• 제목/요약/키워드: Layered material

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ZnS/$Na_3AlF_6$/ZnS/Cr 다층 박막의 광학적 두께 변화에 따른 광특성 (The optical properties of ZnS/$Na_3AlF_6$/ZnS/Cr multi-layered thin film with different optical thickness)

  • 김준식;장강재;장건익
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.535-536
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    • 2008
  • Multi-layered thin films of ZnS/$Na_3AlF_6$/ZnS/Cr were deposited on glass substrate by evaporation process. ZnS and $Na_3AlF_6$ were selected as high and low refractive index material, and additionally Cr was chosen as mid reflective layer respectively. The multi-layered thin films were prepared in terms of different optical thickness and different staking sequence and layers. The optical properties were systematically characterized with different optical thickness of $Na_3AlF_6$ especially $0.25\lambda$ and $0.5\lambda$. In order to expect the experimental result, the simulation program, the Essential Macleod Program(EMP) was adopted. Based on the results taken by spectrophotometer at viewing angle $45^{\circ}$, the ZnS/$Na_3AlF_6$/ZnS/Cr multi-layered thin film shows purple colour range in $0.25\lambda$, bluish green in $0.5\lambda$, red purple in $0.75\lambda$, and purple in $1.0\lambda$ respectively.

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적층 평판형 SOFC에서 LSM 전극의 기공 제어 (Porosity Control in LSM Electrode Formation in Layered Plannar SOFC Module)

  • 이원준;여동훈;신효순;정대용
    • 한국전기전자재료학회논문지
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    • 제27권12호
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    • pp.866-870
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    • 2014
  • In solid oxide fuel cell system, yttria-stabilized zirconia is generally adopted as the electrolyte, which has high strength and superior oxygen ion conductivity, and the air electrode and the fuel electrode are attached to this. Recently, new structure of 'layered planar SOFC module' was suggested to solve the reliability problem due to the high temperature stability of a sealing agent and a binding material. In this study to materialize the air electrode in a layered planar SOFC module, the LSM ink was coated to form homogeneous electrode in the channel after the ink preparation. As the porosity control agent, PMMA or active carbon powder was adopted with use of a commercial dispersant in ethanol. The optimal amounts of both the porosity control agents and the dispersant were determined. Four (4) vol% of the dispersant for the LSM-PMMA case and 15 vol% for LSM-carbon powder showed the lowest viscosities respectively to indicate the best dispersed states of the slurries. With PMMA and carbon powder, sintered LSM ink shows the relatively homogeneous distributions of pores and with increases of the agents, the porosities increased in both cases. From this, it can be thought that the amount of the PMMA or carbon powder could be used to control the porosity of the LSM ink.

Nonlocal bending, vibration and buckling of one-dimensional hexagonal quasicrystal layered nanoplates with imperfect interfaces

  • Haotian Wang;Junhong Guo
    • Structural Engineering and Mechanics
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    • 제89권6호
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    • pp.557-570
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    • 2024
  • Due to interfacial ageing, chemical action and interfacial damage, the interface debonding may appear in the interfaces of composite laminates. Particularly, the laminates display a side-dependent effect at small scale. In this work, a three-dimensional (3D) and anisotropic thick nanoplate model is proposed to investigate the effects of imperfect interface and nonlocal parameter on the bending deformation, vibrational response and buckling stability of one-dimensional (1D) hexagonal quasicrystal (QC) layered nanoplates. By combining the linear spring model with the transferring matrix method, exact solutions of phonon and phason displacements, phonon and phason stresses of bending deformation, the natural frequencies of vibration and the critical buckling loads of 1D hexagonal QC layered nanoplates are derived with imperfect interfaces and nonlocal effects. Numerical examples are illustrated to demonstrate the effects of the imperfect interface parameter, aspect ratio, thickness, nonlocal parameter, and stacking sequence on the bending deformation, the vibrational response and the critical buckling load of 1D hexagonal QC layered nanoplate. The results indicate that both the interface debonding and nonlocal effect can reduce the stiffness and stability of layered nanoplates. Increasing thickness of QC coatings can enhance the stability of sandwich nanoplates with the perfect interfaces, while it can reduce first and then enhance the stability of sandwich nanoplates with the imperfect interfaces. The biaxial compression easily results in an instability of the QC layered nanoplates compared to uniaxial compression. QC material is suitable for surface layers in layered structures. The mechanical behavior of QC layered nanoplates can be optimized by imposing imperfect interfaces and controlling the stacking sequence artificially. The present solutions are helpful for the various numerical methods, thin nanoplate theories and the optimal design of QC nano-composites in engineering practice with interfacial debonding.

치아응용을 위한 층상 세라믹스에서의 접촉손상 및 잔류응력의 영향 (Effects of Contact Damage and Residual Stress in Dental Layered Ceramics)

  • 정종원;최성철
    • 한국세라믹학회지
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    • 제37권3호
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    • pp.288-293
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    • 2000
  • Effects of contact damage and residual stress for two kinds of dental restorative layered ceramics, porcelain/alumina and porcelain/zirconia bilayers, were observed with Hertzian and Vickers indentation methods. Indentation stress-strain behavior of each material, strength degradation of the coating material, and crack propagation behavior in the coating layer after Vickers indentation were examined by an optical microscope. As a result, porcelain as coating materials showed the classical brittleness. It was inferred that damage and strength in two bilayer system were dependent on thermal expansion mismatch between the coating material and the substrate, which affected the strength degradation. Residual stress resulting from thermal expansion mismtch was formed in the coating layer, and specially in the case of porcelain/zirconia, residual stress was eliminated as coating thickness decreased.

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완충재 구성방법에 따른 동탄성계수 및 중량바닥충격음 저감특성 평가 (Evaluation of the Dynamic Stiffness and Heavy-weight Floor Impact Sound Reduction by Composition of Resilient Materials)

  • 김경우;정갑철;손장열
    • 한국소음진동공학회논문집
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    • 제18권2호
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    • pp.247-254
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    • 2008
  • Resilient materials are generally used for the floating floors to reduce the floor impact sound. Dynamic stiffness of resilient material, which has the most to do with the floor impact sound reduction. The resilient materials available in Korea include EPS(styrofoam), recycled urethane types, EVA(ethylene vinylacetate) foam rubber, foam PE(polyethylene). glass fiber & rock wool, recycled tire, foam polypropylene. compressed polyester, and other synthetic materials. In this study, we tested dynamic stiffness of resilient material and floor impact sound reduction characteristic to a lot of kinds of resilient materials. It was found that dynamic stiffness of multi-layered damping material could be estimated if know value of each layer that compose whole structure. And the test showed that the amount of the heavy-weight impact sound reduction appeared by being influenced from this dynamic stiffness of resilient material. The dynamic stiffness looked like between other resilient materials, a similar to the amount of the heavy-weight impact sound reduction was shown.

골판지 적층재와 EPS 사이의 압축거동에 대한 실험적 연구 (Experimental Study on Compression Behavior between Multi-layered Corrugated Structure and EPS Packaging Materials)

  • 박종민;최원식;김종순
    • 한국산업융합학회 논문집
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    • 제23권1호
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    • pp.83-91
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    • 2020
  • The evaluation of the compression behavior of the cushioning material is of importance to achieve appropriate packaging design. In order to change packaging design from polymeric-based to more eco-friendly cellulose-based nire effectively, comparative study on the compression behavior between these two packaging materials is crucial. In this study, the stress-strain behavior, hysteresis loss, and response characteristics for cyclic loading were analyzed through compression tests on multi-layered corrugated structure (MLCS) and expanded polystyrene (EPS) packaging materials. MLCS produced in Korea is produced by winding a certain number of single-faced corrugated paperboard, and the compression behavior of this material was turned out to be 6 stages: elastic stage, first buckling stage, sub-buckling stage, densification stage, last buckling stage and high densification stage. On the other hand, EPS's compression behavior was in 3 stages: linear elastic stage, collapse plateau, and densification stage. The strain energy per unit volume (strain energy density) of MLCS did not differ depending on the material thickness, but it showed a clear difference depending on the raw material and flute type. Hysteresis loss of MLCS ranged from 0.90 to 0.93, and there were no significant differences in the raw material and flute type. These values were about 5 to 20% greater than the hysteresis of the EPS (about 0.78 to 0.87).

휴대용 의료 초음파 프로브 적용을 위한 압전체 제조 및 특성 (Modified Piezoelectric Ceramics for Portable Ultrasonic Medical Probe Application)

  • 강동헌;채미나;홍세원
    • 한국전기전자재료학회논문지
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    • 제29권8호
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    • pp.483-488
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    • 2016
  • Ultrasound imaging by using piezoelectric materials, such as lead zirconium titanate (PZT) has been one of the most preferred modes of imaging in the medical field due to its simple, low cost and non-ionizing radiation in comparison to other imaging techniques. Recently, the market demand for portable ultrasound is becoming larger with applications in developing countries, disaster area, military, and emergency purposes. However, most of ultrasound probes used is bulky and high power consumable, so unsuitable for such applications. In this study, the 3 layered ceramic specimen consisted of 128 pitches of $420{\mu}m$ in width and $450{\mu}m$ in thickness were prepared by using the Ti-rich PZT compositions co-fired at $1,050^{\circ}C$. Their electrical and ultrasound pulse-echo properties were investigated and compared to the single layer specimen. The 3 layered ultrasound probe showed 1.584 V of Vp-p, which is 3.2 times higher than single layered one, implying that it would allow effectively such a portable ultrasound probe system. The result were discussed in terms of higher capacitance, lower impedance and higher dielectric coefficient of the 3 layered ultrasound probe.

솔 - 젤법을 이용한 Bismuth Layered Structure를 가진 강유진성 박막의 제조 및 특성평가에 관한 연구 (II. MOD법으로 제조한 강유전성 $Sr_{0.7}/B_{2.3}(Ta_{1-x}Nb_x)_2O_9$ 박막의 유전특성) (The Preparation and Characterization of Bismuth Layered Ferroelectric Thin Films by Sol-Gel Process (II. Dielectric Properties of Ferroelectric $Sr_{0.7}/B_{2.3}(Ta_{1-x}Nb_x)_2O_9$ Thin Films Prepared by MOD Process))

  • 최무용;송석표;정병직;김병호
    • 한국전기전자재료학회논문지
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    • 제12권1호
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    • pp.62-68
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    • 1999
  • Ferroelectric $Sr_{0.7}/B_{2.3}(Ta_{1-x}Nb_x)_2O_9$(x=0, 0.1, 0.2, 0.3) thin films were deposited on $Pt/SiO_2/Si$ substrate by MOD(Metalorganic Decomposition) process. Metal carboxylate and metal alkoxide were used as precursors, and 2-methoxyethanol, xylene as solvents. After spin coating, thin films were pre-annealed at $400^{\circ}C$, followed by RTA(Rapid Thermal Annealing) and final annealing at $800^{\circ}C$ in oxygen atmosphere. These procedures were repeated three times to obtain thin films with the thickness of $2000{\AA}$. To enhance the nucleation and growth of layered-perovskite phase, thin films were rapid-thermally annealed above $720^{\circ}C$ in oxygen atmosphere. As RTA temperature increased, fluorite phase was transformed to layered-perovskite phase. And the change of Nb contents affected dielectric / electrical properties and microstructure. The ferroelectric characteristics of $Sr_{0.7}/B_{2.3}(Ta_{1-x}Nb_x)_2O_9$ thin film were Pr=8.67 $\mu{C}/cm^2$, Ec=62.4kV/cm and $I_{L}=1.4\times10^{-7}A/cm^2$ at the applied voltage of 5V, respectively.

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Performances of Li-Ion Batteries Using LiNi1-x-yCoxMnyO2 as Cathode Active Materials in Frequency Regulation Application for Power Systems

  • Choi, Jin Hyeok;Kwon, Soon-Jong;Lim, Jungho;Lim, Ji-Hun;Lee, Sung-Eun;Park, Kwangyong
    • KEPCO Journal on Electric Power and Energy
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    • 제6권4호
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    • pp.461-466
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    • 2020
  • There are many application fields of electrical energy storage such as load shifting, integration with renewables, frequency or voltage supports, and so on. Especially, the frequency regulation is needed to stabilize the electric power system, and there have to be more than 1 GW as power reserve in Korea. Ni-rich layered oxide cathode materials have been investigated as a cathode material for Li-ion batteries because of their higher discharge capacity and lower cost than lithium cobalt oxide. Nonetheless, most of them have been investigated using small coin cells, and therefore, there is a limit to understand the deterioration mode of Ni-rich layered oxides in commercial high energy Li-ion batteries. In this paper, the pouch-type 20 Ah-scale Li-ion full cells are fabricated using Ni-rich layered oxides as a cathode and graphite as an anode. Above all, two test conditions for the application of frequency regulation were established in order to examine the performances of cells. Then, the electrochemical performances of two types of Ni-rich layered oxides are compared, and the long-term performance and degradation mode of the cell using cathode material with high nickel contents among them were investigated in the frequency regulation conditions.

층상 반무한 지반의 물성치 추정을 위한 마르코프 연쇄 몬테카를로 모사 기법 (Markov Chain Monte Carlo Simulation to Estimate Material Properties of a Layered Half-space)

  • 이진호;;이세혁
    • 한국전산구조공학회논문집
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    • 제36권3호
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    • pp.203-211
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    • 2023
  • 층상 반무한체에서의 확률론적 완전파형역산을 위한 Markov chain Monte Carlo (MCMC) 모사 기법을 정식화한다. Thin-layer method를 사용하여 조화 수직 하중이 작용하는 층상 반무한체의 지표면에서 추정된 동적 응답과 관측 데이터와의 차이 및 모델 변수의 사전 정보와의 차이를 최소화하도록 목적함수와 모델 변수의 사후 확률밀도함수를 정의한다. 목적함수의 기울기에 기반하여 MCMC 표본을 제안하기 위한 분포함수와 이를 수락 또는 거절할지 결정하는 수락함수를 결정한다. 기본 진동모드 뿐만이 아니라 고차 진동모드가 우세한 경우를 포함하여 다양한 층상 반무한체의 전단파 속도 추정에 제안된 MCMC 모사 기법을 적용하고 그 정확성을 검증한다. 제안된 확률론적 완전파형역산을 위한 MCMC 모사 기법은 층상 반무한체의 전단파 속도와 같은 재료 특성의 확률적 특성을 추정하는 데 적합함을 확인할 수 있다.