• Title/Summary/Keyword: LiBr-water solution

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Approximate solutions on the absorption process of an aqueous LiBr falling film : effects of vapor flow (리튬브로마이드 수용액 유하액막의 흡수과정에 대한 근사 해법 : 증기 유동의 영향)

  • Kim, B.J.;Lee, C.W.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.9 no.2
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    • pp.144-152
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    • 1997
  • Film absorption involves simultaneous heat and mass transfer in the vapor-liquid system. In the present work, the absorption process of water vapor by an aqueous soluton of LiBr flowing inside of the vertical tube was investigated. The continuity, momentum, energy and diffusion equations for the solution film and vapor were formulated in integral forms and solved numerically. The model could predict the film thickness, the pressure gradient, and the heat and mass transfer rate. Particularly the effects of vapor flow conditions on the absorption process were investigated in terms of the vapor Reynolds number. As the vapor Reynolds number increased, the shear stress at the vapor-solution interface also increased. Consequently solution film became thinner at higher vapor flowrate under the co-currentflow condition. Thinner film was capable of higher heat transfer to the wall and leaded to higher absorption rate of the water vapor into the solution film.

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Thermodynamic Analysis of an Absorption Heat Pump System with New Working Pairs[I] (1, 2종 흡수식 히트펌프의 작동 매체에 따른 성능 해석[I])

  • Won, S.H.;Lee, W.Y.;Chung, H.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.1 no.3
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    • pp.219-227
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    • 1989
  • Performance analysis of an absorption heat pump system for solar energy recovery has been done by computer simulation to find improved working pairs. Based on the thermodynamic analysis, the coefficient of performance and mass flow ratio have been calculated to compare two aqueous solutions [LiCl-water, $LiCi-CaCl_2-Zn(NO_3)_2$-water] which were developed for cooling by others, with the conventional LiBr-water solution. As a result of this analysis, the performances of the new aqueous solutions were found to be better than that of LiBr-water solution not only in cooling systems, but also in heating and in heat transformer systems. Their theoretical thermodynamic performance data were given here with.

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Coupled Heat and Mass Transfer during the Absorption of Water Vapor into LiBr-H2O Liquid Solution Flowing down the Outside of the Horizontal Cylinder (수평원관상의 LiBr-수용액에 수증기가 흡수될때의 열 및 물질전달)

  • Lee, K.S.;Seo, S.C.;Kim, Y.I.;Park, D.K.
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.17 no.2
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    • pp.140-149
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    • 1988
  • The problem of heat and mass transfer accompanying the absorption of water vapor into LiBr-$H_2O$ liquid solution flowing over the outside of the horizontal cylinder was theoretically studied to understand the absorption process occuring in the absorber of the absorption heat pump. Numerical results are presented for various quantities of interest relating to temperature, concentration, heat flux and mass flux. Also, the effects of mass flowrate, initial average velocity, and the radius of the cylinder were investigated.

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Coupled Heat and Mass Transfer in Absorption of Water Vapor into LiBr-$H_2O$ Solution Flowing on Finned Inclined Surfaces

  • Seo, Taebeom;Cho, Eunjun
    • Journal of Mechanical Science and Technology
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    • v.18 no.7
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    • pp.1140-1149
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    • 2004
  • The absorption characteristics of water vapor into a LiBr-H$_2$O solution flowing down on finned inclined surfaces are numerically investigated in order to study the absorbing performances of different surface shapes of finned tubes as an absorber element. A three-dimensional numerical model is developed. The momentum, energy, and diffusion equations are solved simultaneously using a finite difference method. In order to obtain the temperature and concentration distributions, the Runge-Kutta and the Successive over relaxation methods are used. The flat, circular, elliptic, and parabolic shapes of the tube surfaces are considered in order to find the optimal surface shapes for absorption. In addition, the effects of the fin intervals and Reynolds numbers are studied. The results show that the absorption mainly happens near the fin tip due to the temperature and concentration gradient, and the absorbing performance of the parabolic surface is better than those of the other surfaces.

Characteristics of Absorption and Heat Transfer for Film Falling along a Vertical inner Tube (1st Report, Characteristics of Absorption) (수직관내(垂直管內)를 흘러내리는 액막식(液膜式) 흡수기(吸收器)의 흡수(吸收) 및 열전달특성(熱傳達特性) (제(第) 1 보(報), 흡수특성(吸收特性)))

  • Ohm, K.C.;Kashiwagi, T.;Seo, J.Y.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.5 no.1
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    • pp.1-9
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    • 1993
  • Mass transfer coefficients were measured for water vapor absorption into a LiBr-Water solution of 60wt% flowing down an absorber of vertical tube type. The absorber is copper tube of 25mm inner diameter and 1000mm length. The film Reynolds number were varied in the range of 35~130. The solution is fed from the top of the pipe, and the conditions of solution are supercooled liquid and superheated liquid. As results, the flowrates of LiBr solution which takes peak value of average absorption mass flux exist. Mass transfer coefficients decrease with increasing the flowrate of LiBr solution, and the decrease rate in the case of supercooled liquid is large as compared with that in the case of superheated liquid. But the absorption rate of supercooled liquid is decidedly superior to that of superheated liquid.

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Experimental investigation of enhanced heat and mass transfer toy LiBr/$H_2O$ absorber (LiBr/$H_2O$계 흉수기의 흡수촉진에 관한 실험적 연구)

  • 설원실;권오경;윤정인
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.10 no.5
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    • pp.581-588
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    • 1998
  • An experimental study of the absorption process of water vapor into Lithium Bromide solution was performed. For the purpose of development of high performance absorption chiller-heater utilizing Lithium Bromide solution as working fluid, the absorber is the most effective to improve the performance of an absorber because it requires the largest heat transfer area in an absorption chiller-heater system. This paper introduces bare tube and floral tube for the absorber of absorption chiller-heaters. floral tube has higher heat and mass transfer performance than bare tube conventionally used in absorbers and the it is expected to perform high heat and mass transfer. This paper will provide important information on the selection of absorber tubes in commercial absorption chiller -heaters.

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Solubility, vapor pressure, duhring and enthalpy-concentration charts of$H_2$O/(LiBr+$CaC1_2$) solution as a new working fluid ($H_2$O/(LiBr+$CaC1_2$) 3성분계 작동매체의 용해도, 증기압측정 및 듀링 선도, 엔탈피-농도 선도 작성)

  • 이형래;구기갑;정시영
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.10 no.6
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    • pp.666-673
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    • 1998
  • Solubilities (LiBr+$CaC1_2$) in water were measured at temperatures form 267.51 to 306.17K for $CaC1_2$ (LiBr+$CaC1_2$)=0.24 by mole. Experimental data were correlated with polynomial equations. Average absolute deviations between the measured and calculated values were 0.31% at concentration smaller than 60wt% and 0.41% at concentration larger than 60wt%, respectively. Vapor pressures were measured at temperatures from 296.75 to 436.75K and concentrations from 40 to 70wt%. Vapor pressure data were fitted to a Antoine-type equation and average absolute deviation was 2.98%. The P-T-X chart and H-T-X chart of $H_2O$/(LiBr+$CaC1_2$) system were constructed by using the correlation equations of solubility, vaper pressure, and heat capacity. The P-T-X chart indicates that $H_2O$/(LiBr+$CaC1_2$) system has potential as a possible working fluid for air-cooled absorption chillers.

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Effects of Non-absorbable Gases in the Absorption of Water Vapor by Aqueous LiBr Solution Film on Horizontal Tube Banks

  • Kwon, Ky-Seok;Kim, Byong-Joo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.9 no.2
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    • pp.19-27
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    • 2001
  • In the present study, the effects of film Reynolds number (60∼200) and volumetric content of non-absorbable gases (0∼10%) in water vapor on the absorption process of aqueous LiBr solution were investigated experimentally. The formation of solution film on the horizontal tubes of six rows was observed to be complete for Re>100. Transition film Reynolds number was found to exist above which the Nusselt number and Schmidt number diminishes with solution flow rate. As the concentration of non-absorbable gases increased, mass transfer rate decreased more seriously than heat transfer rate did. the degradation effects of non-absorbable gases seemed to be significant especially when small amount of non-absorbable gases was introduced to the pure water vapor.

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Cycle simulation of a triple effect LiBr/water absorption chiller (삼중효용 LiBr/물 흡수식 냉방기의 사이클 시뮬레이션)

  • 조광운;정시영;정은수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.10 no.1
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    • pp.79-87
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    • 1998
  • Basic design of a 50USRT(175㎾) triple effect absorption chiller driven by hot gas has been carried out for both parallel and series flow cycles. Parallel flow cycle showed higher COP, however, the temperature in the generator was also higher than that in series flow cycle. Dynamic operation behavior of a parallel flow system at off-design conditions, such as the change in heat transfer medium temperature or the construction change of the system components, has been investigated in detail. It was found that the cooling capacity was seriously decreased by reducing hot gas flow rate and UA-value in the high temperature generator. However, the system COP was improved, because thermal load in the system components was reduced. The COP and the cooling capacity was found to be improved as cooling water temperature decreased or chilled water temperature increased. The optimum ratio of solution distribution could be suggested by considering the COP, the cooling capacity and the highest temperature in the system, which is critical for corrosion.

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Experimental Study on Heat and Mass Transfer Characteristics in bundles of horizontal absorption tubes (수평관군 흡수기의 열 및 물질 전달특성에 관한 실험적 연구)

  • 설원실;정용욱;문춘근;윤정인
    • Journal of Advanced Marine Engineering and Technology
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    • v.24 no.3
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    • pp.113-120
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    • 2000
  • On the absorber of absorption chiller/heater, LiBr solution at high concentration is sprinkled on a bundle of horizontal tube cooled by cooling water. In this case, the conditions of LiBr solution and cooling water have an influence on heat/mass transfer coefficient in this system. Therefor it is important to find optimal operation conditions of absorption chiller/heater to save energy. Heat and mass transfer coefficient increased with the increase of solution flow rate, and also heat and mass transfer rate increased but overall heat and mass transfer coefficient decreased by increasing the solution concentration within the experimental range. The superheating of the solution resulted in superior heat transfer character to a state of equilibrium from the point of heat flux and overall heat transfer coefficient.

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