• 상하수도학회지
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• 제25권1호
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• pp.1-5
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• 2011

Arsenic is one of the most abundant contaminant found in waste mine tailings and soil around refinery, Because of its carcinogenic property, the countries like United States of America and Europe have made stringent regulations which govern the concentration of arsenic in soil. The study focuses on solidification/stabilization for removal of arsenic from soil. Cement was used to solidify/stabilize the abandoned soil primarily contaminated with arsenic (up to 68.92 mg/kg) in and around refinery. Solidified/stabilized (s/s) forms in the range of cement contents 5-30 wt % were evaluated to determine the optimal binder content. Revised Korean standard leaching tests (KSLT), toxicity characteristic leaching procedures (TCLP), Old Korea standard leaching test and revised Korea standard leaching test were used for chemical characterization of the S/S forms. The addition of 10 % cement remarkably reduced the leachability of arsenic in contaminated soil. The concentration of As in leachate of TCLP, KSLT, and old KSLT for soil are below the standard. However that in leachate of revised KSLT is above the standard. Because of extraction fluid used in revised KSLT is very strong acid. It is arsenic in s/s with binder should be exhaustingly leached. Therefore S/S process would not be available for As treatment in soil in Korea.

• Journal of the Korean Wood Science and Technology
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• 제35권5호
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• pp.46-57
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• 2007

The leachability of boron in zinc borate (ZB)-modified oriented strandboard (OSB) from southern wood species was investigated in this study. The leaching experiments were conducted by exposing edge-sealed OSB samples under running water at $31^{\circ}C$ for 8, 24, 72, and 216 h. The results from leached samples were compared with those from the unleached controls. Boron leaching of the modified OSB occurred upon the initial water exposure, and the leaching rate decreased as the leaching time increased. Initial boric acid equivalent (BAE) level, wood species, and sample thickness swelling significantly influenced the leachability. There was no consistent effect of polyethylene glycol (PEG) on zinc borate leaching. The glue-line washing within OSB due to thickness swelling of the test samples under water and decomposition of the borate to form water-soluble boric acid were thought to be two possible causes for the observed leaching. The relationship between assayed BAE and leaching time followed a decaying exponential function for zinc borate treated OSB. From the boron/zinc ratio after each leaching period, boron element in ZB was more or less leachable. The material constant of the regression models allowed comparing the leachability of the modified OSB for various wood species. An unified leaching method for treated wood composite materials is needed.

• Nuclear Engineering and Technology
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• 제55권8호
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• pp.2889-2896
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• 2023

The waste acceptance criteria for heavy metals in mixed waste should be developed by reflecting the leaching behaviors that could highly depend on the repository design and environment surrounding the waste. The current standards widely used to evaluate the leaching characteristics of heavy metals would not be appropriate for the silo-type repository since they are developed for landfills, which are more common than a silo-type repository. This research aimed to explore the leaching behaviors of cementitious waste with Pb, Cd, and Sb metallic and oxide powders in an environment simulating a silo-type radioactive waste repository. The Toxicity Characteristic Leaching Procedure (TCLP) and the ANS 16.1 standard were employed with standard and two modified solutions: concrete-saturated deionized and underground water. The compositions and elemental distribution of leachates and specimens were analyzed using an inductively coupled plasma optical emission spectrometer (ICP-OES) and energy-dispersive X-ray spectroscopy combined with scanning electron microscopy (SEM-EDS). Lead and antimony demonstrated high leaching levels in the modified leaching solutions, while cadmium exhibited minimal leaching behavior and remained mainly within the cement matrix. The results emphasize the significance of understanding heavy metals' leaching behavior in the repository's geochemical environment, which could accelerate or mitigate the reaction.

• Nuclear Engineering and Technology
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• 제55권2호
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• pp.566-574
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• 2023

Investigating the seepage characteristics of the leaching solution in the ore-bearing layer during the in situ leaching process can be useful for designing the process parameters for the uranium mining well. We prepared leaching solutions of four different viscosities and conducted experiments using a self-developed multifunctional uranium ore seepage test device. The effects of different viscosities of leaching solutions on the seepage characteristics of uranium-bearing sandstones were examined using seepage mechanics, physicochemical seepage theory, and dissolution erosion mechanism. Results indicated that while the seepage characteristics of various viscosities of leaching solutions were the same in rock samples with similar internal pore architectures, there were regular differences between the saturated and the unsaturated stages. In addition, the time required for the specimen to reach saturation varied with the viscosity of the leaching solution. The higher the viscosity of the solution, the slower the seepage flow from the unsaturated stage to the saturated stage. Furthermore, during the saturation stage, the seepage pressure of a leaching solution with a high viscosity was greater than that of a leaching solution with a low viscosity. However, the permeability coefficient of the high viscosity leaching solution was less than that of a low viscosity leaching solution.

• 한국농공학회논문집
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• 제53권3호
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• pp.83-91
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• 2011

This study aimed to investigate the engineering and environmental characteristics of phosphogypsum-cement-soil mixtures composed of phosphogypsum, soil, and a small amount of cement was analysed on the basis of the unconfined compression test, the tensile strength test, the freezing and thawing test, the wetting and drying test, SEM and EDS analysis, XRD analysis and Leaching test. The specimens were manufactured with soil, cement and phosphogypsum. The cement contents was 10 %, and the phosphogypsum contents was 10, 20, 30, and 40 % by the weight of total dry soil. Each specimen was manufactured after curing at constant temperature and humidity room for 3, 7 and 28 days, after which the engineering characteristics of phosphogypsum-cement-soil mixtures were investigated using the unconfined compression test, the tensile strength test, the freezing and thawing test, the wetting and drying test. The basic data were presented for the application of phosphogypsum-cement-soil mixtures as construction materials. To investigate the environmental characteristics, leaching test was performed and the leaching test results were far below than of regulatory requirement of Waste Management Act in Korea. Therefore the results show that phosphogypsum is environmentally safe and can be used as construction materials in environmental aspect.

• 한국결정성장학회지
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• 제19권3호
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• pp.135-143
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• 2009

$Cr^{6+}$의 고용화 가능성과 lignin계 혼화제의 성능을 조사하기 위하여 과잉의 $Cr^{6+}$을 첨가하여 KSLI, 미국 TCLP법, Soaking Procedure를 이용하여 각 기준에 따른 용출 특성을 조사하였다. 그 결과 lignin계 혼화제는 첨가에 따라 모르타르 강도 증진을 보였으며 용출 특성에 큰 변화는 없었다.

• Environmental Engineering Research
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• 제11권1호
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• pp.14-27
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• 2006

The proper management of discarded electronic devices (often called electronic-waste) is an emerging issue for solid waste professionals throughout the world because of the large growth of the waste stream, and the content of toxic metals in them, most notably heavy metals such as lead. Notebook computers are becoming one of the major components of discarded computer devices and will continue to increase in the waste stream in the future. While the computers hold great promise for recycling, a substantial amount of this waste is often disposed in municipal solid waste (MSW) landfills. The toxicity characteristic leaching procedure (TCLP) is commonly used to simulate worse case leaching conditions where a potentially hazardous waste is assumed to be disposed along with municipal solid waste in a landfill with actively decomposing materials overlying an aquifer. The objective of this study was to examine leaching potential of lead from discarded notebook computers using the scale-up TCLP, other standard leaching tests such as California waste extraction test (Cal WET), and the synthetic precipitation leaching procedure (SPLP) and actual landfill leachates as leaching solution. The scale-up TCLP is a modified TCLP (where the device was disassembled and leached in or near entirety) to meet the intent of the TCLP. The results showed that the scale-up TCLP resulted in relatively high lead found in the leachate with an average of 23.3 mg/L. The average level was less than those by the standard TCLP and WET (37.0 mg/L and 86.0 mg/L, respectively), but much greater than those by the SPLP and the extractions with the landfill leachates (0.55 mg/L and 1.47 mg/L, respectively). The pH of the leaching solution and the ability of the organic acids in the TCLP and WET to complex with the lead were identified as major factors that controlled the amount of lead leached from notebook computers. Based on the results obtained by a number of leaching tests in this study, notebook computers may present a potential leaching risk to the environment and human health upon land disposal. However, further investigation is still needed to assess the true risk posed by the land disposal of discarded notebook computers.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2001년도 총회 및 춘계학술발표회
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• pp.30-33
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• 2001

Melting is one of the most effective treatments for stabilizing heavy metals and also creates high value by-products. In this study, authors evaluated the leaching characteristics of heavy metals in melting slag obtained from incinerator ashes. In order to evaluate the environmental compatibility of the recycled melting slag, the samples analysed various leaching tests of heavy metals were raw incinerator ashes, melting slag and the construction materials recycled from melting slag. As the results: (1) The leaching concentrations of tile melting slag were lower than those of the raw incinerator ashes in the experiment performed in accordance with Korea Standard Leaching Test (KSLT). (2) The result of leaching test with the method of RG Min-StB 93. FGSV Forschungsgesellschaft fur Stra $\beta$ en- und Verkehrswesen) met the requirements in German. (3) The compressive strengths of mortar samples used for evaluating the feasibility of recycling the melting slag as construction materials also showed the suitable range for recycling (4) Melting slag was considered the stable materials with respect to the chemical stability against chemical solutions with various pH conditions.

• Environmental Engineering Research
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• 제10권3호
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• pp.112-121
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• 2005

The effectiveness of quicklime-based stabilization/solidification (S/S) in immobilizing lead (Pb) was assessed by performing semi-dynamic leaching tests (ANS16.1). In order to simulate landfill leaching conditions, the ANS 16.1 test was modified by using 0.014 N acetic acid (pH = 3.25) instead of distilled water. Artificial soil samples as well as field soil samples contaminated with Pb were tested. The effectiveness of quicklime treatment was evaluated by determining diffusion coefficients ($D_e$) and leachability indices (LX). A model developed by de Groot and van der Sloat was used to elucidate the controlling Pb leaching mechanisms. Overall, upon quicklime treatment Pb leachability was significantly reduced in a]l of the samples tested. The mean LX values were higher than 9 for an artificial soil sample containing 30% kaolinite treated with 10% quicklime and for a field soil sample treated with 10% quicklime, which suggests that S/S treated soils can be considered acceptable for "controlled utilization". Moreover, quicklime treatment was more effective in artificially contaminated soil with high kaolinite content (30%), indicating the amount of clay plays an important role in the success of the treatment. The controlling Pb leaching mechanism was found to be diffusion, in all quicklime treated samples.

• 한국응용과학기술학회지
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• 제16권3호
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• pp.211-216
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• 1999

This study was conducted to recover the aluminum from water treatment plant sludge containing alumina. The optimum reaction conditions about chlorination of sludge with $NH_4Cl$ are as follows: the weight ratio of sludge to $NH_4Cl$ is 4, the reaction time is 60min, and the temperature is $300^{\circ}C$. And the result of leaching time test showed that the highest yield of alumina at $160^{\circ}C$ was 96% but the result of leaching test at $160^{\circ}C$ was little better than that of leaching test at $100^{\circ}C$ while the leaching concentration of HCl was 4N. The optimum reaction conditions of chlorinated sludge with $NH_4Cl$, gave the highest yield of 95.41% based on aluminum.