• Title/Summary/Keyword: Li-Ti

Search Result 668, Processing Time 0.033 seconds

Design of $Ti:LiNbO_3$ Three-Waveguide Optical Switch with Center-Waveguide Fed (가운데 도파로 입사된 $Ti:LiNbO_3$ 세 도파로 광스위치의 설계 및 제작)

  • Huh, Chang-Yul;Han, Young-Tak;Kim, Chang-Min
    • Journal of the Institute of Electronics Engineers of Korea SD
    • /
    • v.37 no.6
    • /
    • pp.64-71
    • /
    • 2000
  • An optical switch composed of identical, equally-spaced $Ti:LiNbO_3$ three-waveguides was designed and fabricated. Patterned Ti was diffused into z-cut $LiNbO_3$ substrates. $SiO_2$ buffer layer was evaporated to reduce the propagation loss of TM mode, and Al electrodes of CPW structure were built on the layer for switching of the guided beam. The optical switching phenomenon was confirmed when a beam of ${\lambda}=1.3{\mu}m$ was launched into the center waveguide and an electric field was applied to detune the three waveguides symmetrically.

  • PDF

Enhanced Luminescence of $SrTiO_3:Pr^{3+}$by Incorporating with $Li^+$ or $Na^+$Ion

  • Tian, Lianhua;Mho, Sun-Il;Bae, Hyun-Sook;Yu, Byung-Yong;Pyun, Chong-Hong
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2002.08a
    • /
    • pp.819-821
    • /
    • 2002
  • Photoluminescenc (PL) and low-voltage cathodoluminescence (CL) characteristics of $[xSrTiO_3+(1-x)Li_2TiO_3]:Pr^{3+}$ and $[xSrTiO_3+(1-x)Na_2TiO_3]:Pr^{3+}$ systems were investigated. The red luminescence intensities of these compounds are enhanced remarkably by the incorporation of $Li^+$ or $Na^+$ ion as compared to that of $SrTiO_3:Pr^{3+}$. The enhanced luminescence is speculated to result from both the charge compensation of $Pr^{3+}$ site and oxygen vacancies generated in the lattices by $Li^+$ or $Na^+$ ion.

  • PDF

Measurement of Propagation Property in Ti:$LiNbO_3$ Optical Waveguides (Ti strip 너비에 따른 Ti:$LiNbO_3$ 광도파로에서의 도파특성변화)

  • Kim, Woo-Kyung;Jang, Hyun-Soo;Heo, Hyun;Lee, Seung-Tae;Park, Woo-Jung;Yang, Woo-Seok;Lee, Han-Young
    • Proceedings of the Optical Society of Korea Conference
    • /
    • 2003.02a
    • /
    • pp.168-169
    • /
    • 2003
  • Ti:LiNbO$_3$ 광도파로는 확산형 도파로이기 때문에 그 도파특성이 확산공정 조건에 크게 의존할 뿐만 아니라 굴절률 분포를 모델링하기가 어렵다. 이러한 이유로 설계된 Ti:LiNbO$_3$ 광도파로의 특성은 실제 제작된 소자와 큰 차이를 보이는 경우가 많은데, 이를 개선하기 위해서는 각 공정파라미터에 따른 도파 특성의 변화를 파악하는 작업이 우선적으로 수행되어야 한다. 본 논문에서는 서로 다른 너비를 갖는 Ti strip을 동일한 확산조건에서 확산시킨 후 제작된 광도파로의 도파손실 및 모드패턴을 측정하였다. (중략)

  • PDF

Effect of Ti-Doped Al2O3 Coating Thickness and Annealed Condition on Microstructure and Electrochemical Properties of LiCoO2 Thin-Film Cathode (Ti 첨가 Al2O3 코팅층의 두께와 열처리 조건이 LiCoO2 양극 박막의 미세구조와 전기화학적 특성에 미치는 영향)

  • Choi, Ji-Ae;Lee, Seong-Rae;Cho, Won-Il;Cho, Byung-Won
    • Korean Journal of Materials Research
    • /
    • v.17 no.8
    • /
    • pp.447-451
    • /
    • 2007
  • We investigated the dependence of the various annealing conditions and thickness ($6\sim45nm$) of the Ti-doped $Al_2O_3$ coating on the electrochemical properties and the capacity fading of Ti-doped $Al_2O_3$ coated $LiCoO_2$ films. The Ti-doped-$Al_2O_3$-coating layer and the cathode films were deposited on $Al_2O_3$ plate substrates by RF-magnetron sputter. Microstructural and electrochemical properties of Ti-doped-$Al_2O_3$-coated $LiCoO_2$ films were investigated by transmission electron microscopy (TEM) and a dc four-point probe method, respectively. The cycling performance of Ti-doped $Al_2O_3$ coated $LiCoO_2$ film was improved at higher cut-off voltage. But it has different electrochemical properties with various annealing conditions. They were related on the microstructure, surface morphology and the interface condition. Suppression of Li-ion migration is dominant at the coating thickness >24.nm during charge/discharge processes. It is due to the electrochemically passive nature of the Ti-doped $Al_2O_3$ films. The sample be made up of Ti-doped $Al_2O_3$ coated on annealed $LiCoO_2$ film with additional annealing at $400^{\circ}C$ had good adhesion between coating layer and cathode films. This sample showed the best capacity retention of $\sim92%$ with a charge cut off of 4.5 V after 50 cycles. The Ti-doped $Al_2O_3$ film was an amorphous phase and it has a higher electrical conductivity than that of the $Al_2O_3$ film. Therefore, the Ti-doped $Al_2O_3$ coated improved the cycle performance and the capacity retention at high voltage (4.5 V) of $LiCoO_2$ films.

핵융합로 증식재용 Li계 산화물 분말 합성

  • 박지연;정충환;오석진;김영석;국일현
    • Proceedings of the Korean Nuclear Society Conference
    • /
    • 1997.05b
    • /
    • pp.195-200
    • /
    • 1997
  • 핵융합로 증식재용 r-LiAlO$_2$, Li$_2$ZrO$_3$, Li$_2$TiO$_3$ 분말을 자발착화 연소반응법으로 합성하였다. LiAlO$_2$와 달리 Li$_2$ZrO$_3$ 와 Li$_2$TiO$_3$는 가열하는 동안 침전물이 생겼지만 카르복실산기만을 지닌 구연산과 아민기만을 지닌 우레아를 화학정량의 조성으로 혼합한 연료로 쉽게 분말을 합성할 수 있었다. LiAlO$_2$나 Li$_2$TiO$_3$분말은 별도의 하소 공정이필요없이 원하는 결정상이 형성되었으며, Li$_2$ZrO$_3$분말은 Li이 과량인 상이 형성되므로 110$0^{\circ}C$에서 하소하여 원하는 상을 얻었다. 합성된 Li계 산화물 분말은 비표면적 10~17 $m^2$/g으로 약 150 nm정도의 입자크기를 갖는 미세한 입자이었다.

  • PDF

Electrochemical Properties of $TiO_2$ and ZnO-Added $LiNiO_2$ ($TiO_2$와 ZnO를 첨가한 $LiNiO_2$의 전기화학적 특성)

  • Kim, Hun-Uk;Song, Myoung-Youp
    • Journal of Hydrogen and New Energy
    • /
    • v.16 no.2
    • /
    • pp.142-149
    • /
    • 2005
  • [ $LiNiO_2$ ] was mixed with $TiO_2$ or ZnO for the preparation of a cathode. The electrochemical properties of the cathode were investigated and the effects of the addition of $TiO_2$ or ZnO were discussed. The first discharge capacity decreased as the quantity of the added $TiO_2$ or ZnO increased. It is probably due to the decrease in the area of reaction interface according to the increase in the amount of the added oxide. When 2wt.% and 5wt.% of oxides are added, the discharge capacity increased as the number of cycles increased. It is considered that this results from the increase in the area of reaction interface because the oxide is detached from the $LiNiO_2$ with the increase in the number of cycles. The 1wt.% $TiO_2$ or ZnO-added $LiNiO_2$ had a larger first charge capacity than $LiNiO_2$. This is considered to result from the deintercalation of Li ions in the Ni sites along with the Li ions in the Li sites.

Effect of the Mixed Treatment of Electrolyzed Micronutrients with Nutrient Solution and SCB Slurry on Mineral Content and Growth of Cherry Tomatoes (Lycopersicon esculentum) (양액과 SCB액비 처리에 미량요소 첨가가 방울토마토의 미네랄 함량과 생육에 미치는 영향)

  • Ryoo, Jong-Won
    • Korean Journal of Organic Agriculture
    • /
    • v.20 no.3
    • /
    • pp.385-397
    • /
    • 2012
  • A pot experiment was carried out to examined the effect of electrolyzed micronutrients (Fe, Mn, Zn, Sr, Se, Sn, Co, Ti, and V) solution treatments with nutrient solution and SCB slurry on the mineral content and growth of tomato in cherry tomato (Lycopersicon esculentum). The treatment of nutrient solution (NS)+micronutrients solution (MS) significantly increased the concentrations of Li, Zn, Sr, Se, Ti as compared with that of NS alone in the cherry tomato fruits, and SCB+MS solution treatment significantly increased Li, Zn, Se, Co, Sr, and Ti contents as compared with SCB treatment. The micronutrient contents of MN+SCB+MS treatment were significantly higher in Li, Zn, Se, Co and in Ti than those of SCB and NS treatment, respectively. The growth and yield of cherry tomato fruits was highest with NS treatment. The yield indices of cherry tomato treated with NS+MS treatment and SCB+NS+MS were 97% and 94% of NS treatment. In conclusion, it seems to be possible to produce micronutrient-fortified cherry tomato by the mixed treatment of electrolyzed micronutrients.

2×2Ti:LiNbO3 Integrated Optical Add/Drop Multiplexers utilizing Strain-Optic Effect (스트레인광학효과를 이용한 2×2Ti:LiNbO3 삽입/분기 집적광학 멀티플렉서)

  • Jung, Hong-Sik;Choi, Yong-Wook
    • Korean Journal of Optics and Photonics
    • /
    • v.17 no.5
    • /
    • pp.430-436
    • /
    • 2006
  • Polarization-independent $Ti:LiNbO_3\;2{\times}2$ optical add/drop multiplexer for the 1550nm wavelength region is fabricated. The device consists of two input waveguides, two polarization beam splitters. two polarization conversion/electrooptic tuning waveguide sections, and two output waveguides. The single mode channel waveguides for both TE and TM polarizations are fabricated on a x-cut $Ti:LiNbO_3$substrate by Ti diffusion. Spectral section is based on phase-matched polarization conversion due to shear strain induced by a thick $SiO_2$ grating overlay film. An applied voltage tunes the device by changing the waveguide birefringence, hence the optical wavelength at which most efficient polarization conversion occurs. Tuning rate of 0.094nm/V with a maximum range of 17nm has been obtained. The nearest side-lobe is about 8.2dB. The FWHM is 3.72nm.

Electric Properties of $LiCO_3$ doped $(Ba_{0.5}Sr_{0.5})TiO_3$ Thick Films ($LiCO_3$가 첨가된 $(Ba_{0.5}Sr_{0.5})TiO_3$ 후막의 전기적 특성)

  • Nam, Sung-Pill;Park, In-Gil;Lee, Sung-Gap;Bae, Seon-Gi;Lee, Young-Hie
    • Proceedings of the KIEE Conference
    • /
    • 2006.07c
    • /
    • pp.1432-1433
    • /
    • 2006
  • $Li_{2}CO_3$ doped $Ba_{0.5}Sr_{0.5}TiO_3$ ceramics were fabrication by sol-gel method. Sintering temperature must be suited to the LTCC technology. Structure and dielectric properties were investigated for effect of $Li_{2}CO_3$ dopants at BST. Structure of $Li_{2}CO_3$ doped $Ba_{0.5}Sr_{0.5}TiO_3$ ceramics were dense and homogeneous with almost no pore. Relative permittivity was decreased and dielectric loss was increased with increasing $Li_{2}CO_3$ doping rations. In the case of the 3wt% $Li_{2}CO_3$ doped $Ba_{0.5}Sr_{0.5}TiO_3$ ceramics sintered at $900^{\circ}C$, relative permittivity and dielectric loss were 907 and 0.003 at 100 kHz.

  • PDF

Electrochemical Study of Nanoparticle Li4Ti5O12 as Negative Electrode Material for Lithium Secondary Battery (리튬이차전지 음극재용 나노입자 Li4Ti5O12의 전기화학적 연구)

  • Oh Mi-Hyun;Kim Han-Joo;Kim Young-Jae;Son Won-Keun;Lim Kee-Joe;Park Soo-Gil
    • Journal of the Korean Electrochemical Society
    • /
    • v.9 no.1
    • /
    • pp.1-5
    • /
    • 2006
  • Lithium titanium oxide $(Li_4Ti_5O_{12})$ with spinel-framework structures as anode material for lithium-ion battery was prepared by sol-gel and high energy ball milling (HEBH) method. According to the X-ray diffraction (XRD), Particle Size Analyses(PSA) and scanning electron microscopy (SEM) analysis, uniformly distributed $Li_4Ti_5O_{12}$ particles with grain sizes of 100 nm were observed. Half cells, consisting of $Li_4Ti_5O_{12}$ as working electrode and lithium foil as both counter and reference electrodes showed the high performance of high rate discharge capacity and 173 mAh/g at 0.2C in the range of $1.0\sim2.5 V$. Furthermore, the crystalline structure of $Li_4Ti_5O_{12}$ didn't transform during the lithium intercalation and deintercalation process.