• Title/Summary/Keyword: Li Diffusion

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Coupled Heat and Mass Transfer in Absorption of Water Vapor into LiBr-$H_2O$ Solution Flowing over a Finned Inclined Surface (좁은 휜이 달린 경사면을 흐르는 리튬브로마이드 수용액 흡수기에서의 열 및 물질전달)

  • 조은준;서태범
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.9
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    • pp.860-867
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    • 2001
  • Absorption of water vapor into LiBr-$H_2O$ O solution flowing over a finned inclined surface is numerically investigated. The momentum, energy, and diffusion equation are numerically solved using a finite difference method. The four different shapes of the wall surfaces are considered to find the best surface for absorption assuming that the wall temperature and the surface tension are constant. The effects of the fin interval and Reynolds number are investigated. Based on the numerical results, it is known that the parabolic surface shows better absorption performance than the other surfaces, and that water vapor absorption increases gradually with decreasing the fin interval.

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Parametric Study on the $LiBr-H_{2}O$ Absorption Process on Horizontal Tubes Using Wavier-Stokes Equations (Navier-Stokes 방정식을 사용한 수평원관상의 $LiBr-H_{2}O$ 흡수특성에 대한 연구)

  • Min J. K.;Choi D. H.
    • 한국전산유체공학회:학술대회논문집
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    • 1999.05a
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    • pp.213-218
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    • 1999
  • The $LiBr-H_{2}O$ absorption process on a horizontal tube has been analyzed using the numerical method which incorporates the fully elliptic Navier-Stokes equations for the momentum equations, the energy and mass-diffusion equations. On a staggered grid, the SIMPLER algorithm with the QUICK scheme is used to solve these equations along with the MAC method for the free surface tracking. With the assumption that the absorbent is linear, calculations have been made for various inlet temperature and flow-rate conditions. The detailed results of the parametric study, such as the temperature, concentration, absorption mass flux and wall heat flux distributions are presented. The self-sustained feature of the absorption process is clearly elaborated. The analyses have also been carried out for multiple tube arrangement and the results show that the absorption rate converges after a few tube rows.

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Coupled Heat and Mass Transfer in Absorption of Water Vapor into LiBr-$H_2O$ Solution Flowing on Finned Inclined Surfaces

  • Seo, Taebeom;Cho, Eunjun
    • Journal of Mechanical Science and Technology
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    • v.18 no.7
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    • pp.1140-1149
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    • 2004
  • The absorption characteristics of water vapor into a LiBr-H$_2$O solution flowing down on finned inclined surfaces are numerically investigated in order to study the absorbing performances of different surface shapes of finned tubes as an absorber element. A three-dimensional numerical model is developed. The momentum, energy, and diffusion equations are solved simultaneously using a finite difference method. In order to obtain the temperature and concentration distributions, the Runge-Kutta and the Successive over relaxation methods are used. The flat, circular, elliptic, and parabolic shapes of the tube surfaces are considered in order to find the optimal surface shapes for absorption. In addition, the effects of the fin intervals and Reynolds numbers are studied. The results show that the absorption mainly happens near the fin tip due to the temperature and concentration gradient, and the absorbing performance of the parabolic surface is better than those of the other surfaces.

Diagnostic Significance of Apparent Diffusion Coefficient Values with Diffusion Weighted MRI in Breast Cancer: a Meta-Analysis

  • Sun, Jiang-Hong;Jiang, Li;Guo, Fei;Zhang, Xiu-Shi
    • Asian Pacific Journal of Cancer Prevention
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    • v.15 no.19
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    • pp.8271-8277
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    • 2014
  • Aims: Apparent diffusion coefficient (ADC) values of nodes in diffusion-weighted imaging (DWI) are widely used in differentiating metastatic from non-metastatic lymph nodes. The purpose of this meta-analysis was to demonstrate whether DWI could contribute to the precise diagnosis of breast cancer (BC) with and without lymph node metastasis (LNM). Materials and Methods: English and Chinese electronic databases were searched for relevant studies followed by a comprehensive literature search. Two reviewers independently assessed the methodological quality of the included trials based on the quality assessment of diagnostic accuracy studies (QUADAS). Summary odds ratios (ORs) and corresponding 95% confidence intervals (95% CIs) were calculated. Results: Final analysis of 624 BC subjects (patients with LNM = 254, patients without LNM = 370) were incorporated into the current meta-analysis from 9 eligible cohort studies. Combined ORs of ADCs suggested that ADC values in BC patients without LNM were higher than in patients with LNM (OR=0.56, 95%CI: 0.11-1.01, p=0.015). Subgroup analysis stratified by country indicated a low ADC value in BC patients with LNM rather than those without LNM among Chinese (OR=1.27, 95%CI: 0.89-1.66, p<0.001), Italians (OR=0.75, 95%CI: 0.13-1.38, p=0.018), and Egyptians (OR=1.27, 95%CI: 0.71-1.84, p<0.001). The findings of subgroup analysis by MRI machine type revealed that ADC values from diffusion MRI may be potential diagnostic indicators for BC using Non-Philips 1.5T (OR=1.10, 95%CI: 0.84-1.36, p<0.001). Conclusions: The main findings of our meta-analysis demonstrated that increased signal intensity on DWI and decreased signals on ADC are helpful in diagnosis of BC patients with or without LNM. DWI could therefore be an important imaging investigation in patients suspected of BC.

A multiscale numerical simulation approach for chloride diffusion and rebar corrosion with compensation model

  • Tu, Xi;Li, Zhengliang;Chen, Airong;Pan, Zichao
    • Computers and Concrete
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    • v.21 no.4
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    • pp.471-484
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    • 2018
  • Refined analysis depicting mass transportation and physicochemical reaction and reasonable computing load with acceptable DOFs are the two major challenges of numerical simulation for concrete durability. Mesoscopic numerical simulation for chloride diffusion considering binder, aggregate and interfacial transition zone is unable to be expended to the full structure due to huge number of DOFs. In this paper, a multiscale approach of combining both mesoscopic model including full-graded aggregate and equivalent macroscopic model was introduced. An equivalent conversion of chloride content at the Interfacial Transition Layer (ITL) connecting both models was considered. Feasibility and relative error were discussed by analytical deduction and numerical simulation. Case study clearly showed that larger analysis model in multiscale model expanded the diffusion space of chloride ion and decreased chloride content in front of rebar. Difference for single-scale simulation and multiscale approach was observed. Finally, this paper addressed some worth-noting conclusions about the chloride distribution and rebar corrosion regarding the configuration of rebar placement, rebar diameter, concrete cover and exposure period.

Copula entropy and information diffusion theory-based new prediction method for high dam monitoring

  • Zheng, Dongjian;Li, Xiaoqi;Yang, Meng;Su, Huaizhi;Gu, Chongshi
    • Earthquakes and Structures
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    • v.14 no.2
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    • pp.143-153
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    • 2018
  • Correlation among different factors must be considered for selection of influencing factors in safety monitoring of high dam including positive correlation of variables. Therefore, a new factor selection method was constructed based on Copula entropy and mutual information theory, which was deduced and optimized. Considering the small sample size in high dam monitoring and distribution of daily monitoring samples, a computing method that avoids causality of structure as much as possible is needed. The two-dimensional normal information diffusion and fuzzy reasoning of pattern recognition field are based on the weight theory, which avoids complicated causes of the studying structure. Hence, it is used to dam safety monitoring field and simplified, which increases sample information appropriately. Next, a complete system integrating high dam monitoring and uncertainty prediction method was established by combining Copula entropy theory and information diffusion theory. Finally, the proposed method was applied in seepage monitoring of Nuozhadu clay core-wall rockfill dam. Its selection of influencing factors and processing of sample data were compared with different models. Results demonstrated that the proposed method increases the prediction accuracy to some extent.

Coupled diffusion of multi-component chemicals in non-saturated concrete

  • Damrongwiriyanupap, Nattapong;Li, Linyuan;Xi, Yunping
    • Computers and Concrete
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    • v.11 no.3
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    • pp.201-222
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    • 2013
  • A comprehensive simulation model for the transport process of fully coupled moisture and multi-species in non-saturated concrete structures is proposed. The governing equations of moisture and ion diffusion are formulated based on Fick's law and the Nernst-Planck equation, respectively. The governing equations are modified by explicitly including the coupling terms corresponding to the coupled mechanisms. The ionic interaction-induced electrostatic potential is described by electroneutrality condition. The model takes into account the two-way coupled effect of moisture diffusion and ion transport in concrete. The coupling parameters are evaluated based on the available experimental data and incorporated in the governing equations. Differing from previous researches, the material parameters related to moisture diffusion and ion transport in concrete are considered not to be constant numbers and characterized by the material models that account for the concrete mix design parameters and age of concrete. Then, the material models are included in the numerical analysis and the governing equations are solved by using finite element method. The numerical results obtained from the present model agree very well with available test data. Thus, the model can predict satisfactorily the ingress of deicing salts into non-saturated concrete.

Radioactive gas diffusion simulation and inhaled effective dose evaluation during nuclear decommissioning

  • Yang, Li-qun;Liu, Yong-kuo;Peng, Min-jun;Ayodeji, Abiodun;Chen, Zhi-tao;Long, Ze-yu
    • Nuclear Engineering and Technology
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    • v.54 no.1
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    • pp.293-300
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    • 2022
  • During the decommissioning of the nuclear facilities, the radioactive gases in pressure vessels may leak due to the demolition operations. The decommissioning site has large space, slow air circulation, and many large nuclear facilities, which increase the difficulty of workers' inhalation exposure assessment. In order to dynamically evaluate the activity distribution of radionuclides and the committed effective dose from inhalation in nuclear decommissioning environment, an inhalation exposure assessment method based on the modified eddy-diffusion model and the inhaled dose conversion factor is proposed in this paper. The method takes into account the influence of building, facilities, exhaust ducts, etc. on the distribution of radioactive gases, and can evaluate the influence of radioactive gases diffusion on workers during the decommissioning of nuclear facilities.

A variational nodal formulation for multi-dimensional unstructured neutron diffusion problems

  • Qizheng Sun ;Wei Xiao;Xiangyue Li ;Han Yin;Tengfei Zhang ;Xiaojing Liu
    • Nuclear Engineering and Technology
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    • v.55 no.6
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    • pp.2172-2194
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    • 2023
  • A variational nodal method (VNM) with unstructured-mesh is presented for solving steady-state and dynamic neutron diffusion equations. Orthogonal polynomials are employed for spatial discretization, and the stiffness confinement method (SCM) is implemented for temporal discretization. Coordinate transformation relations are derived to map unstructured triangular nodes to a standard node. Methods for constructing triangular prism space trial functions and identifying unique nodes are elaborated. Additionally, the partitioned matrix (PM) and generalized partitioned matrix (GPM) methods are proposed to accelerate the within-group and power iterations. Neutron diffusion problems with different fuel assembly geometries validate the method. With less than 5 pcm eigenvalue (keff) error and 1% relative power error, the accuracy is comparable to reference methods. In addition, a test case based on the kilowatt heat pipe reactor, KRUSTY, is created, simulated, and evaluated to illustrate the method's precision and geometrical flexibility. The Dodds problem with a step transient perturbation proves that the SCM allows for sufficiently accurate power predictions even with a large time-step of approximately 0.1 s. In addition, combining the PM and GPM results in a speedup ratio of 2-3.

Mechanism of Tungsten Recovery from Spent Cemented Carbide by Molten Salt Electrodeposition

  • Hongxuan Xing;Zhen Li;Enrui Feng;Xiaomin Wang;Hongguang Kang;Yiyong Wang;Hui Jin;Jidong Li
    • Journal of Electrochemical Science and Technology
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    • v.14 no.1
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    • pp.75-84
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    • 2023
  • The accumulation of spent carbide (YG8), not only pollutes the environment but also causes waste of tungsten, cobalt and other rare metal resources. To better address this issue, we proposed a combined electrochemical separation process of low-temperature aqueous solution and high-temperature molten salt for tungsten and cobalt. H2WO4 was obtained from spent carbide in an aqueous solution, and we calcined it to obtain WO3, which was used as a raw material to obtain tungsten by using molten salt electrodeposition. The influence of the current efficiency and the electrochemical behavior of the discharge precipitation of W(VI) were also studied. The calcination results showed that the morphology of WO3 was regular and there were no other impurities. The maximum current efficiency of 82.91% was achieved in a series of electrodeposition experiments. According to XRD and SEM analysis, the recovered product was high purity tungsten, which belongs to the simple cubic crystal system. In the W(VI) reduction mechanism experiments, the electrochemical process of W(VI) in NaCl-Na2WO4-WO3 molten salt was investigated using linear scanning voltammetry (LSV) and chronoamperometry in a three-electrode system. The LSV showed that W(VI) was reduced at the cathode in two steps and the electrode reaction was controlled by diffusion. The fitting results of chronoamperometry showed that the nucleation mechanism of W(VI) was an instantaneous nucleation mode, and the diffusion coefficient was 7.379×10-10 cm2·s-1.