• Title/Summary/Keyword: Leach

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The Recovery of Silver from Thiourea Leaching Solution by Cementation Technique (침전법을 이용한 Thiourea 용출용액으로부터 Silver 회수)

  • Kim, Bong-Ju;Cho, Kang-Hee;Choi, Nag-Choul;Park, Cheon-Young
    • Economic and Environmental Geology
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    • v.46 no.1
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    • pp.29-37
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    • 2013
  • In order to apply the silver cementation method using Fe powder from pregnant thiourea leaching solution. Parameters such as the amount of Fe powder addition, agitation speed, and temperature were investigated. The silver cementation rate was increased by the increasing of Fe powder addition, agitation speed, and temperature. The highest silver cementation rate was found when the addition of Fe powder was 50 g/L at the agitation speed of 500 rpm. The silver cementation rate increase with increasing temperature according to the Arrhenius equation and obeys $1^{st}$ order kinetics. The activation energy from the kinetics data was found to be between 13.73 KJ/mol and 17.02 KJ/mol. In the XRD analysis, goethite was detected in the precipitate of the thiourea leach solution. This indicates that an oxidation-reduction reaction had occurred in the thiourea solution due to the addition of the Fe powder.

Bioleaching of valuable metals from electronic scrap using fungi(Aspergillus niger) as a microorganism (곰팡이균(Aspergillus niger)을 이용(利用)한 전자스크랩중 유가금속(有價金屬)의 미생물(微生物) 침출(浸出) 연구(硏究))

  • Ahn, Jae-Woo;Jeong, Jin-Ki;Lee, Jae-Chun;Kim, Dong-Gin
    • Resources Recycling
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    • v.14 no.5 s.67
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    • pp.24-31
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    • 2005
  • In order to recover valuable metals from fine-grained electronic waste, bioleaching of Cu, Zn, Al, Co, Ni, Fe, Sn and Pb were carried out using Aspergillus niger as a leaching microorganism in a shaking flask. Aspergillus niger was able to grow in the presence of electronic scrap. The formation of organic acids(citric and oxalic acid) from Aspergillus niger caused the mobilization of metals from waste electronic scrap. In a preliminary study, in order to obtain the data on the leaching of Cu, Zn, Al, Fe, Co and Ni from electronic scrap, chemical leaching using organic acid(Citric acid and Oxalic acid) was accomplished. At the electronic scrap concentration of 50 g/L, Aspergillus niger were able to leach more than 95% of the available Cu, Co. But Al, Zn, Pb and Sn were leached about 15-35%. Ni and Fe were detected in the leachate less than 10%.

Recovery of Precious Metals from Spent Catalyst Generated in Domestic Petrochemical Industry (한내 석유화학 폐촉매로부터 귀금속의 회수 연구)

  • 김준수;박형규;이후인;김성돈;김철주
    • Resources Recycling
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    • v.3 no.1
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    • pp.17-24
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    • 1994
  • Recovery of precious metal values from petrochemical spent catalyst is important from the viewpoint of environmental protection and resource recycling. Two types of spent catalysts were used in this study. One used in the manufacture of ethylene contains 0.3% Pd in the alumina substrate. The other used in oil refining contains 0.3% Pt and 0.3% Re. Both spent catalysts are roasted to remove volatile matters as carbon and sulfur. Then, metallic Pd powder from Pd spent catalyst is obtained in the course of grinding, hydrochloric acid or aqua regia leaching and cementation with iron. For the recovery of Pt and Re from Pt-Re spent catalyst, Pt and Re are leached with either HCI or aqua regia, first. Metallic Pt powder is recovered from the leach solution by cementation with Fe powder. Re in sulfide form is precipitated by the addition of sodium sulfide to the solution obtained after Pt recovery. It is found that 6N HCI can be successfully used as leaching agent for both types of spent catalyst. 6N HCI is considered to be better than aqua regia in consideration of reagent and equipment cost.

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Preparation of Castable Refractories by Recycling of Aluminum Dross (알루미늄드로스를 재활용한 캐스타블내화물 제조)

  • Park Hyungkyu;Lee Hooin;Lee Jinyoung
    • Resources Recycling
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    • v.12 no.3
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    • pp.46-53
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    • 2003
  • Recycling of aluminum dross is an important issue in the secondary aluminum industries. In this study, aluminum dross generated in the domestic secondary aluminum industry was processed to use it as raw material for producing alumina refractories. Sample dross was classified according to its size. The dross smaller than 1 mm was leached with sodium hydroxide solution to extract the remained aluminum from the dross into the solution. and then aluminum hydroxide precipitate was recovered from the leach liquor. The waste residue in the leaching was washed, dried and roasted. Most remained metallic components in the residue was changed into oxide through the processes. The roasted dross was made into alumina castable refractories by mixing with aggregates and a binder. Bending strength of the tested castable specimen was over $25\;kg/\textrm{m}^2$ and compressive strength over $80\;kg/\textrm{cm}^2$, which satisfied the Korean Standard value respectively. From the results, it was suggested that this process could be applicable to recycling of aluminum dross.

ESBL: An Energy-Efficient Scheme by Balancing Load in Group Based WSNs

  • Mehmood, Amjad;Nouman, Muhammad;Umar, Muhammad Muneer;Song, Houbing
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.10 no.10
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    • pp.4883-4901
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    • 2016
  • Energy efficiency in Wireless Sensor Networks (WSNs) is very appealing research area due to serious constrains on resources like storage, processing, and communication power of the sensor nodes. Due to limited capabilities of sensing nodes, such networks are composed of a large number of nodes. The higher number of nodes increases the overall performance in data collection from environment and transmission of packets among nodes. In such networks the nodes sense data and ultimately forward the information to a Base Station (BS). The main issues in WSNs revolve around energy consumption and delay in relaying of data. A lot of research work has been published in this area of achieving energy efficiency in the network. Various techniques have been proposed to divide such networks; like grid division of network, group based division, clustering, making logical layers of network, variable size clusters or groups and so on. In this paper a new technique of group based WSNs is proposed by using some features from recent published protocols i.e. "Energy-Efficient Multi-level and Distance Aware Clustering (EEMDC)" and "Energy-Efficient Multi-level and Distance Aware Clustering (EEUC)". The proposed work is not only energy-efficient but also minimizes the delay in relaying of data from the sensor nodes to BS. Simulation results show, that it outperforms LEACH protocol by 38%, EEMDC by 10% and EEUC by 13%.

The Method of Certificating Waterproof Effect for Consecutive Column-Wall Mass in Underground (주열식 지중연속벽체의 차수효과 확인 방안)

  • Koh, Yong-IL
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.9
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    • pp.5-9
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    • 2017
  • On the flow of groundwater, the effect of consecutive column-wall in underground as a hydraulic barrier could be identified by conventional geotechnical methods ((1)visualiy identification of wall mass after underground excavating, (2)uniaxial compressive strength test for core of wall mass in underground, (3)in-situ permeability test in the hole after coring wall mass). However, for the cut off the leakage or infiltration of very high concentrated leachate from the waste landfill or the contaminated groundwater, the waterproof effect of consecutive column-wall in underground should be verified more objectively, by in-situ measuring of pH, temperature and salinity. and by evaluating of their consistency and similarity throughout analyzing the characteristics of basic components and their profiles through the series of chemical experiments. Furthermore, its waterproof effect could be verified additionally throughout deciding the similarity more simply by comparing the general distribution patterns including the difference of high and low peaks from the chromatograms using GC-MS for surrounding groundwater.

Experimental Study of Leaching Phenomena of Cs-137 From a Cement Matrix Generated at PWR Plant (가압 경수로에서 생성된 시멘트 고화체로부터 Cs-137의 용출 현상의 실험적 연구)

  • Doh, Jeong-Yeul;Lee, Kun-Jai
    • Journal of Radiation Protection and Research
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    • v.11 no.2
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    • pp.91-103
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    • 1986
  • Experimental study for the leaching behavior of Cs-137 was carried out using the simulated evaporator bottom product of PWR plant. The method of leach test proposed by the IAEA was partially modified using ANS method. The effect of various factors, i.e., sampling method, curing temperature, curing time, leachant temperature, vermiculite addition and volume-to-surface ratio, was considered in this experiment. Diffusion model in semi-infinite slab was in a good agreement with the data obtained from 4-weeks cured specimens. The effective diffusion coefficient of the specimens which were cured at the temperature of $24^{\circ}C$ for 4 weeks was found to be $1.20{\sim}1.47{\times}10^{-11}cm^2/sec$. With the experimentally obtained diffusion coefficient ($1.47{\times}10^{-11}cm^2/sec$), long-term prediction for the leaching of Cs-137 was carried out using finite-slab approximation. The estimated fraction of Cs-137 which remains in the environment is found to be less than 0.25 percent of initial amount after 100 years. About 25 years after the beginning of leaching, its fractional amount in the environment reachs the maximum value, 0.66 percent of initial amount.

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A Study on the Efficient TICC(Time Interval Clustering Control) Algorithm using Attribute of Node (노드의 속성을 고려한 효율적인 TICC(Time Interval Clustering Control) 알고리즘에 관한 연구)

  • Kim, Young-Sam;Doo, Kyoung-Min;Lee, Kang-Whan
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.12 no.9
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    • pp.1696-1702
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    • 2008
  • A MANET(Mobile Ad-hoc Network) is a multi-hop routing protocol formed by a collection without the intervention of infrastructure. So the MANET also depended on the property as like variable energy, high degree of mobility, location environments of nodes etc. Generally the various clustering technique and routing algorithm would have proposed for improving the energy efficiency. One of the popular approach methods is a cluster-based routing algorithm using in MANET. In this paper, we propose an algorithm techniques which is TICC (Time Interval Clustering Control) based on energy value in property of each node for solving cluster problem. It provides improving cluster energy efficiency how can being node manage to order each node's energy level. TICC could be able to manage the clustering, re-configuration, maintenance and detection of Node in MANET. Furthermore, the results of modeling shown that Node's energy efficiency and lifetime are improved in MANET.

Modeling and Simulation of LEACH Protocol to Analyze DEVS Kernel-models in Sensor Networks

  • Nam, Su Man;Kim, Hwa Soo
    • Journal of the Korea Society of Computer and Information
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    • v.25 no.4
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    • pp.97-103
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    • 2020
  • Wireless sensor networks collect and analyze sensing data in a variety of environments without human intervention. The sensor network changes its lifetime depending on routing protocols initially installed. In addition, it is difficult to modify the routing path during operating the network because sensors must consume a lot of energy resource. It is important to measure the network performance through simulation before building the sensor network into the real field. This paper proposes a WSN model for a low-energy adaptive clustering hierarchy protocol using DEVS kernel models. The proposed model is implemented with the sub models (i.e. broadcast model and controlled model) of the kernel model. Experimental results indicate that the broadcast model based WSN model showed lower CPU resource usage and higher message delivery than the broadcast model.

The Efficiency of Bioleaching Rates for Valuable Metal Ions from the Mine Waste Ore using the Adapted Indigenous Acidophilic Bacteria with Cu Ion (Cu 이온에 적응된 토착호산성박테리아를 이용한 폐광석으로부터 미생물용출 효율 향상)

  • Kim, Bong-Ju;Wi, Dae-Woong;Choi, Nag-Choul;Park, Cheon-Young
    • Journal of Soil and Groundwater Environment
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    • v.17 no.4
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    • pp.9-18
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    • 2012
  • This study was carried out to leach valuable metal ions from the mine waste ore using the adapted indigenous bacteria. In order to tolerance the heavy metals, the indigenous bacteria were repeatedly subcultured in the adaptation-medium containing $CuSO_4{\cdot}5H_2O$ for 3 weeks and 6 weeks, respectively. As the adaptation experiment processed, the pH was rapidly decrease in the adaptation-medium of 6 weeks more than the 3 weeks. The result of bioleaching with the adapted bacteria for 42 days, the pH value of leaching-medium in the 3 weeks tend to increased, whereas the pH of the 6 weeks decreased. In decreasing the pH value in the adaptation-medium and in the leaching-medium, it was identified that the indigenous bacteria were adapted $Cu^{2+}$ the ion and the mine waste ores. The contents of Cu, Fe and Zn in the leaching solution were usually higher leached in 6 weeks than 3 weeks due to the adaptation. Considering the bioleaching rates of Cu, Fe and Zn from these leaching solutions, the highest increasing the efficiency metal ion were found to be Fe. Accordingly, it is expected that the more valuable element ions can be leached out from the any mine waste, if the adapted bacteria with heavy metals will apply in future bioleaching experiments.