• Title/Summary/Keyword: Lead Shift

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Optical Properties of Sn-doped CH3NH3PbBr3 Perovskite Nanoparticles (Sn 첨가에 따른 CH3NH3PbBr3 페로브스카이트 나노입자의 광학적 특성)

  • Sihn, Moon Ryul;Jeon, Mingi;Park, Hyerin;Choi, Jihoon
    • Journal of the Korean institute of surface engineering
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    • v.52 no.2
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    • pp.90-95
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    • 2019
  • Methylammonium lead bromide ($MAPbBr_3$) has attracted a lot of attention due to their excellent optoelectronic properties such as the compositional flexibility relevant to photoluminescence (PL) and UV-Vis absorbance spectrum, high diffusion length, and photoluminescence quantum yield (PLQY). Despite such advantages of organic-inorganic perovskite materials, more systematic study on manipulation of their optoelectronic properties in homo- or heterovalent metal ions doped halide perovskite nanocrystals is lacking. In this study, we systematically investigated the optical properties of colloidal $CH_3NH_3Pb_{1-x}Sn_xCl_{2x}Br_{3-2x}$ particles by addition of $SnCl_2$ into the typical methylammonium lead tribromide ($CH_3NH_3PbBr_3$) precursor solution. We found that only 1% addition of $SnCl_2$ shows a significant blue-shift from 540 nm to 420 nm in UV-Vis absorbance spectrum due to the strong quantum confinement effect. Furthermore, continuous blue-shift in photoluminescence spectra was observed as the amount of Cl increases. These experimental results provide new insights into the replacement of Pb within $MAPbBr_3$, required for the broadening of their application.

The Effect of Occupational Noise Exposure on Serum Cortisol Concentration of Night-shift Industrial Workers: A Field Study

  • Zare, Sajad;Baneshi, Mohammad R.;Hemmatjo, Rasoul;Ahmadi, Saeid;Omidvar, Mohsen;Dehaghi, Behzad F.
    • Safety and Health at Work
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    • v.10 no.1
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    • pp.109-113
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    • 2019
  • Background: In both developed and developing countries, noise is regarded as the most common occupational hazard in various industries. The present study aimed to examine the effect of sound pressure level (SPL) on serum cortisol concentration in three different times during the night shift. Methods: This case-control study was conducted among 75 workers of an industrial and mining firm in 2017. The participants were assigned to one of the three groups (one control and two case groups), with an equal number of workers (25 participants) in each group. Following the ISO 9612 standard, dosimetry was adopted to evaluate equivalent SPL using a TES-1345 dosimeter. The influence of SPL on serum cortisol concentration was measured during the night shift. The serum cortisol concentration was measured using a radioimmunoassay (RIA) test in the laboratory. Repeated measure analysis of variance and linear mixed models were used with ${\alpha}=0.05$. Results: The results indicated a downward trend in the serum cortisol concentration of the three groups during the night shift. Both SPL and exposure time significantly affected cortisol concentration (p < 0.0001, p < 0.0001). Conversely, age and body mass index had no significant influence on cortisol concentration (p = 0.360, p = 0.62). Conclusion: Based on the obtained results, increasing SPL will lead to enhancement of serum cortisol concentration. Given that cortisol concentration varies while workers are exposed to different SPLs, this hormone can be used as a biomarker to study the effect of noise-induced stress.

IPMSM Design for Sensorless Control Considering Magnetic Neutral Point Shift According to Magnetic Saturation

  • Choi, JaeWan;Seol, Hyun-Soo;Lee, Ju
    • Journal of Electrical Engineering and Technology
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    • v.13 no.2
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    • pp.752-760
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    • 2018
  • In this paper, interior permanent magnet synchronous motor (IPMSM) design for sensorless drive, considering magnetic neutral point shift according to magnetic saturation, has been proposed. Sensorless control was divided into a method based on inductance and a method based on back induced voltage. Because induced voltage is very small at zero or low speed, error in rotor initial position estimation may occur. Using the ratio of saliency addresses this problem. When using high-frequency injections at low speed, the rotor's initial position is estimated at the smallest portion of the inductance. IPMSM has the minimum inductance at the d-axis. However, if magnetic saturation leads to magnetic neutral point variation, following the load current change, there is a change in the minimum point of inductance. In this case, it can lead to failure of initial rotor position estimation. As a result, it is essential that the blocking design has an inductance minimum point shift. As such, in this study, an IPMSM design method, by blocking magnetic neutral point change, has been proposed. After determining the inductance profile based on the finite element analysis (FEA), the results of proposed method were verified.

Design and Fabrication of Tool Change Multi-nozzle FDM 3D Printer (툴 체인지 방식 멀티 노즐 3D프린터의 설계 및 제작)

  • Suk, Ik-hyun;Park, Jong-kyu
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.2
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    • pp.38-44
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    • 2021
  • To cater to the transition from single-color to multicolor/multi-material printing, this paper proposes a cartridge-replacing type multi-nozzle Fused Depositon Modeling(FDM) three-dimensional (3D) printer. In the test printing run, tool change failure/wobble/layer shift occurred. It was confirmed that improper support was the cause of this tool change failure. As a solution, spline and electromagnetic cartridges were designed. Wobble was caused by machine vibration and the motor stepping out. To minimize wobble, an additional Z-axis was installed, and the four-point bed leveling method was used instead of the three-point bed leveling method. The occurrence of layer shift was ascribed to the eccentricity of the Z-axis lead screw. Therefore, slit coupler was replaced with an Oldham type. In addition to the mechanical supplementation, the control environment was integrated to prevent accidents and signal errors due to wire connections. Before the final test printing run, a rectifier circuit was added to the motor to secure precise control stability. The final test printing run confirmed that the wobble/layer shift phenomenon was minimized, and the maximum error between layers was reduced to 0.05.

POSSIBLE MERGER SIGNATURE IN SZ MAPS

  • KOCH PATRICK
    • Journal of The Korean Astronomical Society
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    • v.37 no.5
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    • pp.471-476
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    • 2004
  • We propose an analytical model to estimate the influence of a merger on the thermal SZ effect. Following observations we distinguish between subsonic and transonic mergers. Using analytical velocity fields and the Bernoulli equation we calculate the excess pressure around a moving subcluster for an incompressible subsonic gas. Positive excess around the stagnation point and negative excess on the side of the subcluster lead to characteristic signatures in the SZ map, of the order of $10\%$ compared to the unperturbed signal. For a transonic merger we calculate the change in the thermal spectral SZ function, resulting from bow shock accelerated electrons. The merger shock compression factor determines the power law tail of the new non-thermal electron population and is directly related to a shift in the crossover frequency. This shift is typically a few percent towards higher frequencies.

Determination of Quality Cost Policy under the Multiple Assignable Causes (다중이상원인하의 경제적 품질비용 정책결정)

  • Kim Kyewan;Park Ji Yeon;Yun Deok Kyun
    • Proceedings of the Society of Korea Industrial and System Engineering Conference
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    • 2002.05a
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    • pp.1-8
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    • 2002
  • At present, company has to produce a product that consumer like with a competitive price, a good quality, and a fitting time to supply. Process control and qualify control are very important to supply with a product uniformly and inexpensively In this paper, the characteristic of product quality is monitored by control chart during the machining process and construction of quality control cycle is considered to divide into two types in this case that different assignable causes lead to shifts having different magnitudes. Then we are intended to find a process shift magnitude which has economical quality cost policy and are considered to quality cost functions to find a process shift magnitude. Those costs are categorized into the well-known categories of prevention, appraisal, and internal failure and external failure. This paper ends with numerical examples that demonstrate the usefulness of the model.

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Modeling and Evaluation of Slip-Mode Frequency Shift Method for Anti-islanding Method (슬립모드 방식을 이용한 단독운전 검출기법의 모델링과 평가)

  • Yu, Byung-Gyu;Jung, Young-Seok;So, Jung-Hun;Yu, Gwon-Jong
    • Proceedings of the KIPE Conference
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    • 2005.07a
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    • pp.520-522
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    • 2005
  • Islanding phenomenon is undesirable because it lead to a safety hazard to utility service personnel and may cause damage to power generation and power supply facilities as a result of unsynchronized reclosure. In order to prevent this phenomenon, various anti-islanding methods have been studied. Even though the slip mode frequency shift (SMS) method has been regarded as a highly effective anti-islanding method, the analytical design method of that was not cleared. This paper proposes a modeling of the SMS method using non-detection zone (NDZ) and evaluation of the method according to the test conditions of IEEE Std. 929-2000. The SMS method is derived analytically through the modeling and verified visually by simulation and experiment.

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Gold Nanoparticle Optical Effect on Graphene (금 미세 입자에 의한 그래핀 광학 특성 변화)

  • Park, Byeongho;Lim, Juhwan;Jun, Seong Chan
    • Transactions of the Society of Information Storage Systems
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    • v.9 no.1
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    • pp.1-4
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    • 2013
  • Graphene and Graphene oxide have intense interest in fields such as physics, chemistry, and materials science, among others. They are the promising material for solving the current limitation that organics have barely luminescence. We observed variation of photoluminescence on graphene oxide based solution with Gold nanoparticle. Gold nanoparticles lead to shift the peak wavelength of graphene oxide and to enhance the photoluminescence intensity totally. This shows the possibility that control the luminescence property of graphene oxide by adding gold nanoparticle.

Analysis and Modeling of Slip Mode Frequency Shift Method for Anti-islanding (슬립모드 주파수변이 방식의 단독운전 검출법의 분석과 모델링)

  • Yu, Byung-Gyu;Jung, Young-Seok;So, Jung-Hun;Yu, Gwon-Jong
    • Proceedings of the KIEE Conference
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    • 2005.07b
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    • pp.1699-1701
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    • 2005
  • Islanding phenomenon is undesirable because it lead to a safety hazard to utility service personnel and may cause damage to power generation and rower supply facilities as a result of unsynchronized reclosure. In order to prevent this phenomenon, various anti-islanding methods have been studied. Even though the slip mode frequency shift(SMS) method has been regarded as a highly effective anti-islanding method, the analytical design method of that was not cleared. This paper proposes a modeling of the SMS method using non-detection tone(NDZ) and evaluation of the method according to the test conditions of IEEE Std. 929-2000. The SMS method is derived analytically through modeling and verified visually by simulation and experiment.

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Deciphering Key Genes of Proliferative and Secretory Phase Using Integrated Transcriptomics and Network Analysis

  • Payal Gupta;Shriya Dube;Payal Priyadarshini;Shanvi Singh;Anasuya Pravallika R;Vijay Lakshmi Srivastava;Abhishek Sengupta;Priyanka Narad
    • Microbiology and Biotechnology Letters
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    • v.51 no.3
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    • pp.317-324
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    • 2023
  • Endometrium receptivity is a complex mechanism of intricate pathways that lead to the shift from the proliferative to the secretory phase. Our goal was to identify high-ranking differentially expressed genes and study the pathways associated with the phenomenon. Raw data were retrieved from six GEO datasets and 705 DEGs were identified through robust ranking aggregation after the integration of five datasets. 20 key genes were identified that were further re-validated in an additional dataset. Supporting evidence through the experimental references confirms them as major biomarkers of the shift from the proliferative to the secretory phase.