• Title/Summary/Keyword: Lead Oxide

Search Result 375, Processing Time 0.022 seconds

Electrical and Piezoelectric Properties on the Piezoceramics PZT Substituted for B-Sites (압전 세라믹(PZT)의 B-Site 치환에 따른 전기 및 압전 특성)

  • 이수호;박준범;사공건
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1992.05a
    • /
    • pp.133-136
    • /
    • 1992
  • Electrical resistivity and piezoelectric properties were investigated in Lead Zirconate-Titante(PZT) with Nb$_2$O$\sub$5/dopant, fabricated from conventional mixed-oxide powders and molten salt synthesis. The resistivity and electromechanical coupling factor(K$\sub$p/) were increased with increasing Nb content. The reason for increasing of the electrical resistivity below the Curie Temperature(TC). It is believed that the Curie Temperature(Tc). It is believed that the p-type electrical conduction in PZT is due to lead vacancies. The electromechanical coupling factor(K$\sub$p/) and piezoelectric constant d$\sub$33/ were improved. This behavior can be explained as a compensation effect and Nb$\^$5+/ can serve as a donar and contribute electrons to the conduction process. As a result, the optimized Nb$_2$O$\sub$5/ dopants on the PZT specimens were 0.75 wt%.

  • PDF

Effect of different tungsten compound reinforcements on the electromagnetic radiation shielding properties of neopentyl glycol polyester

  • Can, Omer;Belgin, Ezgi Eren;Aycik, Gul Asiye
    • Nuclear Engineering and Technology
    • /
    • v.53 no.5
    • /
    • pp.1642-1651
    • /
    • 2021
  • In this study, isophtalic neopentyl glycol polyester (NPG-PES) based composites with different loading ratios of pure tungsten metal (W), tungsten (VI) oxide (WO3), tungsten boron (WB) and tungsten carbide (WC) composites were prepared as alternative shielding materials for ionizing electromagnetic radiation (IEMR) shielding. Structural characterizations of the composites were done. Gamma spectrometric analysis of composites for 80-2000 keV energy range was performed and their usability as IEMR shielding was discussed. As a result, the produced composites showed a shielding performance of 60-100% of the lead (the most widely used IEMR shielding material) depending on the reinforcement material, reinforcement loading rate and experimental conditions. Thus, it was reported that produced composites could be an alternative to lead shieldings that have several disadvantages as toxic properties, difficulty of processing and inelasticity.

Gas Sensitization of Tin Oxide Film by Resistance

  • Chwa, Sang-Ok;Park, Hee-Chan;Kim, Kwang-Ho
    • The Korean Journal of Ceramics
    • /
    • v.4 no.3
    • /
    • pp.183-188
    • /
    • 1998
  • Gas sensitizations of tin oxide film were investigated by measuring the change of film resistance in various gas atmospheres such as $N_2,\; O_2,\; H_2O$. The main test sample, polycrystalline $SnO_2$ film containing small Sb as a dopant was prepared by a sputtering technique and showed a long term stability in base resistance and thus, in gas sensitivity. The adsorption of oxygen on the film surface as a type of $(O_{ads})$ at the temperature of around $300^{\circ}C$ played important roles in sensor operating mechanism. The roles were ⅰ) the increase of base resistance in ambient air, which consequently lead to high sensitivity and ⅱ) the promotion of fast recovery. The reaction of hydrogen gas with the already adsorbed $(O_{ads})$ ions was considered as a decisive sensitization mechanism of tin oxide film. However, the dissociation of hydrogen molecules on film surface, by direct donation of electron to film also took a major part in the sensitization. The effect of humidity on gas sensitization was found to be negligible at the sensor operating temperature of around $300^{\circ}C$.

  • PDF

A study on the Glass Frit for Thick Film Copper Conductor (후막 구리도체용 유리에 관한 연구)

  • Lee, Joon;Lee, Sang Won
    • Applied Chemistry for Engineering
    • /
    • v.2 no.3
    • /
    • pp.289-299
    • /
    • 1991
  • In order to obtain glasses appropriate to the thick film copper conductors, nine glasses based on both lead borosilicate and leadless borosilicate systems were made and the applicabilities of them were examined in conjunction with the requirements for thick film copper conductors. As the results, it was found that all the glasses are fitted to provide suitable sheet resistance, solderability and solder leach resistance to thick film copper conductors. However, it was turned out that only the lead borosilicate based glasses worked for getting usable aged adhesion strength of copper thick film to the alumina substrate, while copper conductor films made from the other glasses had poor aged adhesion strengths. Particularly cuprous oxide added lead borosilicate glass was considered as one of the most favorable glasses for manufacturing thick film copper conductors.

  • PDF

Electrical Properties of (Ba,Ca)(Ti,Zr)O3 Ceramics for Bimorph-type Piezoelectric Actuator

  • Shin, Sang-Hoon;Yoo, Ju-Hyun
    • Transactions on Electrical and Electronic Materials
    • /
    • v.15 no.4
    • /
    • pp.226-229
    • /
    • 2014
  • In this study, lead-free $(Ba_{0.85}Ca_{0.15})(Ti_{1-x}Zr_x)O_3$ ceramics and a bimorph-type piezoelectric actuator were fabricated using the normal oxide-mixed sintering method, and their dielectric properties, microstructure, and displacement properties were investigated. From the results of X-ray diffraction, the pattern of the specimen has a pure perovskite structure. In addition, no secondary impurity phases were found. The excellent piezoelectric coefficient of $d_{33}=454pC/N$, the electromechanical coupling factor $k_p=0.51$, the dielectric constant ${\varepsilon}_r=3,657$, the mechanical quality factor $Q_m=239$, and $T_c$(Tetragonal-Cubic) =$90^{\circ}C$ were shown at x= 0.085. ${\Delta}k_p/k_p20^{\circ}C$ and ${\Delta}f_r/f_r20^{\circ}C$ showed the maximum value of -0.255 and 0.111 at $-20^{\circ}C$ and $80^{\circ}C$, respectively. The maximum total-displacement was $60{\mu}m$ under the input voltage of 50 V. As a result, it is considered that lead-free $(Ba_{0.85}Ca_{0.15})(Ti_{1-x}Zr_x)O_3$ ceramics is a promising candidate for piezoelectric actuator application for x= 0.085.

Study on the Electrical Insulation of Current Lead in the conduction-cooled 1-2kV Class High-Tc Superconducting DC Reactor (전도냉각되는 1-2kV급 고온초전도 직류리액터 전류도입부의 전기적 절연에 대한 연구)

  • 배덕권;안민철;이찬주;정종만;고태국;김상현
    • Progress in Superconductivity and Cryogenics
    • /
    • v.4 no.1
    • /
    • pp.30-34
    • /
    • 2002
  • In this Paper, Insulation of current lead in the conduction-cooled DC reactor for the 1.2kV class 3 high-Tc superconducting fault current limiter(SFCL) is studied. Thermal link which conducts heat energy but insulates electrical energy is selected as a insulating device for the current lead in the conduction-cooled Superconducting DC reactor. It consists of oxide free copper(OFC) sheets, Polyimide films, glass fiberglass reinforced Plastics (GFRP) plates and interfacing material such an indium or thermal compound. Through the test of dielectric strength in L$N_2$, polyimide film thickness of 125 ${\mu}{\textrm}{m}$ is selected as a insulating material. Electrical insulation and heat conduction are contrary to each other. Because of low heat conductivity of insulator and contact area between electrical insulator and heat conductor, thermal resistance of conduction-cooled system is increased. For the reducing of thermal resistance and the reliable contact between Polyimide and OFC, thermal compound or indium can be used As thermal compound layer is weak layer in electrical field, indium is finally selected for the reducing of thermal resistance. Thermal link is successfully passed the test. The testing voltage was AC 2.5kVrms and the testing time was 1 hour.

Piezoelectric Properties of Lead Free (Na1K1Cd)NbO3 Ceramics ((Na1K1Cd)NbO3 무연 세라믹스의 압전특성)

  • No Young-Woo;Yoo Young-Bae;Son Se-Mo;Chung Su-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.19 no.8
    • /
    • pp.717-723
    • /
    • 2006
  • Lead free $(Na_{0.5}K_{0.47}Cd_x)NbO_3$ ceramics (x=0.015-0.005) were prepared by the conventional mixed oxide route. The effects of CdO addition on the sintering, dielectric and piezoelectric properties of the samples were examined. The addition of CdO greatly enhanced the sinterability of ceramics and the sample has a lower dielectric loss. The $k_p\;and\;Q_m$ of the samples with 0.02 mol CdO addition are 0.35 and 125, respectively, The $(Na,K)NbO_3$ ceramics show a large degradation of $k_p$ due to the deliquescence when exposed to humidity, while the $(Na,K,Cd)NbO_3$ ceramics have no a significant degradation of it.

Piezoelectric Properties of NKN-BZT Ceramics Sintered with CuO and ZnO Additives (CuO와 ZnO 첨가에 따른 NKN-BZT 세라믹스의 압전 특성)

  • Lee, Seung-Hwan;Baek, Sang-Don;Lee, Dong-Hyun;Lee, Sung-Gap;Lee, Young-Hie
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.24 no.8
    • /
    • pp.636-640
    • /
    • 2011
  • The lead-free $0.98(Na_{0.5},K_{0.5})NbO_3-0.02Ba(Zr_{0.52},Ti_{0.48})O_3$-(hereafter NKN-BZT) CuO, ZnO-doped ceramics were prepared using a conventional mixed oxide method. NKN-BZT ceramics doped CuO, ZnO have superior structural and electrical properties than pure NKN-BZT ceramics. For the NKN-BZT-ZnO ceramics sintered at $1,120^{\circ}C$, piezoelectric constant ($d_{33}$) of sample showed the optimum values of 172 pC/N. The $0.98(Na_{0.5},K_{0.5})NbO_3-0.02Ba(Zr_{0.52},Ti_{0.48})O_3$-ZnO ceramics are a promising candidate for lead-free piezoelectric materials.

Trend in New Distribution Class Arrester Ground Lead Disconnector Design (신뢰성이 향상된 배전급 피뢰기 설계 기술의 동향)

  • Lee, Ju-Hong;Yun, Ju-Ho;Kim, In-Hee;Choi, Yong-Sung;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2007.06a
    • /
    • pp.541-542
    • /
    • 2007
  • The paper also introduces a new Distribution Class ground lead disconnector design that not only extends the claimable detonation range well below the 20 amps specified in industry standards, but is very durable when exposed to severe arrester durability tests. Finally. this paper shows how this next generation disconnector interacts with the connected arrester to improve the overvoltage withstand capability of the arrester assembly. The interaction of the disconnector grading capacitor with the series-connected arrester metal oxide disc elements actually improves the arrester assembly temporary overvoltage withstand capability, making the design less vulnerable to TOV failures. Since the vast majority of distribution class arresters are sold domestically with ground lead disconnectors, this design improvement in the disconnector to improve detonation reliability also translates into a significantly improved distribution class arrester design.

  • PDF

Isolation of the Constituent Inhibiting Nitric Oxide formation from Lycopus lucidus in LPS-induced Macrophage Cells (LPS로 유도한 대식세포에서 Nitric Oxide 생성을 저해하는 쉽싸리 성분의 분리)

  • Park, Hee-Juhn
    • Korean Journal of Plant Resources
    • /
    • v.32 no.4
    • /
    • pp.264-269
    • /
    • 2019
  • This research was performed to identify the anti-inflammatory constituent from the herb of Lycorus lucidus (Lamiaceae). The MeOH extract of this plant material and its two fractions, the lipophilic- ($CHCl_3$ fraction) and the hydrophilic fraction (BuOH fraction), were prepared to test anti-inflammatory activity. For this purpose, the inhibition rate on inducible nitric oxide synthase (iNOS) activity was assessed by determining nitric oxide (NO) formation in lipopolysaccharide (LPS)-induced macrophage 264.7 cells. The $CHCl_3$ fraction that greatly inhibited nitric NO formation was chromatographed to lead the isolation of ursolic acid. Since ursolic acid inhibited NO formation dose dependently in this study, this compound was considered as one of the active constituent responsible for anti-inflammation. However, the activity of rosmarinic acid isolated from the BuOH fraction was weak.