• Title/Summary/Keyword: Lead-Calcium

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Elemental Composition of the Soils using LIBS Laser Induced Breakdown Spectroscopy

  • Muhammad Aslam Khoso;Seher Saleem;Altaf H. Nizamani;Hussain Saleem;Abdul Majid Soomro;Waseem Ahmed Bhutto;Saifullah Jamali;Nek Muhammad Shaikh
    • International Journal of Computer Science & Network Security
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    • v.24 no.6
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    • pp.200-206
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    • 2024
  • Laser induced breakdown spectroscopy (LIBS) technique has been used for the elemental composition of the soils. In this technique, a high energy laser pulse is focused on a sample to produce plasma. From the spectroscopic analysis of such plasma plume, we have determined the different elements present in the soil. This technique is effective and rapid for the qualitative and quantitative analysis of all type of samples. In this work a Q-switched Nd: YAG laser operating with its fundamental mode (1064 nm laser wavelength), 5 nanosecond pulse width, and 10 Hz repetition rate was focused on soil samples using 10 cm quartz lens. The emission spectra of soil consist of Iron (Fe), Calcium (Ca), Titanium (Ti), Silicon (Si), Aluminum (Al), Magnesium (Mg), Manganese (Mn), Potassium (K), Nickel (Ni), Chromium (Cr), Copper (Cu), Mercury (Hg), Barium (Ba), Vanadium (V), Lead (Pb), Nitrogen (N), Scandium (Sc), Hydrogen (H), Strontium (Sr), and Lithium (Li) with different finger-prints of the transition lines. The maximum intensity of the transition lines was observed close to the surface of the sample and it was decreased along the axial direction of the plasma expansion due to the thermalization and the recombination process. We have also determined the plasma parameters such as electron temperature and the electron number density of the plasma using Boltzmann's plot method as well as the Stark broadening of the transition lines respectively. The electron temperature is estimated at 14611 °K, whereas the electron number density i.e. 4.1 × 1016 cm-3 lies close to the surface.

Evaluation of In-Vitro Efficacy of Active Ingredients in Dentifrice Used for Different Treatment Times (치약용 약효제의 적용시간에 따른 실험실적 효능 연구)

  • Ahn, Jae-Hyun;Kim, Ji-Hye;Kim, Ji-Young
    • Journal of dental hygiene science
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    • v.16 no.2
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    • pp.176-182
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    • 2016
  • The purpose of this study was to evaluate the in-vitro efficacy of the active ingredients of dentifrice following treatment time. The whitening effect was evaluated by a change in lightness value relative to the contact time of hydrogen peroxide, by using artificially stained hydroxyapatite discs. The anti-calculus effect was assessed based on the amount of calcium eluted from the human dental calculus by sodium pyrophosphate. Remineralization was evaluated by the Vickers hardness test following the application of sodium fluoride to bovine enamel. In order to view dentinal tubules occlusion, the formation of insoluble calcium salts by bovine dentin specimens was observed using scanning electron microscopy. Change in lightness value (${\Delta}L$) was $5.50{\pm}1.51$ after 1 min of treatment, $5.73{\pm}0.43$ after 3 min, $8.64{\pm}0.24$ after 10 min, $18.93{\pm}0.76$ after 30 min, and $27.35{\pm}0.54$ after 60 min. The amount of calcium eluted from the human dental calculus was $4.23{\pm}0.14ppm$ after 1 min of treatment, $4.51{\pm}0.04ppm$ after 3 min, $12.12{\pm}0.16ppm$ after 10 min, $17.85{\pm}0.81ppm$ after 30 min, and $25.15{\pm}0.32ppm$ after 60 min. The Vickers hardness change value (${\Delta}VHN$) was $1.96{\pm}1.44$ after 1 min, $1.52{\pm}1.06$ after 3 min, $9.06{\pm}0.15$ after 10 min, $10.83{\pm}5.13$ after 30 min, and $12.55{\pm}2.09$ after 60 min. Partial dentinal tubules occlusion was observed at 10 min and complete occlusion was evident at 60 min. In summary, the use of patch type dentifrices for 10, 30, or 60 min were 1.57 to 8.26 times more effective than using the paste type dentifrices for 1 to 3 min. Based on these findings, it is reasonable to expect that the use of patch type dentifrices for 10 min would lead to remineralization, anti-calculus and dentinal tubules occlusion effects, and that use for 30 min would result in a whitening effect.

Physicochemical Properties of Pearl Oyster Muscle and Adductor Muscle as Pearl Processing Byproducts (진주 가공부산물(육 및 패주)의 이화학적 특성)

  • Kim, Jin-Soo;Kim, Hye-Suk;Oh, Hyeun-Seok;Kang, Kyung-Tae;Han, Gang-Uk;Kim, In-Soo;Jeong, Bo-Young;Moon, Soo-Kyung;Heu, Min-Soo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.4
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    • pp.464-469
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    • 2006
  • This study was conducted to evaluate a knowledge on food components of muscle and adductor muscle of pearl oyster (Pinctada fucata martensii) as pearl processing byproducts. The concentrations of mercury and chromium as heavy metal were not detected in both pearl oyster muscle and adductor muscle, and those of cadmium and lead were 0.06 ppm and 0.11 ppm in only pearl oyster muscle, respectively. Thus, the heavy metal levels of pearl processing byproducts were below the reported safety limits. The volatile basic nitrogen (VBN) content and pH of pearl oyster muscle were 11.6 mg/100g and 6.31 and those of abductor muscle were 8.6 mg/100 g and 6.33, respectively. It was concluded that pearl oyster muscle and adductor muscle might not invoke health risk in using food resource. The contents of crude protein (16.5%) and total amino acid (15,691 mg/100 g) of adductor muscle were higher than those of muscle (11.2% and 10,131 mg/100 g) and oyster (12.1% and 11,213 mg/100 g) as a control. The contents of calcium and phosphorus were 95.4 mg/100 g and 116.0 mg/100 g in muscle, 75.2 mg/100g and 148.1 mg/100 g in adductor muscle, respectively. The calcium level based on phosphorus was a good ratio for absorbing calcium. The free amino acid contents and taste values were 635.5 mg/100 g and 40.2 in muscle, and 734.9 mg/100 g and 24.1 in adductor muscle, respectively, but that (882.8 mg/100 g and 40.2) of oyster was higher than those of pearl processing byproducts. Based on the results of physicochemical and nutritional properties, pearl oyster muscle and adductor muscle can be utilized as a food resource.

Studies on the Effect of Various Forms of Phosphate on the Production of Paddy Rice (수도작(水稻作)에서 각종인산질비료(各種燐酸質肥料)의 비효에 관(關)한 연구(硏究))

  • Oh, W.K.
    • Korean Journal of Soil Science and Fertilizer
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    • v.1 no.1
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    • pp.27-41
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    • 1968
  • In order to clarify the effect of various forms or phosphate on the production of paddy in Korea and to find out the superiority of any form, a number of field and pot experiments involving various phosphate fertilizers were carried out in addition to conducting one each of sand culture and soil culture pot experiments in 1963 and 1964. The results of these studies are summarized as follows: 1. In sand culture experiment, the best effect of a phosphate fertilizer was obtained with the mono-calcium phosphate which is soluble in water, followed by citric acid soluble phosphate such as fused phosphate and di-calicum phosphate. However, in the pot culture and field experiments, fused phosphate had shown it's superiority than triple superphosphate which contains water soluble form of phosphate followed by hypo phosphate, roasted phosphate, compound fertilizer, and slag phosphate. The effect of rock phosphate was the least in most cases. 2. The superiority of fused phosphate to triple super phosphate in soil culture was supposed to be: a) The fused phosphate can neutralize the soil acidity. b) The fused phosphate can supply magnesium and magnesium lead to the balanced conditions of exchangeable bases in soils. c) The magnesium in the fused phosphate helps the transportation of phosphate, and regulate the absorption of the element.

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Chlorphenesin Galactoside Production using Immobilized β-galactosidase-producing Escherichia coli (고정화된 β-galactosidase 생산 대장균을 이용한 chlorphenesin galactoside 생산)

  • Jung, Kyung-Hwan
    • Journal of Life Science
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    • v.25 no.10
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    • pp.1164-1168
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    • 2015
  • Previous research showed that chlorphenesin galactoside (CPN-Gal), a preservative in cosmetics, was safer than CPN against human skin cells [9]. To establish a stable and long-term process for CPN-Gal production, we investigated the repeated-batch process. In this process, β-gal-producing recombinant Escherichia coli cells were immobilized in calcium alginate beads, and CPN was converted to CPN-Gal by the transgalactosylation reaction. The process was conducted in a 300 ml flask, which contained E. coli cell-immobilized alginate beads, 33.8 mM of CPN, and 400 g/l of lactose. The pH and temperature were 7.0 and 40℃, respectively. During the repeated-batch operation, four consecutive batch operations were conducted successfully until 192 hr. The conversion yield of CPN to CPN-Gal was 64% during 192 hr, which was higher than the values in previous reports [3, 13]. Thereafter, however, the conversion yield gradually decreased until the operation was finished at 336 hr. Western blotting of immobilized E. coli cells revealed that β-gal gradually decreased after 192 hr. In addition, alginate beads were cracked when the operation was finished. It is probable that, including this loss of E. coli cells by cracks, deactivation, and product inhibition of E. coli β-gal might lead to a gradual decrease in the production of CPN-Gal after 192 hr. However, as the purification of β-gal is not necessary with β-gal-producing recombinant E. coli cells, β-gal-producing E. coli cells might be a practical and cost-effective approach for enzymatically synthesizing CPN-Gal. It is expected that this process will be extended to long-term production process of CPN-Gal for commercialization.

Deterioration of granite in Bunhwangsaseoktap (Stone pagoda of Bunhwnagsa Temple) (분황사석탑 구성 화강암의 훼손현상)

  • Do, Jinyoung
    • Journal of Conservation Science
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    • v.17 s.17
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    • pp.73-82
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    • 2005
  • The Bunhwangsaseoktop is the oldest stone brick pagoda in Silla Period. The pagoda body is made by piling small brick-shaped stones trimmed from black andesite and the first-story core has a shrine, which is made by granite. In 1915 it was repaired on a large scale, but now is severely damaged. Many kind of the stone decay like flaking, granular disintegration have occurred especially on the granite surface of the pagoda. In this study have been investigated the stone decay type and its cause in relation to efflorescence on the body part. Various analysis show that the deterioration on the granite is due to the same materials that lead to efflorescence on the body stone surface. The soluble salt like sodium nitrate, calcium sulfate and sodium sulfate come from white joint mortar. This salt solution is recrystallized in the outside of the pagoda, but most of them flow down with rain. In This process the porous granite absorbes the dissolved salts with moisture into the inside by capillary action. In order to reduce this problem, therefore, white joint moral is changed with other less soluble materials. And it is necessary to take steps to prevent water from seep into the inside of the stone, because this water dissolves the white joint mortar.

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FIBRIN SEALANTS IN MAXILLOFACIAL SURGERY : A INTRODUCTORY REPORT (악안면 외과 영역에서의 FIBRIN SEALANTS 의 이용)

  • Kim, Myung-Jin;Park, Hyung-Kook
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.13 no.2
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    • pp.129-136
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    • 1991
  • The fibrin sealant was first designed as an alternative to surgical suture for the purpose of surface-to-surface union especially in parenchymal organs like the liver, spleen and kidney. The clinical application of currently used fibrin sealant was first introduced in 1972. The fibrin sealant consists of principal two components; lyophilized human fibrinogen and bovine thrombin. The fibrinogen component also contains coagulation factor XIII. A solution of aprotinin, an inhibitor of fibrinolysis is used to dissolve the fibrinogen and to provide the first component, and a solution of calcium chloride is also used to provide the second component. From July to December in 1990, during 6 months, we used fibrin sealant in the 28 patients of 33 various cases, in the following ways; supportive application of fibrin sealant after free autogenouse nerve graft for the repair of inferior alveolar nerve, facial nerve or accessory nerve, treament of hemangioma or lymphangioma to thrombosize and lead to the tumor shrinking, skin grafting to stimulate the adhesion and tissue repair, bone grafting in the patients of cleft alveolus, mandibular reconstruction or orthognathic surgery to facilitate the knitting of bone chips, tissue adhesion after tumor resection, radical neck dissection or flap reconstructions, and supportive adhesion of external auditory cannal after TMJ surgery via postauricular approach. No adverse effects were observed, none of the patients developed hepatitis or other blood transmitted disease, and the wound healing were acceptable.

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Enamel Renal Syndrome: A Case Report of Amelogenesis Imperfecta Associated with Nephrocalcinosis (신석회증을 동반한 희귀한 법랑질 형성 부전증 : 증례 보고)

  • Choi, Sooji;Sohn, Young Bae;Ji, Suk;Song, Seungil;Shin, Jeongwon;Kim, Seunghye
    • Journal of the korean academy of Pediatric Dentistry
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    • v.47 no.3
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    • pp.344-351
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    • 2020
  • Amelogenesis imperfecta (AI) occurs either in isolation or in association with other dental abnormalities and systemic disorder. A rare syndrome associating AI with nephrocalcinosis was named as Enamel Renal Syndrome (ERS; OMIM #204690). This syndrome is characterized by severe enamel hypoplasia, failed tooth eruption, intra pulpal calcifications, enlarged gingiva, and nephrocalcinosis. Nephrocalcinosis is a condition where calcium salts are deposited in renal tissue, and this may lead to critical kidney complications. This rare syndrome shows pathognomonic oral characteristics that are easily detectable at an early age, which proceeds the onset of renal involvement. Pediatric dentists are the first oral health practitioners whom ERS patients will meet at early age. The role of pediatric dentists is critically important for early diagnosis and referral of patients to both nephrologists for renal assessment and geneticists for identification of causative mutation and diagnosis. Early detection of renal involvement may provide chances to prevent further undesired renal complications.

Agricultural Utilization of Paper Mill Sludge Manure Compost - II. Effects on the Growth of Carrot(Daucus carota L.) (제지(製紙) 스럿지 퇴비(堆肥)의 농업적(農業的) 이용연구 - II. 당근에 대(對)한 시용효과)

  • Chang, Ki-Woon;Kim, Sang-Deog;Choi, Woo-Young;Lee, Kyu-Seung
    • Korean Journal of Soil Science and Fertilizer
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    • v.25 no.2
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    • pp.155-159
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    • 1992
  • This study was carried out to know the effects of two kinds of peper mill sludge manure compost(SMC-1 and SMC-2) on the growth and chemical comments of carrot(Daucus carota L.) : SMC-1 contained 18% of swine manure and 8 % of sawdust on a fresh weight basis and SMC-2 contained swine manure without sawdust a third of the total weight of the manure and S-0(control) was treated with chemical fertilizer only, S-1 and S-2 was with SMC-1 and SMC-2 respectively, in addition to the chemical fertilizer. Carrot treated with S-1 and S-2 showed the increasing tendency of fresh weight per root and fresh yield of carrot per unit area than control(S-0), and the contents of nitrogen(N), phosporus(P), potassium(K) and calcium(Ca) in carrot grown on SMC treatments were higher than those on control(S-0), The S-2 treatment tended to increase values of the fresh weight of live leaves, root diameter, fresh weight per root and fresh yield of carrot per unit area than S-1 treatment. The contents in carrot were higher in the order of K>Ca, N. P>Mg, and the contents of aluminium, zinc, copper and chromium were below the level of toxicity for plant growth, and the contents of cadmium and lead were negligible. From the results obtained, it can be said that SMC application showed favorable effects on the growth of carrot when compared to control(S-0), and with the SMC treatments SMC-2 aplication was favorable.

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Study on the Chemical Compositions of Sun-dried, Refined, and Processed Salt Produced in Chonbuk Area (전라북도내 천일염, 재제 및 가공염의 성분 조사에 관한 연구)

  • 조은자;신동화
    • Journal of Food Hygiene and Safety
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    • v.13 no.4
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    • pp.360-364
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    • 1998
  • The sun-dried, refined, and processed salt (roasted and bamboo salt) manufactured in Chonbuk province were analyzed their chemical compositions and minerals including heavy metals for safety evaluation. Average content of each eomponent as the lowest and the highest were as follows-pH; 6.80 (refined) to 10.35 (bamboo), water content; 0.13% (bamboo) to 10.7% (sun-dried), sodium chloride; 96.6% (roasted) to 84.3% (sun-dried), 804; 0.59% (bamboo) to 3.0% (sun-dried), water insoluble matters; 0.001% (refined) to 1.98% (bamboo), acid inoluble matters; <0.001% (refined) to 0.21% (bamboo), calcium; 0.038% (refined) to 0.213% (sun-dried), magnesium; 0.111% (refmed) to 1.078% (sun-dried), lead; 0.45 ppm (refmed) to 1.15 ppm (bamboo). Cadminium, arsenic and mercury were not detected in all salt. As the analytical results, all salts were differtent in their chemical compositions and safe in view of heavy metals.

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