• Title/Summary/Keyword: Light wavelength effect

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The effect of 4,4'-bis(N,N-diethylamino)benzophenone on the degree of conversion in liquid photopolymer for dental 3D printing

  • Lee, Du-Hyeong;Mai, Hang Nga;Yang, Jin-Chul;Kwon, Tae-Yub
    • The Journal of Advanced Prosthodontics
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    • v.7 no.5
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    • pp.386-391
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    • 2015
  • PURPOSE. The purpose of this preliminary study was to investigate the effects of adding 4,4'-bis(N,N-diethylamino) benzophenone (DEABP) as a co-initiator to a binary photoinitiating system (camphorquinone-amine) to analyze on the degree of conversion (DC) of a light-cured resin for dental 3D printing. MATERIALS AND METHODS. Cylindrical specimens (N=60, n=30 per group, ${\phi}5mm{\times}1mm$) were fabricated using bisphenol A glycerolate dimethacrylate (BisGMA) both with and without DEABP. The freshly mixed resins were exposed to light in a custom-made closed chamber with nine light-emitting diode lamps (wavelength: 405 nm; power: $840mW/cm^2$) for polymerization at each incidence of light-irradiation at 10, 30, 60, 180, and 300 seconds, while five specimens at a time were evaluated at each given irradiation point. Fourier-transform infrared (FTIR) spectroscopy was used to measure the DC values of the resins. Two-way analysis of variance and the Duncan post hoc test were used to analyze statistically significant differences between the groups and given times (${\alpha}$=.05). RESULTS. In the DEABP-containing resin, the DC values were significantly higher at all points in time (P<.001), and also the initial polymerization velocity was faster than in the DEABP-free resin. CONCLUSION. The addition of DEABP significantly enhanced the DC values and, thus, could potentially become an efficient photoinitiator when combined with a camphorquinone-amine system and may be utilized as a more advanced photopolymerization system for dental 3D printing.

The Effect of Sun Light on Color Bleaching of Red Pepper Powder (일광(日光) 노출(露出)이 고추 가루의 탈색(脫色)에 미치는 영향)

  • Chun, Jae-Kun;Suh, Chung-Sik
    • Korean Journal of Food Science and Technology
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    • v.12 no.2
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    • pp.82-87
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    • 1980
  • The red color bleaching phenomena of red pepper powder by the exposure to sun light were studied on the various factors such as drying methods of pepper and the storage conditions of pepper powder, relative humidities, particle sizes, and the amounts and qualities of light. The surface color of red pepper was rapidly bleached by the successive daily exposures until the color retention value (capsanthin remained/original capsanthin content) reached to 0.5, while that of dark storge showed a negligible change. The color changes were related with the cumulative solar energy at various water activities $(a_w)$. As decreasing $a_w$ below 0.5, the bleaching reaction was highly accelerated, and thereafter was slowly progressed. Sun lights transmitted by red-, yellow- and blue-gelatin filters, respectivly, bleached in different degrees and at the shorter wavelength light, the more color bleaching occurred. From this fact a red colored package film could be effectivly used for the color preservation purpose in the red pepper storage.

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Study on Optical Characteristics of Nano Hollow Silica with TiO2 Shell Formation

  • Roh, Gi-Yeon;Sung, Hyeong-Seok;Lee, Yeong-Cheol;Lee, Seong-Eui
    • Journal of the Korean Ceramic Society
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    • v.56 no.1
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    • pp.98-103
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    • 2019
  • Optical filters to control light wavelength of displays or cameras are fabricated by multi-layer stacking process of low and high index thin films. The process of multi-layer stacking of thin films has received much attention as an optimal process for effective manufacturing in the optical filter industry. However, multi-layer processing has disadvantages of complicated thin film process, and difficulty of precise control of film morphology and material selection, all of which are critical for transmittance and coloring effect on filters. In this study, the composite $TiO_2$, which can be used to control of UV absorption, coated on nano hollow silica sol, was synthesized as a coating material for optical filters. Furthermore, systematic analysis of the process parameters during the chemical reaction, and of the structural properties of the coating solutions was performed using SEM, TEM, XRD and photo spectrometry. From the structural analysis, we found that the 85 nm nano hollow silica with 2.5 nm $TiO_2$ shell formation was successfully synthesized at proper pH control and titanium butoxide content. Photo luminescence characteristics, excited by UV irradiation, show that stable absorption of 350 nm-light, correlated with a 3.54 eV band gap, existed for the $TiO_2$ shell-nano hollow silica reacted with 8.8 mole titanium butoxide solution. Transmittance observed on substrate of the $TiO_2$ shell-nano hollow silica showed effective absorption of 200-300 nm UV light without deterioration of visible light transparency.

Characterization of Optical Properties of Light-Emitting Diodes Grown on Si (111) Substrate with Different Quantum Well Numbers and Thicknesses

  • Jang, Min-Ho;Go, Yeong-Ho;Go, Seok-Min;Yu, Yang-Seok;Kim, Jun-Yeon;Tak, Yeong-Jo;Park, Yeong-Su;Jo, Yong-Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.313-313
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    • 2012
  • In recent years there have been many studies of InGaN/GaN based light emitting diodes (LEDs) in order to progress the performance of luminescence. Many previous literatures showed the performance of LEDs by changing the LED structures and substrates. However, the studies carried out by the researchers so far were very complicated and sometimes difficult to apply in practice. Therefore, we propose one simple method of changing the thickness and the numbers of multiple quantum wells (MQWs) in order to optimize their effects. In our research, we investigated electrical and optical properties by changing the well thickness and the number of quantum well (QW) pair in LED structures by growing the structure -inch Si (111) wafer. We defined the samples from LED_1 to LED_3 according to MQW structure. Samples LED_1, LED_2 and LED_3 consist of 5-pair InGaN/GaN (3.5 nm/ 4.5 nm), 5-pair InGaN/GaN (3 nm/4.5 nm) and 7-pair InGaN/GaN (3.5 nm/4.5 nm), respectively. We characterized electrical and optical properties by using electroluminescence (EL) measurement. Also, Efficiency droop was analyzed by calculating external quantum efficiency (EQE) with varying injection current. The EL spectra of three samples show different emission wavelength peaks, FWHM and the blueshift of wavelength caused by screening the internal electric field because of the effect of different MQW structure. The results of optical properties show that the LED_2 sample reduce the internal electric field in QW than LED_1 from EL spectra. the increase in the number of QW pairs reduces the strain and increase the In composition in MQW. And, the points of efficiency droop's peak show different trend from LED_1 to LED_3. It is related with the carrier density in active region. Thus, from the results of experiments, we are able to achieve high performance LEDs and a reduction of efficiency droop and emission wavelength blueshift by optimizing MQWs structure.

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A Study on the Effect on UV Exposure in Coastal Buildings (연안건축물의 자외선 노출에 따른 안전성 연구)

  • Kim, Taehwan;Uh, Jesun
    • Journal of the Society of Disaster Information
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    • v.17 no.2
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    • pp.195-205
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    • 2021
  • Purpose: The ultraviolet reflectance and transmittance of coastal building materials are one of the important factors of ultraviolet radiation in and out of coastal building. In this research, the ultraviolet spectral reflectance of many kinds of building materials was measured. Also, the relationships with the lightness, roughness, and chromaticity, which are surface characteristics, were reviewed and suggested. Method: In this study, according to the CIE classification, the ultraviolet region was defined as short-wavelength region UV-C(10nm~280nm), medium-wavelength region UV-B (280-315 nm), and long-wavelength region UV-A (315-400nm), and the visible light region was defined as (400nm~780nm). Spectrophotometer was used to continuously measure the reflectance from the ultraviolet region to the visible light region. Results: From the measurement results, the ultraviolet reflectance on Wood was shown to be about Visible 55-68%, UV-A* 7-12%, and UV-B 4-5%. Wall tiles are about Visible18-40%, UV-A* 8-20%, and UV-B* 7-8%. That on concrete was shown to be about Visible 37%, UV-A* 28%, and UV-B*19%. Conclusion: The ultraviolet reflectance can be estimated by visible reflectance. Also, it is important to select a variety of materials according to the application when blocking UV.

Deterioration Mechanism of Paper according to Sizing and Beating(I)-Influences of Sizing- (사이징과 고해에 따른 종이의 열화기구(제1보)- 사이징의 영향 -)

  • 김봉용
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.2
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    • pp.24-29
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    • 1998
  • This study was carried out in order to elucidate the deterioration mechanism of paper according to various sizing chemicals. No additive paper and four kinds of papers containing rosin-alum, alum only, alkylketene dimer(AKD)-cation polymer and cation polymer only were treated by UV light to study changes of water-resistant, optical and mechanical properties from the view points of natural deterioration of paper. Since rosin chemicals have UV absorption at the relatively long wavelength region, rosins are degraded to form hydrophilic groups such as carboxylic acid from their double bonds by UV treatments. These phenomena caused the decreasing of sizing degree and wetting time in case of rosin-sized paper, while the UV treatments brought about the slight increase of wetting time in rosin-free papers such as no additive, alum and kymene only paper owing to the auto-sizing effect. Optical properties were primarily influenced by sizing chemicals. Rosin-sized paper showed lower brightness after UV and near UV treatment because of its UV instability.

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Highly Miniaturized On-Chip $180^{\circ}$ Hybrid Employing Periodic Ground Strip Structure for Application to Silicon RFIC

  • Yun, Young
    • ETRI Journal
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    • v.33 no.1
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    • pp.13-17
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    • 2011
  • A highly miniaturized on-chip $180^{\circ}$ hybrid employing periodic ground strip structure (PGSS) was realized on a silicon radio frequency integrated circuit. The PGSS was placed at the interface between $SiO_2$ film and silicon substrate, and it was electrically connected to top-side ground planes through the contacts. Owing to the short wavelength characteristic of the transmission line employing the PGSS, the on-chip $180^{\circ}$ hybrid was highly miniaturized. Concretely, the on-chip $180^{\circ}$ hybrid exhibited good radio frequency performances from 37 GHz to 55 GHz, and it was 0.325 $mm^2$, which is 19.3% of a conventional $180^{\circ}$ hybrid. The miniaturization technique proposed in this work can be also used in other fields including compound semiconducting devices, such as high electron mobility transistors, diamond field effect transistors, and light emitting diodes.

Analysis of Hematoporphyrin Derivative by Design and Manufacture of High Resolution Charge Coupled Device in Spectrometry (분광기에 고 분해능 Charge Coupled Device의 설계 및 제작에 의한 Hematoporphyrin Derivative의 분석)

  • Kim, Ki-Jun
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.1
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    • pp.77-83
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    • 2005
  • The influence of fluorescence, scattering, and absorbance in turbid material by light scattering was interpreted by the scattered fluorescence intensity and wavelength. The effect of optical property in scattering media was investigated. It is very important to study the charge coupled device(CCD) in spectrometry because we can use the molecular energy level, molecular structure, absorption or emission, intermolecular reaction, weakly bound molecular energy, photochemistry, fluorescence and photodynamic therapy. CCD is very essential to study the molecular structure and medical engineering combined laser spectroscopy in the modem physical and chemistry. Accordingly, this study has designed and manufactured the electromagnetic spectrometry with CCD, and has analyzed the hematoporphyrin derivative.

A Variational Framework for Single Image Dehazing Based on Restoration

  • Nan, Dong;Bi, Du-Yan;He, Lin-Yuan;Ma, Shi-Ping;Fan, Zun-Lin
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.10 no.3
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    • pp.1182-1194
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    • 2016
  • The single image dehazing algorithm in existence can satisfy the demand only for improving either the effectiveness or efficiency. In order to solve the problem, a novel variational framework for single image dehazing based on restoration is proposed. Firstly, the initial atmospheric scattering model is transformed to meet the kimmel's Retinex variational model. Then, the green light component of image is considered as an input of the variational framework, which is generated by the sensitivity of green wavelength. Finally, the atmospheric transmission map is achieved by multi-resolution pyramid reduction to improve the visual effect of the results. Experimental results demonstrate that the proposed method can remove haze effectively with less memory consumption.

The Effect of the Plasma Treatment in ITO Film to reduce impurities in LCOS Imager

  • Kim, Joo-Hyung;Kim, Sang-Ha;Cho, Chul-Sik
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.541-544
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    • 2002
  • The reflective liquid crystal(LC) imager in one panel Liquid Crystal on Silicon(LCoS) System must have the properties such as fast response time, high contrast ratio(C/R) and voltage holding ratio(VHR) which are more related to the lifetime of imager than the others. As the high-output light including a short wavelength from UHP lamp is exposed to LCoS imager, the indium metal impurities, which decrease the C/R and VHR, are diffused from ITO thin film on glass. To ensure the high reliable LCoS imager for HD projection TV, we have studied the effects of the plasma treatment on ITO film to reduce impurities in imager.

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