• Title/Summary/Keyword: LiBr-water solution

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Approximate Solution of Absorption Process in an Air-Cooled Vertical Plate Absorber (공냉식 수직평판형 흡수기의 흡수과정에 대한 근사해법)

  • Jeong, E.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.6 no.4
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    • pp.453-462
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    • 1994
  • An unsteady quasi one-dimensional model of momentum, heat and mass transfer in a falling film of a vertical plate absorber which is cooled by air was developed using the integral method. Energy conservation of the absorber wall is considered in the model. The model can predict absorption rate, film thickness and mean velocity as well as concentration and temperature profiles. Predictions of steady state temperature and concentration profiles for LiBr/water system for constant wall temperature condition are in good agreement with the two-dimensional finite difference method solutions. Effects of operating conditions, such as convective heat transfer coefficient between the cooling air and the absorber wall, cooling air temperature and film thickness at inlet, on absorption rate of water vapor into LiBr/water solution were shown.

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Performance analysis of a cooling system with refrigerant in a marine absorption refrigerator (선박용 흡수식 냉동기의 냉매적용 냉각 시스템 성능 분석)

  • Yun, Sang-Kook
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.4
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    • pp.282-287
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    • 2016
  • Recently in order to protect the ocean environment and to reduce energy consumption, shipbuilders have been developing highly economized ships. This research analyzed the possibility of adopting the onshore absorption refrigerator to offshore ships having a cooling system with refrigerant by using the waiste heat of the engine jacket cooling water instead of compression refrigerators. The results showed that R236fa could be a suitable medium for absorbing the heat of the absorber and condenser in an absorption refrigerator. The cooling system using R236fa achieved a high COP of 0.798, which is 15% and 5% higher than an air cooling system with a cooling tower and a water cooling system with a heat exchanger, respectively. The cooling system with R236fa achieved high efficiency with a 25% reduction in flow rate of LiBr solution and only 15.7% flow rate of cooling medium as compared to the water cooling system. The heating of sea water by the engine jacket water flowing out from the generator can prevent the crystallization of LiBr solution due to the low temperature of sea water.

A Study on the Characteristics of Local Corrosion for Gas Absorption Refrigeration and Hot Water Systems in LiBr-$H_2O$ Working Fluids (LiBr작동유체 중에서 가스흡수식 냉온수기의 국부부식 특성에 관한 연구)

  • Uh- Joh Lim;Ki-Cheol Jeong;Byoung-Du Yun
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.6
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    • pp.714-720
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    • 2003
  • Due to the electric power shortage in summer season and regulation of freon refrigerant, the application of gas absorption refrigeration and hot water systems are considerably increasing trend. But, this system consists of condenser, heat exchanger, supply pipe and radiator etc. which are easily corroded by acidity and dissolved oxygen and gases. In result, this system occurs scale attachment and corrosion damage like pitting and crevice corrosion. In this study, electrochemical polarization test of heat exchanger tubing material (copper, aluminium brass, 30% cupronickel(30% Cu-Ni)) was carried out in 60% lithium bromide solution at $95^{\circ}C$. As a result of polarization test, corrosion behavior by impressed potential and local corrosion. such as galvanic corrosion, pitting corrosion behavior, of tubing materials was investigated. The main results obtained are as follows: (1) The effect of pitting and crevice corrosion control of 30% cupronickel in 60% LiBr solution at $95^{\circ}C$ is very excellent. (2) Dissimilar metal corrosion of 30% cupronickel coupling to aluminium bronze is the most sensitive. (3) Current density behavior of tube materials by impressed potential is high in order of copper > aluminium brass > 30% cupronickel.

Development of High Efficiency Cycle by Combining Double-Effect with Single-Effect Absorption Chiller Systems (이중 효용과 일중 효용을 복합한 다단 재생 고효율 흡수식 냉동 사이클 개발)

  • Yun, Sang Kook
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.7
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    • pp.360-365
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    • 2017
  • Recently, development efforts of triple-effect absorption chiller have been increased in order to improve the efficiency of double-effect absorption chiller. However, triple-effect absorption chiller has some disadvantages, including high corrosion characteristic of LiBr solution at high temperature of $200^{\circ}C$. Moreover, it is necessary to develop new components for operation under high pressure of 2 bars even though COP is increased to 1.6 or 1.7. The objective of this study was to introduce a new system by combining double effect absorption chiller with single effect absorption chiller with multi-generators using bypass flow of LiBr dilute solution to $3^{rd}$ generator to overcome the disadvantages of triple-effect chiller and improve energy efficiency. Results indicate that the new absorption cycle had a much higher efficiency than double-effect chiller system, showing significant improvement when bypass solution flow rate of 25% was applied to the $3^{rd}$ generator using the main dilute solution of the absorber. The COP of the new chiller system was found to be 1.438, which was 21.7% higher than that (1.18) of the present double-effect system. The COP was decreased when solution by-pass rate to the $3^{rd}$ generator was increased. In addition, lower cooling water temperature caused higher COP. Therefore, the multi-generator system with by-pass solution might be an excellent chiller alternative to triple-effect absorption chiller with higher efficiency.

Thermodynamic Analysis of a Double-Effect Absorption Heating System Using Water-LiCl-$CaCl_2-Zn(NO_3)_2$ Solution at Solar Evaporator Heating (LiCl-$CaCl_2-Zn(NO_3)_2$ 수용액을 사용하는 흡수 2중효용 시스템에서 태양열을 증발기 열원으로 사용하는 난방기의 열역학적 해석)

  • Won, Seung-Ho
    • Journal of the Korean Solar Energy Society
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    • v.27 no.3
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    • pp.87-94
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    • 2007
  • In this paper, with water-LiCl-$CaCl_2-Zn(NO_3)_2$ mixture which utilizes solar energy at the evaporator heat source, a thermodynamic analysis was performed to provide design data for a double-effect absorption heating system. A comparative study of the water-LiCl-$CaCl_2-Zn(NO_3)_2$ mixture against the water-LiBr pair was conducted by a computer simulation. The computer simulation is based on mass, material and heat balance equations for each part of the system. Coefficients of performance and flow ratios for effects of different operating temperatures are investigated. It is found that the heating COP is higher for the water-LiCl-$CaCl_2-Zn(NO_3)_2$ mixture than for the water-LiBr pair, and FR is lower for the former.

Effect of a non-absorbable gag on the absorption process in a vortical tube absorber (수직원관형 흡수기의 흡수과정에 미치는 비흡수가스의 영향)

  • 허기준;정은수;정시영
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.10 no.4
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    • pp.456-465
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    • 1998
  • Effect of a non-absorbable gas on the absorption process in a vertical tube absorber was investigated numerically. The water vapor mined with air as the non-absorbable gas is absorbed into LiBr/water solution film. The flow is assumed to be laminar and fully developed in both liquid and gas phases. The diffusion and energy equations were solved in both phases to give the temperature and concentrations, from which heat and mass fluxes were determined. It was shown that the local absorption rate decreases as the mass fraction of air in water vapor increases. The vapor pressure of water at the liquid-vapor interface reduces significantly since the non-absorbable gas is accumulated near the interface. The effect of non-absorbable gases on absorption rate becomes larger as the mass flow rate of the vapor decreases. For small amount of non-absorbable gases the total absorption rate of water vapor increases as the mass flow rate of the vapor decreases. Total absorption rate increases as the mass flow rate of the vapor increases for large concentration of non-absorbables at the inlet of an absorber.

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Characteristics of Absorption and Heat Transfer for Film Falling along a Vertical Inner Tube (3rd. Report, Refrigerating Capacity in Evaporator and Heating Capacity in Absorber) (수직관(수직관)내를 흘러내리는 액막식흡수기(液膜式吸收器)의 흡수(吸收) 및 열전달(熱傳達) 특성(特性) (제(第)3보(報), 증발기(蒸發器)의 냉동능력(冷凍能力)과 흡수기(吸收器)의 난방능력(暖房能力)))

  • Ohm, K.C.;Kashiwagi, Takao;Seo, J.Y.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.6 no.3
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    • pp.175-181
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    • 1994
  • This paper deals with the correlation of absorption rate in absorber and evaporation rate in evaporator. The evaporator consists of a copper tube of 10mm dia, and 600mm long and chilled water flowing through the tube is fed by the chilled water circulator. The flowrate of LiBr-water solution in the absorber plays a significant role in determining the magnitude of the heat transfer rate from chilled water to refrigerant There exists a flowrate of solution which has a maximum value of heat transfer. It is interesting to note that the absorption rate of absorber increases with increasing the heat transfer rate of the evaporator. Also, absorption rate increases with evaportation rate, and the ratio(the former/the other) depends on the inlet temperature of LiBr-water solution in the absorber. The heating capacity in the absorber is higher than the refrigerating capacity in the evaporator.

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Analysis of heat and mass transfer in a vertical tube absorber cooled by air (공랭형 수직원관 흡수기에서의 열 및 물질전달 해석)

  • Kim, Seon-Chang;O, Myeong-Do;Lee, Jae-Heon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.10
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    • pp.3293-3303
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    • 1996
  • Numerical analyses have been performed to estimate the absorption heat and mass transfer coefficients in absorption process of the LiBr aqueous solution and the total heat and mass transfer rates in a vertical tube absorber which is coolING ed by air. Axisymmetric cylindrical coordinate system was adopted to model the circular tube and the transport equations were solved by the finite volume method. Absorption behaviors of heat and mass transfer were analyzed through falling film of the LiBr aqueous solution contacted by water vapor in tube. Effects of film Reynolds number on heat and mass transfer coefficients have been also investigated. Especially, effects of tube diameter have been considered to observe the total heat and mass transfer rates through falling film along the tube. Based on the analysis it has been found that the total mass transfer rate increases rapidly in a region with low film Reynolds number(10 ~ 40) as the film Reynolds number increases, while decreases beyond that region. The total heat and mass transfer rates increase with increasing the tube diameter.

Characteristics of Absorption and Heat Transfer for Film Falling along a Vertical Inner Tube (2nd. Report, Characteristics of Heat Transfer) (수직관내(垂直管內)를 흘러내리는 액막식(液膜式) 흡수기(吸收器)의 흡수(吸收) 및 열전달특성(熱傳達特性)(제(第)2보(報) 열전달특성(熱傳達特性)))

  • Ohm, K.C.;Rie, D.H.;Choi, G.G.;Kasiwagi, Takao;Seo, J.Y.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.5 no.4
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    • pp.257-264
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    • 1993
  • This is the second report of a three part study on the absorption and heat transfer characteristics of absorber, the correlation of refrigerating capacity and heating capacity. The 2nd report deals with the heat transfer characteristics of a vertical falling film type absorber of inner copper tube. The solute is LiBr-Water solution(60wt%) and the solvent is water vapor. The film Reynoles numbers are varied in the range of 35~130. The states of LiBr solution at the top of absorber are supercooled liquid and superheated liquid. The results are summarized as follows ; Heat transfer results reveal that for the absorption of falling film, the state of LiBr solution appears to be influential in determining the heat transfer. Thus, for the state of supercooled liquid, heat transfer coefficient decreases with increasing the film Reynolds number, but in the condition of superheated liquid, it increases conversely. The mass transfer coefficients that were presented in the 1st.report and heat transfer coefficients of this paper are presented as the dimensionless correlation. The optimum water flowrate which brings about maximum value of heat flux in the film exists, and that increases with increasing the cooling water temperature.

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Analysis of Thermodynamic Design Data for Cooling of Double -Effect Absorption System of Solar Energy using LiBr - water and Ethylene Glycol Mixture (흡수액으로 에틸렌글리콜이 혼합되고 태양열을 이용한 이중효용 흡수식 시스템의 냉방 특성해석)

  • Won, Seung-Ho;Park, Sang-Il
    • Journal of the Korean Solar Energy Society
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    • v.23 no.4
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    • pp.45-54
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    • 2003
  • For cooling of double effect absorption heat pump system of solar heating source, analysis of thermodynamic design data has been done to find the property of Libr-water + ethylene Glycol mixture for working fluid by computer simulation. Derived thermodynamic design data, enthalpy based coefficient of performance and flow ratio for possible combinations of operating temperature for water - LiBr and Ethylene Glycol mixture ($H_2O$ : CHO ratio 10:1 by mole) by computer simulation are done. The obtained results, COP and mass flow ratio of the water - lithium bromide - ethylene glycol system, are compared with data for the water-Libr pair solution.