• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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• pp.627-628
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• 2005

In recent years, the rapid growth of portable electronic device market requires higher density characteristics of batteries. The speed at which portability and mobility is advancing hinges much on the battery. What is important is this energy source that engineers design handled devices around the battery, rather than the other way around. Much improvement has been made in reducing the power consumption of portable devices. Currently, the most popular secondary battery is Li-ion battery. Li-ion has won the limelight and become the most prominent battery. This paper reviews the prospect and future of the Li-ion battery.

• 한국수소및신에너지학회논문집
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• 제31권5호
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• pp.489-497
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• 2020

The Li-ion battery is considered to be one of the potential power sources for electric vehicles. In fact, the efficiency, reliability, and cycle life of Li-ion batteries are highly influenced by their thermal conditions. Therefore, a novel thermal management system is highly required to simultaneously achieve high performance and long life of the battery pack. Basically, thermal modeling is a key issue for the novel thermal management of Li-ion battery systems. In this paper, as a basic study for battery thermal modeling, temperature distributions inside the simple Li-ion battery pack (comprises of nine 18650 Li-ion batteries) under a 1C discharging condition were investigated using measurement and computational fluid dynamics (CFD) simulation approaches. The heat flux boundary conditions of battery cells for the CFD thermal analysis of battery pack were provided by the measurement of single battery cell temperature. The temperature distribution inside the battery pack were compared at six monitoring locations. Results show that the accurate estimation of heat flux at the surface of single cylindrical battery is paramount to the prediction of temperature distributions inside the Li-ion battery under various discharging conditions (C-rates). It is considered that the research approach for the estimation of temperature distribution used in this study can be used as a basic tool to understand the thermal behavior of Li-ion battery pack for the construction of effective battery thermal management systems.

• 전력전자학회논문지
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• 제23권2호
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• pp.106-111
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• 2018

In this work, we propose techniques for estimating the SOC of Li-air battery. First, we describe and explain the operation principle of the Li-air battery. Energy density of the Li-air battery was compared with that of the Li-ion battery. The capacity and impedance value of the fully discharged voltage is analyzed, and the OCV value for SOC estimation is measured through the electrochemical characterization of the Li-air battery. Estimation value is obtained by SOC modeling through extended Kaman filter and is compared with the measurement value from the Coulomb counting method. Moreover, the performance of SOC estimation circuit is evaluated.

• 신재생에너지
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• 제16권4호
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• pp.1-8
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• 2020

The possibility of conversion to the RC-MAT propulsion system (gasoline engine → electric motor) was studied. However, as commercial battery capacities are low. it is not possible to change the propulsion system. Nevertheless, development of nex-generation batteries is necessary for high capacity and high energy density. Although Li/S batteries are theoretically suitable as new generation batteries, these batteries are not composed of only Li and S. Hence, ensuring high energy density can be difficult. Moreover, electrolytes are important components in the study of energy density; hence, the battery by Li2S8 Molarity was sorted. There are no studied on its various electrode components. In this study, a Li/S battery was fabricated using an assorted 3D sulfur electrode of high energy density and its electrochemical properties were studied. The Li/S battery has a high energy density of 468 Wh/kg at 1.28 M Li2S8 (A805-1.28). Its capacity rapidly decreased after 1 cycle with more than 1 M Li2S8.

• 한국군사과학기술학회지
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• 제14권4호
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• pp.740-746
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• 2011

Thermally activated batteries have good stability, reliability and long shelf life. Due to these characteristics and operational mechanism, thermal batteries are usually applied to military power sources. Especially, Li/$FeS_2$ thermal batteries, which are used mostly in these days, use LiCl-KCl and LiBr-LiCl-LiF as electrolytes. The electrochemistry of thermal batteries have been researched for long time, however, electrochemical study using impedance spectroscopy was not published so much. Through this research, microscopic electrochemical research was investigated with electrochemical impedance spectroscopy(E.I.S). Electrolyte effects on Li/$FeS_2$ thermal battery was researched changing electrolytes, LiCl-KCl and LiBr-LiCl-LiF. Additionally, the salts, which are added to electrolytes, effects on thermal battery were researched. It is expected that the impedance spectroscopy analysis is applicable to not only thermal battery electrochemical study effectively, but also, thermal battery developments.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1995년도 하계학술대회 논문집 C
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• pp.1054-1057
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• 1995

The pollution-free secondary Li ion battery has been developed recently. However due to short history of Li ion battery, the standards for characterized assessments and standardized testing methods have not been prepared and established yet. Also, the researches have not been done systematically regarding the operating methods of these new type of batteries. Such limited knowledge of new batteries emphasizes the importance of development of characterized assessment and the operating methods.

• 한국산학기술학회논문지
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• 제15권7호
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• pp.4692-4697
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• 2014

태양광 전원은 태양광 패널이 설치된 지역의 위치와 날씨 그리고 기후 등에 매우 큰 영향을 받으며, 전원으로서의 사용시간의 제한과 출력의 불확실성이라는 특성을 갖는다. 이러한 태양광 전원의 불확실성을 가능한 줄이기 위해, 태양광 전원의 출력에 대한 오랜 기간 동안의 데이터를 분석하여 출력의 평균값을 산출해 내었다. 태양광 전원의 출력의 평균값은 태양광 전원에 직접 연결되어 그리드에 안정적인 전력을 공급하기 위한 Li 에너지 저장장치의 적정 용량산정과 운용방식에 꼭 필요한 데이터이며, 이로부터 Li 배터리의 충방전모드에 의해 그리드에 일정한 출력의 전력을 공급하는 것이 가능하도록 하였다. 태양광 전원과 Li 배터리를 포함하는 시스템이 악조건의 그리드 운전상태에서의 동작특성을 관찰하기 위해 Li 배터리의 충전율이 100%에서 10%로 단시간에 감소될 정도의 과부하 상태에 대해 태양광 전원과 Li 배터리의 운용특성을 분석하고 Li 배터리 셀 단위의 출력 및 온도특성을 해석하였다.

• 조명전기설비학회논문지
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• 제28권8호
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• pp.106-112
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• 2014

This paper presents the analysis of connected operation of photo voltaic source and Li energy storage system. The micro-grid has been installed and operated for several years at the campus of USF and has been a role of test bed. Photo voltaic source has been strongly influenced by the location, weather and climate of a installed area and Li battery is connected directly to the photo voltaic source to compensate for the limitations. The Li battery is operated to supply power output to the grid by the charging or discharging mode based on the average power output of the PV source which is calculated from monitored data for several years. The load of the PV and Li battery system is operated as a severe loading condition and the operating characteristics of PV source and Li battery are analyzed in detail. In connected operations of PV and Li battery to power system, the PV and Li battery is operated to supply constant power during only day time or peak time to increase load shedding ratio and efficient usage of generation sources in power system.

• 전기화학회지
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• 제11권3호
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• pp.197-210
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• 2008

리튬이차전지용 양극재는 전지 성능발전과 더불어 다양하게 발전되어 왔다. 처음으로 채용된 $LiCoO_2$는 초기의 부족한 성능을 도핑이나 표면개질이라는 기술을 채용하여 지속적인 발전을 거듭하면서 최근 4.3V에 가까운 충전전압에서도 적용 가능하게 되었다. 한편으로 응용기기가 복잡해지면서 요구되는 특성도 한층 강화되었다. 높은 작동전압 뿐만 아니라 고용량이 요구되면서 새로운 재료에 대한 연구개발이 시작되었고, 그 중에서도 ${LiNi}_{1-x}{M_xO_2}$, $Li[Ni_{x}Mn_{y}Co_{z}]O_{2}$, $Li[{Ni}_{1/2}{Mn}_{1/2}]O_{2}$등 다양한 재료들이 개발되기에 이르렀다. 최근에는 고유가에 따라 전기자동차용 개발이활발해지면서 고안전성의 새로운 재료가 필요하게 되었고, 이러한 요구에 수렴하여 ${LiMn_2}{O_4}$, $LiFePO_4$와 같은 안전성이 매우 우수한 재료가 개발되었다. 향 후 양극재 부분은 이외에도 다양한 상들이 고용량과 동시에 안전성이 뛰어난 고용체를 이루고 있는 복합체 양극재를 비롯하여 다양한 재료들이 개발될 것으로 여겨진다.

• 한국수소및신에너지학회논문집
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• 제31권6호
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• pp.622-629
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• 2020

The performance and cost of electric vehicles (EVs) are much influenced by the performance and service life of the Li-ion battery system. In particular, the cell performance and reliability of Li-ion battery packs are highly dependent on their operating temperature. Therefore, a novel battery thermal management is crucial for Li-ion batteries owing to heat dissipation effects on their performance. Among various types of battery thermal management systems (BTMS'), the phase change material (PCM) based BTMS is considered to be a promising cooling system in terms of guaranteeing the performance and reliability of Li-ion batteries. This work is mainly concerned with the basic research on PCM based BTMS. In this paper, a basic experimental study on PCM based battery cooling system was performed. The main purpose of the present study is to present a comparison of two PCM-based cooling systems (n-Eicosane and n-Docosane) of the unit 18650 battery module. To this end, the simplified PCM-based Li-ion battery module with two 18650 batteries was designed and fabricated. The thermal behavior (such as temperature rise of the battery pack) with various discharge rates (c-rate) was mainly investigated and compared for two types of battery systems employing PCM-based cooling. It is considered that the results obtained from this study provide good fundamental data on screening the appropriate PCMs for future research on PCM based BTMS for EV applications.