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Effects of metal contacts and doping for high-performance field-effect transistor based on tungsten diselenide (WSe2)

  • Jo, Seo-Hyeon;Park, Jin-Hong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.294.1-294.1
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    • 2016
  • Transition metal dichalcogenides (TMDs) with two-dimensional layered structure, such as molybdenum disulfide (MoS2) and tungsten diselenide (WSe2), are considered attractive materials for future semiconductor devices due to its relatively superior electrical, optical, and mechanical properties. Their excellent scalability down to a monolayer based on the van der Waals layered structure without surface dangling bonds makes semiconductor devices based on TMD free from short channel effect. In comparison to the widely studied transistor based on MoS2, researchs focusing on WSe2 transistor are still limited. WSe2 is more resistant to oxidation in humid ambient condition and relatively air-stable than sulphides such as MoS2. These properties of WSe2 provide potential to fabricate high-performance filed-effect transistor if outstanding electronic characteristics can be achieved by suitable metal contacts and doping phenomenon. Here, we demonstrate the effect of two different metal contacts (titanium and platinum) in field-effect transistor based on WSe2, which regulate electronic characteristics of device by controlling the effective barreier height of the metal-semiconductor junction. Electronic properties of WSe2 transistor were systematically investigated through monitoring of threshold voltage shift, carrier concentration difference, on-current ratio, and field-effect mobility ratio with two different metal contacts. Additionally, performance of transistor based on WSe2 is further enhanced through reliable and controllable n-type doping method of WSe2 by triphenylphosphine (PPh3), which activates the doping phenomenon by thermal annealing process and adjust the doping level by controlling the doping concentration of PPh3. The doping level is controlled in the non-degenerate regime, where performance parameters of PPh3 doped WSe2 transistor can be optimized.

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Poly-4-vinylphenol and Poly (melamine-co-formaldehyde)-based Tungsten Diselenide (WSe2) Doping Method

  • Nam, Hyo-Jik;Park, Hyung-Youl;Park, Jin-Hong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.194.1-194.1
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    • 2015
  • Transition metal dichalcogenide (TMD) with layered structure, has recently been considered as promising candidate for next-generation flexible electronic and optoelectronic devices because of its superior electrical, optical, and mechanical properties.[1] Scalability of thickness down to a monolayer and van der Waals expitaxial structure without surface dangling bonds (consequently, native oxides) make TMD-based thin film transistors (TFTs) that are immune to the short channel effect (SCE) and provide very high field effect mobility (${\sim}200cm^2/V-sec$ that is comparable to the universal mobility of Si), respectively.[2] In addition, an excellent photo-detector with a wide spectral range from ultraviolet (UV) to close infrared (IR) is achievable with using $WSe_2$, since its energy bandgap varies between 1.2 eV (bulk) and 1.8 eV (monolayer), depending on layer thickness.[3] However, one of the critical issues that hinders the successful integration of $WSe_2$ electronic and optoelectronic devices is the lack of a reliable and controllable doping method. Such a component is essential for inducing a shift in the Fermi level, which subsequently enables wide modulations of its electrical and optical properties. In this work, we demonstrate n-doping method for $WSe_2$ on poly-4-vinylphenol and poly (melamine-co-formaldehyde) (PVP/PMF) insulating layer and adjust the doping level of $WSe_2$ by controlling concentration of PMF in the PVP/PMF layer. We investigated the doping of $WSe_2$ by PVP/PMF layer in terms of electronic and optoelectronic devices using Raman spectroscopy, electrical measurements, and optical measurements.

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Design and Implementation of Smart Gardening System Using Real-Time Visualization Algorithm Based on IoT (IoT 기반 실시간 시각화 알고리즘을 이용한 스마트가드닝 시스템 설계 및 구현)

  • Son, Soo-A;Park, Seok-Cheon
    • Journal of Internet Computing and Services
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    • v.16 no.6
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    • pp.31-37
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    • 2015
  • Data generated from sensors are exploding with recent development of IoT. This paradigm shift requires various industry fields that demand instant actions to analyze the arising data on a real-time basis, along with the real-time visualization analysis. As the existing visualization systems, however, perform visualization after storing data, the response time of the server cannot guarantee the ms-level processing that is close to real-time. They also have a problem of destroying data that can be major resources as they do not possess the process resources. Therefore, a smart gardening system that applies a real-time visualization algorithm using IoT sensing data under a gardening environment was designed and implement in this study. The response time of the server was measured to evaluate the performance of the suggested system. As a result, the response speed of the suggested real-time visualization algorithm was guaranteeing the ms-level processing close to real-time.

Study on the Lubricant Flow Behaviors in the Wet Clutch Pack System of Dual Clutch Transmission (습식 DCT(Dual Clutch Transmission) 클러치 팩 내부에서의 체결 동작에 따른 변속기유 거동 연구)

  • Kim, WooJung;Lee, SangHo;Jang, Siyoul
    • Tribology and Lubricants
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    • v.33 no.3
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    • pp.85-91
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    • 2017
  • This work studies the flow behaviors in the gap between the friction pad and separator in wet-clutch systems. The fluid volume of the lubricant is modeled using the entire system of wet-clutch pack of a dual clutch transmission that has larger outer radius of odd gear shifts and smaller inner radius of even gear shifts. Flow behaviors in the gap of the clutch pad are computed using the gear shift modes that consider the real relative velocities between the friction pad and separator. Flow behaviors in the gap of the disengaged clutch pad are mainly investigated for the wet-clutch system, whereas the engaged clutch pad is modeled with no fluid rate through the contacting surfaces. The developed hydrodynamic fluid pressures and velocity fields in the clutch pad gap are computed to obtain the relevant information for managing flow rates in wet-clutch packs under dual operating conditions during gear shifts. These hydrodynamic pressures and velocity fields are compared on the basis of each gear level and gap location, which is necessary to determine the effects of groove patterns on the friction pad. Shear stresses in the gap locations are also computed on the basis of the gear level for the inner and outer clutch pads. The computed results are compared and used for the design of cooling capacity against frictional heat generation in wet-clutch pack systems.

Temperature and Coverage Dependent Quasi-reversible Two-photon Photoemission of 1-phenyl-1-propyne on Cu(111)

  • Sohn, Young-Ku;Wei, Wei;Huang, Weixin;White, John M.
    • Bulletin of the Korean Chemical Society
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    • v.32 no.6
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    • pp.1980-1984
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    • 2011
  • A temperature- and coverage-dependant quasi-reversible change in two-photon photoemission (2PPE) of chemisorbed 1-phenyl-1-propyne (PP) on Cu(111) is reported. For PP on Cu(111) at 300 K probed at a photon energy of 4.13 eV, two broad peaks of comparable intensity show final state energies of 7.25 and 7.75 eV above the Fermi level. The former peak could be assigned to the first image potential state (IS, n = 1) and/or unoccupied molecular orbital (UMO), located at 3.1 eV above the Fermi level. The latter is plausibly attributed to a mix of unoccupied higher-order IS (and/or UMO) and occupied surface state (SS) of Cu(111). With decreasing the temperature, the former 2PPE peak shows a shift in position by about 0.2 eV, and the latter exhibits a dramatic increase in intensity. In the system, intermolecular interactions (and/or order-disorder transition) of PP and substrate lattice temperature may play a significant role in change in photoexcitation lifetime (or excitation cross-section), and the unoccupied molecular orbital (UMO)-metal (IS) charge transfer coupling. Our unique 2PPE results provide a deeper insight for understanding photoexcitation charge transfer with temperature in an organic molecule/metal system.

Industrial Fatigue and Low Back Pain of the Workers (산업장 근로자들의 피로자각증상과 요통)

  • Kim, Soon-Lae;Moon, Jung-Soon
    • Research in Community and Public Health Nursing
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    • v.7 no.2
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    • pp.400-409
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    • 1996
  • To investigate industrial fatigue and low back pain, the questionaire survey for subjective symptoms of fatigue and low back pain was carried out among 591 male workers aged 20-55 employed in an automobile industry in Korea. Workers participated to this study were divided into low back pain group(LBP) and control group, according to the self-reports by written questionaires. The subjective sysptoms of fatigue comprised three groups of 10 items each, representing dullness and sleepiness(level of cerebral activation), difficulty in concentration(level of motivation) and bodily projection of fatigue. The resultant data were processed for $\chi^2-test$, t-test and a pearson's correlation coefficient to confirm the relationships. The results were as follows: 1. 30 items of fatigue subjective symptoms exeptone item, 'lack in perseverance', were directly associated with low back pain. 2. The percentage of fatigue complaint were sig nificantly higher in LBP group. 3. Of the 30 items of fatigue subjective symptoms, the highest percentage was accounted for 'eye strain'(27.9%), followed by 'whole body feels tired' and 'legs feel heavy'(22.9%), 'feel like lying'(21.4%), 'feel a pain in the low back'(18.7%), 'feel drowsy'(16.4%) and 'feel stiffness in the neck or the shoulders'(16.2%) in the order of sequence. 4. The average weighted score for the first group of fatigue items(dullness and sleepiness) was the largest among three groups and was followed by the second group(difficulty in concentration) and the third group(bodily projection of fatigue) in the order of sequence, suggesting the heavier shift work stress of the workers. 5. In the groups of the aged 30-40, work duration of 5-7yrs, heavy work amount and irregular work speed, significant high fatigue complaints were revealed in terms of eye strain, whole body feels tired, legs feel heavy, feel like lying, feel a pain in the low back and feel stiffness in the neck or the shoulders. 6. A significant negative correlations were shown between age, work duration and eleven subjective symptoms while positive reciprocal correlations were shown between eleven items with one another.

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Morphology-dependent Nanocatalysis: Rod-shaped Oxides

  • Shen, Wenjie
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.130-131
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    • 2013
  • Nanostructured oxides are widely used in heterogeneous catalysis where their catalytic properties are closely associated with the size and morphology at nanometer level. The effect of particle size has been well decumented in the past two decades, but the shape of the nanoparticles has rarely been concerned. Here we illustrate that the redox and acidic-basic properties of oxides are largely dependent on their shapes by taking $Co_3O_4$, $Fe_2O_3$, $CeO_2$ and $La_2O_3$ nanorods as typical examples. The catalytic activities of these rod-shaped oxides are mainly governed by the nature of the exposed crystal planes. For instance, the predominant presence of {110} planes which are rich in active $Co^{3+}$ on $Co_3O_4$ nanorods led to a much higher activity for CO oxidation than the nanoparticles that mainly exposed the {111} planes. The simultaneous exposure of iron and oxygen ions on the surface of $Fe_2O_3$ nanorods have significantly enhanced the adsorption and activation of NO and thereby promoted the efficiency of DeNOx process. Moreover, the exposed surface planes of these rod-shaped oxides mediated the reaction performance of the integrated metal-oxide catalysts. Au/$CeO_2$ catalysts exhibited outstanding stability under water-gas shift conditions owing to the strong bonding of gold particle on the $CeO_2$ nanorods where the formed gold-ceria interface was resistant towards sintering. Cu nanoparticles dispersed on $La_2O_3$ nanorods efficiently catalyzed transfer dehydrogenation of primary aliphatic alcohols based on the uniue role of the exposed {110} planes on the support. Morphology control at nanometer level allows preferential exposure of the catalytically active sites, providing a new stragegy for the design of highly efficient nanostructured catalysts.

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Development of the College Curriculum using the Competency-based Model (역량기반의 전문대학 교육과정 개선 방안)

  • Choi, Kil-Sung
    • The Journal of the Korea Contents Association
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    • v.10 no.10
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    • pp.464-478
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    • 2010
  • Competency, a frequently mentioned word in connection to the recent education reform, is often used in discussing a paradigm shift from the education focusing on knowledge to the one emphasizing students' adaptability to the real social life. In order to foster talents equipped with practical knowledge and skills geared to the requirements of the jobs, education at college level also need to be improved by reforming the current curricula. This paper aims to develop better ways for college education based on the scrutiny of the pros and cons of the current curricula of colleges. To this end, it reviews preceeding studies on this subject and examines the applicability of the model of competency-based education. We analyse whether this model can be applied to college education or not. By indicating specific ways to apply the standards of the basic-level job competency developed by Human Resources Development Service of Korea to job training courses, the study also aims to contribute to the improvement of education at college.

Experiences of Ethical Issues and Needs for Ethics Education in Clinical Nurses (임상간호사의 윤리적 이슈 경험과 윤리교육 요구)

  • Shin, Ja Hyun;Jeong, Seok Hee;Lee, Myung Ha;Yang, Youngran
    • Journal of Korean Academy of Nursing Administration
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    • v.21 no.3
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    • pp.327-339
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    • 2015
  • Purpose: This study was done to identify the experiences of ethical issues and needs for ethics education in clinical nurses. Methods: A cross-sectional survey was used and data were collected in 2013. Participants were 428 clinical nurses working in the general units of seven medical hospitals. The Ethical Issues in Clinical Practice Tool was used. Data analysis was performed using SPSS/WIN 19.0. Results: 'Providing care with a possible risk to your health' was the most frequent and disturbing ethical problems for nurses. The highest helpful ethical topic was 'the patients' right, autonomy and informed consent'. The ethical issue experience was significantly different according to education level, work units, and type of employment. The necessity of ethics education was statistically different according to age, religion, level of education, duration of working as RN, position, shift type, and continuing education about nursing ethics. Conclusion: The results of this study show that nursing educators need to provide practical ethics education based on frequent ethical issues and helpful education topics. These findings can be used in developing effective education strategies for clinical nurses and nursing organizations to improve nurses' ethical decision-making abilities.

The Interoperability between RDF/OWL and Topic Maps using the Semantic Wiki (시맨틱 위키를 이용한 RDF/OWL과 토픽맵 사이의 상호운용성)

  • Kim, Hoon-Min;Yang, Jung-Jin
    • The Journal of Society for e-Business Studies
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    • v.12 no.1
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    • pp.123-133
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    • 2007
  • With the emergence of Semantic Web and Web 2.0, the paradigm shift of the Web is on resource-centered services. That is, the focus now moves from having just rich resources to the meta-information of describing the resources. The relevant standards, RDF(Resource Description Language) and Topic Maps, of describing the meta-information are defined and adopted by W3C and ISO respectively. Describing meta-information in such a XML form could be burdensome to participants. Semantic Wiki extended from 1)WikiWikiWeb is proposed to deal with the problem. It enables users to generate RDF meta-information about Wiki pages with simple usages of the grammar. We discuss the way of improving interoperability between Topic Maps-based semantic Wiki papges and RDF-based ones. The method proposed by RDFTM task force is present with the usage of high-level Wiki grammar for facilitating low-level transformation.

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