• Title/Summary/Keyword: LiBr

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Effects of Non-Absorbable Gases on the Absorption Process of Aqueous LiBr Solution Film in a Vertical Tube (I) (수직관내 리튬브로마이드 수용액막의 흡수과정에 대한 비흡수가스의 영향)

  • Kim, Byeong-Ju;Lee, Chan-U
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.4
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    • pp.489-498
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    • 1998
  • Among the heat/mass exchange units composing an absorption system, the absorber, where the refrigerant vapor is absorbed into the liquid solution is the one least understood. In the present study, the effects of non-absorbable gas on the absorption process of aqueous lithium bromide solution falling film inside a vertical tube were experimentally investigated. In the range of film Reynolds number of 30 ~ 195, heat and mass transfer characteristics were investigated as a function of non-absorbable gas volumetric concentration, 0.2 ~ 20%. An increase of non-absorbable gas volumetric concentration degraded the mass transfer rate dramatically in the absorption process. The reduction of mass transfer rate was significant for the addition of small amount of non-absorbable gas to the pure vapor. At film Reynolds number of 130, an increase of non-absorbable gas concentration from 0.2 to 6.0% resulted in the decrease of mass transfer rate by 36% and 20% of non-absorbable gas by 59%. However the decrease of film Nusselt number with the increase of volumetric concentration of non absorbable gas was relatively smaller than the decrease of Sherwood number. Critical film Reynolds number was identified to exist for the maximum heat and mass transfer regardless of the volumetric concentration of non-absorbable gases.

Characterization of Chemical Properties of Precipitation at Busan, Korea, 2009 (2009년 부산지역 강수의 화학적 특성)

  • Jung, Woon-Seon;Park, Sung-Hwa;Kang, Deok-Du;Lee, Dong-In;Kim, Dongchul
    • Journal of Environmental Science International
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    • v.23 no.1
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    • pp.69-79
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    • 2014
  • The seasonal variation of pH and ion components in precipitation were investigated from January to December 2009 at Busan, Korea. The precipitation was acidic with a volume-weighted mean pH concentration of 5.32, which ranged from 3.79 to 8.66. The volume-weighted mean conductivity showed 86.77 ${\mu}S/cm$ and indicated higher concentration about 96.69 ${\mu}S/cm$ in summer. The volume-weighted mean equivalent concentration of components followed the order: $K^+$ > $Ca^{2+}$ > $nss-Ca^{2+}$ > $NH_4^+$ > $Mg^{2+}$ > $Na^+$ > $Li^+$ in cations and $Cl^-$ > $SO_4^{2-}$ > $nss-SO_4^{2-}$ > $NO_3^-$ > $NO^{2-}$ > $F^-$ > $Br^-$ in anions. Particularly, concentration of $K^+$ and $Cl^-$ showed 56 and 78 % in cations and anions. The higher concentration in $K^+$, $Na^+$, $Mg^{2+}$ and $Cl^-$ were shown in Busan city as compared to the other cities. The neutralization factors have been found to have higher value for potassium ion in winter compared with different seasons, indicating significant neutralization of acidic components over the region by potassium. Therefore, the precipitation characteristics at Busan had both continental and coastal as consequence of pH, conductivity and ionic analyses.

Trace Element Analysis by Neutron Activastion Analysis in the Human Cancer Tissue (폐암조직에서 중성자 방사화 분석법을 이용한 미량 원소 분석)

  • Lim, Sang-Moo;Zo, Jae-Il;Shim, Young-Mog;Chung, Young-Ju;Cho, Seung-Yeon;Chung, Yong-Sam
    • The Korean Journal of Nuclear Medicine
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    • v.27 no.1
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    • pp.104-111
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    • 1993
  • Trace elements are important components in the biological system, as a structural material and metabolic controller. Neutron activation analysis (NAA) with high neutron flux and high energy resolution Ge (Li) detector coupled to multichannel analyzer (MCA) has been one of the most accurate method for the determination of ultra-trace level components, and is applicable to biological material. In human body, the NAA can be used for quantitation of trace elements in various organs and tissue with endocrinological and metabolic disease and industrial metal poisoning. In this study, Triga Mark III nuclear reactor in Korea Atomic Research Institute was used for quantitation of trace eleement in human lung cancer tissues by neutron activation analysis. In the squamous cell carcinoma tissues, Br, Hg, La, Sb, Sc, Cl, Fe and I content were lower than normal lung tissues, and K, Rb and Se content were higher. In the adenocarcinoma tissues, Fe, Au, La, Sc and Zn content were lower than normal lung tissues, and Rb, Co and Se content were higher. Rb content was higher in the adenocarcinoma tissues than in the squamous cell carcinoma tissues. Fe and Na content were higher in the squamous cell carcinoma tissues than in the adenocarcinoma tissues.

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Performance analysis for the Characteristics of Double Stage Evaporator/Absorber for Large temperature Difference Absorption System (흡수식 대온도차 시스템에서 2단 증발/흡수기의 성능 특성에 관한 수치적 연구)

  • Park, Chan-Woo;Kang, Yong-Tae;Im, Ick-Tae;Moon, Sang-Done
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.304-308
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    • 2008
  • The optimal design of two stage evaporation & absorption system which is related to the large temperature difference system was investigated numerically in the absorption refrigeration system. The concentrations at inlet & oulet of absorber are 62.9% and 56.9%, but in two stage absorption system the values are 62.2% and 56.2%. Therefore strong solution & weak solution became diluted than the standard value. The amount of weak solution circulation can be reduced in absorption refrigeration system, and the sensible heat load is more reduced to enhance the COP of system. As UAR is increased, COP becomes larger, and this means the role of top section is more important than bottom section in two stage evaporation & absorption system. But the increase of COP becomes slower at 0.7 of UAR ratio. The performance of Type2 is higher than Type1 in COP with the flow direction of cooling waters. This phenomena is due to the active absorption of vapor -absorption & lower temp. cooling water is more effective. The pressure at bottom section becomes higher & that at top section becomes lower and therefore the circulation rate can be diminished more.

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Optimum design of the Characteristics of Double Stage Evaporator/Absorber for Large temperature Difference Absorption System (냉수 대온도차 흡수식 냉동기용 2단 증발기/ 흡수기 최적 설계)

  • Park, Chan-Woo;Im, Ick-Tae;Kang, Yong-Tae
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.203-211
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    • 2008
  • The optimal design of two stage evaporation & absorption system which is related to the large temperature difference system was investigated numerically in the absorption refrigeration system. The concentrations at inlet & oulet of absorber are 62.9% and 56.9%, but in two stage absorption system the values are 62.2% and 56.2%. Therefore strong solution & weak solution became diluted than the standard value. The amount of weak solution circulation can be reduced in absorption refrigeration system, and the sensible heat load is more reduced to enhance the COP of system. As UAR is increased, COP becomes larger, and this means the role of top section is more important than bottom section in two stage evaporation & absorption system. But the increase of COP becomes slower at 0.7 of UAR ratio. The performance of Type2 is higher than Type1 in COP with the flow direction of cooling waters. This phenomena is due to the active absorption of vapor -absorption & lower temp. cooling water is more effective. The pressure at bottom section becomes higher & that at top section becomes lower and therefore the circulation rate can be diminished more.

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Studies on Silk Fibroin Membranes(I) -Structure of Silk Fibroin Membranes and Their properties- (Silk Fibroin 막에 관한 연구(I) -Silk Fibroin막의 구조특성-)

  • 최해욱;박수민;김경환
    • Textile Coloration and Finishing
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    • v.6 no.1
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    • pp.62-70
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    • 1994
  • Silk fibroin was dissolved in 9.3 M LiBr aqueous solution at 4$0^{\circ}C$ for 1 hour. The dissolved silk fibroin was regenerated by casting the dialyzed solution into the membrane. The freshly prepared silk fibroin membrane was soluble in water and was. mainly consisted of random coil conformation. By the treatments in saturated water vapor at 3$0^{\circ}C$ and in 75% ethanolic aqueous solution (V/V), the insoluble membranes were obtained and the structure and morphology of those were investigated for the structure by means of X-ray diffraction analysis, infrared spectroscopy, thermal analysis. Rheovibron and scanning electron micrograph. Silk II type crystals were obtained by treating amorphous silk fibroin membrane in the random coil conformtion with 75% ethanol solution(V/V). Crystallization to silk II type crystals occured even after a few minutes, and a large number of silk II type crystals were formed after 30 mins. On the other and, the membrane treated in saturated water vapor was composed of the mixtures of silk I and silk II type crystals. A large number of silk I and silk II type crystals were formed after 24 hours. The micro brownian motion in the amorphous regions of silk fibroin membrane started at about 175~185$^{\circ}C$. $\alpha$ dispersion appeared at about 20$0^{\circ}C$ in the amorphous membrane, and at about 22$0^{\circ}C$ in the crystalline membrane. The crystallization of random coil conformation to silkII type crystals occured at about 215$^{\circ}C$. The surface, bottom and cross-section of the membranes were observed by scanning electrom microscope. Fine forms alike spherulites appeared at the surface of crystalline membrane.

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A Study on the Shrinkage of Silk Fabric by $Ca(NO_3){_2}$ Solution

  • Choi, Se-Min;Shin, Yu-Ju;Kim, Jong-Jun;Jeon, Dong-Won
    • Journal of Fashion Business
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    • v.13 no.3
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    • pp.136-148
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    • 2009
  • The phenomenon of the shrinkage of silk fibers induced by inorganic salts including LiBr, $Ca(NO_3){_2}$, and $CaCl_2$, has been studied up to the present as one of the finishing methods of silk. It is expected that the shrinkage phenomenon may greatly contribute to the realization of the high sensibility of silk fibers. Especially the shrinkage enables the expression of three-dimensional appearance of silk fabrics along with the improvements in dimensional stability, resilience in stretching, and comfort. Numerous theoretical studies on the contraction phenomenon by $Ca(NO_3){_2}$ have been conducted so far. These studies have focused mostly on the silk fibers. It is difficult to find studies on silk fabrics. The negative aspects of the finishing are such as strength drop, yellowish discoloration, and fiber damage. These should also be considered as well as the positive aspects. In this study, the phenomenon of salt shrinkage is diversely reviewed by applying $Ca(NO_3){_2}$ solution for the silk fabrics as objects. The changes in the air permeability, thickness, and color were investigated with focus on the shrinkage of the silk fabrics according to the changes in treatment conditions. Some findings from this study are as follows: Within short period of time at the initiation of salt shrinkage, the salt shrinkage proceeds effectively. In the case of concentration of 47.4%, or 46.3% of $Ca(NO_3){_2}$ solution, appropriate treatment time seems to be 20seconds, or $2{\sim}8$minutes, respectively. Excessive shrinkage is obtained when lower liquor ratio is adopted. As a result, the condition is acting extremely disadvantageously against the thickness and yellow discoloration aspects.

Sulfur Dioxide, Mineral Contents and Physicochemical Properties Generated during Manufacture of Bamboo Salt (죽염 제조공정에 따른 이산화황, 미네랄 함량 및 이화학적 특성)

  • Kim, Hag-Lyeol;Lee, Seong-Jae;Lee, Jung-Hee;Kim, In-Cheol
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.8
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    • pp.1248-1256
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    • 2014
  • The purpose of this study was to investigate the mechanisms of behind $SO_2$ formation and elevated cause of reducing power in purple bamboo salt (PBS) along with an analysis of physicochemical properties, content of sulfur compounds, oxidation reduction potential (ORP), mineral contents of salt type (MSS, mudflat solar salt; BS, bamboo salt), and addition of raw bamboo (RB). $SO_2$ content of 630 ppm was detected in PBS. $SO_2$ was not detected in MSS, BS, or RB, whereas $SO_2$ (782 ppm) from $K_2SO_4$ was detected after heating a NaCl, KCl, $MgCl_2$, $MgSO_4$, MgO, $CaCl_2$, $K_2SO_4$, and $FeSO_4$ with RB. $SO_2$ content of BS increased with baking time, and it originated from BSRB1 (13.88 ppm) to BSRB4 (109.13 ppm). $SO_3{^{2-}}$ originated only from MSSRB4 and BSRB2~BSRB4. Sulfate ion content decreased along with increasing $SO_2$ and sulfite ion contents. ORP increased with baking time of MSS and BS, and it was present at higher levels in BSRB4 (-211.40 mV) of BS than MSS. Insoluble content was higher in BS than MSS. Further, Ca, K, and Mg ion contents decreased in MSS and increased in BS with baking time. BSRB4 had 1.4 fold higher levels of Ca, 1.5 fold higher levels of Mg, and 1.8 fold higher levels of K than BS. Li, Al, Mn, Fe, and Sr in MSS as well as Al, Fe, and Ni in BS increased with baking time. Anions (Cl, $NO_3$, and Br) and heavy metals (Pb, Cd, Hg, and As) between MSS and BS were not significantly different. These results suggest that the reducing power of BS was due to $SO_2$ and sulfite ion. To increase the amounts of these compounds and reducing power, higher melting temperature and longer baking time are necessary along with BS, which is created by the addition of RB to roasted salt.

BSA-Seq Technologies Identify a Major QTL for Clubroot Resistance in Chinese Cabbage (Brassica rapa ssp. pekinesis)

  • Yuan, Yu-Xiang;Wei, Xiao-Chun;Zhang, Qiang;Zhao, Yan-Yan;Jiang, Wu-Sheng;Yao, Qiu-Ju;Wang, Zhi-Yong;Zhang, Ying;Tan, Yafei;Li, Yang;Xu, Qian;Zhang, Xiao-Wei
    • 한국균학회소식:학술대회논문집
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    • 2015.05a
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    • pp.41-41
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    • 2015
  • BSA-seq technologies, combined Bulked Segregant Analysis (BSA) and Next-Generation Sequencing (NGS), are making it faster and more efficient to establish the association of agronomic traits with molecular markers or candidate genes, which is the requirement for marker-assisted selection in molecular breeding. Clubroot disease, caused by Plasmodiophora brassicae, is a serious threat to Brassica crops. Even we have breed new clubroot resistant varieties of Chinese cabbage (B. rapa ssp. pekinesis), the underlying genetic mechanism is unclear. In this study, an $F_2$ population of 340 plants were inoculated with P. brassicae from Xinye (Pathotype 2 on the differentials of Williams). Resistance phenotype segregation ratio for the populations fit a 3:1 (R:S) segregation model, consistent with a single dominant gene model. Super-BSA, using re-sequencing the parents, extremely R and S DNA pools with each 50 plants, revealed 3 potential candidate regions on the chromosome A03, with the most significant region falling between 24.30 Mb and 24.75 Mb. A linkage map with 31 markers in this region was constructed with several closely linked markers identified. A Major QTL for clubroot resistance, CRq, which was identified with the peak LOD score at 169.3, explaining 89.9% of the phenotypic variation. And we developed a new co-segregated InDel marker BrQ-2. Joint BSA-seq and traditional QTL analysis delimited CRq to an 250 kb genomic region, where four TIR-NBS-LRR genes (Bra019409, Bra019410, Bra019412 and Bra019413) clustered. The CR gene CRq and closely linked markers will be highly useful for breeding new resistant Chinese cabbage cultivars.

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Model of Water, Energy and Waste Management for Development of Eco-Innovation Park ; A Case Study of Center for Research of Science and Technology "PUSPIPTEK," South Tangerang City, Indonesia

  • Setiawati, Sri;Alikodra, Hadi;Pramudya, Bambang;Dharmawan, Arya Hadi
    • World Technopolis Review
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    • v.3 no.2
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    • pp.89-96
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    • 2014
  • Center for Research of Science and Technology ("PUSPIPTEK") has 460 hectares land area, still maintained as a green area with more than 30% green space. There are 47 centers for research and testing technology, technology-based industries, and as well as public supporting facilities in PUSPIPTEK area. Based on the concepts developed to make this area as an ecological region, PUSPIPTEK can be seen as a model of eco-innovation. The purpose of this research is to develop a model of water, energy and waste management with eco-innovation concept. As a new approach in addressing environmental degradation and maintaining the sustainability of ecosystem, studies related to eco-innovation policy that combines the management of water, energy and waste in the region has not been done. In order to achieve the objectives of the research, a series of techniques for collecting data on PUSPIPTEK existing conditions will be carried out, which includes utilities data (water, electricity, sewage) and master plan of this area. The savings over the implementation of the concept of eco-innovation in water, energy, and waste management were calculated and analyzed using quatitative methods. The amount of cost savings and feasibility were then calculated. Eco innovation in water management among other innovations include the provision of alternative sources of water, overflow of rain water and water environments utilization, and use of gravity to replace the pumping function. Eco-innovation in energy management innovations include the use of LED and solar cell for air conditioning. Eco-innovation in waste management includes methods of composting for organic waste management. The research results: (1) The savings that can be achieved with the implementation of eco innovation in the water management is Rp. 3,032,640 daily, or Rp.1,106,913,600 annually; (2) The savings derived from the implementation of eco innovation through replacement of central AC to AC LiBr Solar Powered will be saved Rp.1,933,992,990 annually and the use of LED lights in the Public street lighting PUSPIPTEK saved Rp.163,454,433 annually; (3) Application of eco innovation in waste management will be able to raise awareness of the environment by sorting organic, inorganic and plastic waste. Composting and plastic waste obtained from the sale revenue of Rp. 44,016,000 per year; (4) Overall, implementation of the eco-innovation system in PUSPIPTEK area can saves Rp. 3,248,377,023 per year, compared to the existing system; and (5)The savings are obtained with implementation of eco-innovation is considered as income. Analysis of the feasibility of the implementation of eco-innovation in water, energy, and waste management in PUSPIPTEK give NPV at a 15% discount factor in Rp. 3,895,228,761; 23.20% of IRR and 4.48 years of PBP. Thus the model of eco-innovation in the area PUSPIPTEK is feasible to implement.