• pp.35-46
• /
• 2007

Shinyemi skarn deposits occur as Fe-Mo skarn type and Pb-Zn-Cu hydrothermal replacement type along the contact between Cretaceous Shinyemi granitoids and Cambro-Ordovician mixed limestone and dolostone sequence of the Choseon Supergroup. In the lower part of Western Shinyemi ore body two stages of skarn formation have been observed: the early, stage I (magnesian) skarn with Fe mineralization and the late, stage II(calcic) skarn with Mo mineralization. The stage I skarn spatially is overprinted by stage II skarn. The stage I skarn is predominantly composed of olivine, magnetite and diopside whereas, the stage II skarn is dominated by hedenbergite and garnet. The skarnification process occurred in two stages, both prograde and retrograde for stage I and stage II skarns. In stage I, the prograde skarns, mainly composed of anhydrous silicate minerals, were formed at relatively higher temperatures (about $400\;to\;550^{\circ}C$) under low $CO_{2}$ fugacity ($X_{CO2}<0.1$) conditions. On the other hand, the retrograde skarns that consisted of hydrous minerals were formed at lower temperatures (about $300\;to\;400^{\circ}C$).

• Economic and Environmental Geology
• /
• v.29 no.4
• /
• pp.411-419
• /
• 1996

The Janggun magnetite deposits occur as the lens-shaped magnesian skarn, magnetite and base-metal sulfide orebodies developed in the Cambrian Janggun Limestone Formation. The K-Ar age of alteration sericite indicates that the mineralization took place during late Cretaceous age (107 to 70 Ma). The ore deposition is divided into two stages as a early skarn and late hydrothermal stage. Mineralogy of skara stage (107 Ma) consists of iron oxide, base-metal sulfides, Mg-Fe carbonates and some Mg- and Ca-skarn minerals, and those of the hydrothermal stage (70 Ma) is deposited base-metal sulfides, some Sb- and Sn-sulfosalts, and native bismuth. Based on mineral assemblages, chemical compositions and thermodynamic considerations, the formation temperature, $-logfs_2$, $-logfo_2$ and pH of ore fluids progressively decreased and/or increased with time from skarn stage (433 to $345^{\circ}C$, 8.8 to 9.9 atm, 29.4 to 31.6 atm, and 6.1 to 7.2) to hydrothermal stage (245 to $315^{\circ}C$, 11.2 to 12.3 atm, 33.6 to 35.4 atm, and 7.3 to 7.8). The ${\delta}^{34}S$ values of sulfides have a wide range between 3.2 to 11.6‰. The calculated ${\delta}^{34}S_{H_2S}$ values of ore fluids are relatively homo-geneous as 2.9 to 5.4‰ (skam stage) and 8.7 to 13.5‰ (hydrothermal stage), which are a deep-seated igneous source of sulfur indicates progressive increasing due to the mixing of oxidized sedimentary sulfur with increasing paragenetic time. The ${\delta}^{13}C$ values of carbonates in ores range from -4.6 to -2.5‰. Oxygen and hydrogen isotope data revealed that the ${\delta}^{38}O_{H_2O}$ and ${\delta}D$ values of ore fluids decreased gradually with time from 14.7 to 1.8‰ and -85 to -73‰ (skarn stage), and from 11.1 to -0.2‰ and -87 to -80‰ (hydrothermal stage), respectively. This indicates that magmatic water was dominant during the early skarn mineralization but was progressively replaced by meteoric water during the later hydrothermal replacement.