• Title/Summary/Keyword: Layer Removal

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Correlation between Oxidation State and Electron Blocking Performance of Tungsten Oxide Interlayer in Organic Solar Cell

  • Lee, Ji-Seon;Jang, In-Hyuk;Park, Nam-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.217-217
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    • 2012
  • Solution-processed tungsten oxide thin film with thickness of about 30 nm is prepared from ammonium tungstate. This layer is introduced into the interface between the poly(3-hexylthiophene):[6,6]-phenyl-C61-butyric acid methyl ester (P3HT:PCBM) layer and the ITO electrode to be used as an electron blocking layer. The annealed tungsten oxide thin films at $150^{\circ}C$ and $300^{\circ}C$ show amorphous phase, while the $400^{\circ}C$ -annealed tungsten oxide film shows crystalline phase. At $150^{\circ}C$ annealing temperature, the conversion efficiency is significantly improved from 0.71% to 1.42% as the condition is changed from vacuum to air atmosphere, which is related to oxidation state of tungsten in amorphous phase. For the air annealing condition, the conversion efficiency is further increased from 1.42% to 2.01% as the temperature is increased from $150^{\circ}C$ to $300^{\circ}C$, which is mainly due to the removal of the chemisorbed water. However, a slight deterioration in photovoltaic performance is observed when the temperature is increased to $400^{\circ}C$, which is ascribed to poor electron blocking ability due to the formation of crystalline phase. It is concluded that $W^{6+}$ oxidation state and amorphous nature in tungsten oxide interlayer is essential for blocking electron effectively from the active layer to the ITO electrode.

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Effect of Tetracycline-HCL in Root Conditioning;A SEM Study (염산테트라싸이클린을 이용한 치근면처리의 효과)

  • Kim, Eun-Jung;Heer, Yeek;Lee, Man-Sup;Kwon, Young-Hyuk
    • Journal of Periodontal and Implant Science
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    • v.30 no.1
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    • pp.121-134
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    • 2000
  • Root conditioning has introduced to dissolve the smear layer and to produce surface demineralization, resulting to exposure of dentin collagen fibril and opening of dentinal tubules. The purpose of the present study was to examine the effect of different concentration and application time of tetracycline-HCL on root conditioning. Total 40 root specimen were prepared from 20 periodontitis-prone human single rooted tooth. The specimen were treated with tetracycline-HCL solution(20mg/ml, 50mg/ml, 100mg/ml)for 20 sec, 3 min, 5 min., and saline for 30 sec. The application method was rubbing method with cotton pellet. Under the scanning electron microscopy(20KV), the extent of smear removal and opening of the dentinal tubules were examined at x 3000. The following results were obtained. 1. Treatment of root specimen with saline did not remove the smear layer and open the dentinal tubules. 2. Treatment of root specimen with different concentration of tetracycline-HCL for 20 sec also did not remove the smear layer completely. 3. Treatment of root specimen with different concentration of tetracycline-HCL for 3 min opened the dentinal tubules and removed smear layer. 4. Treatment of root specimen with 50mg/ml of tetracycline-HCL for 3 min showed collagen fibril within the opened dentinal tubules. In conclusion, the effect of root conditioning with tetracycline-HCL is more dependent on the application time than the application concentration. Root conditioning with 50mg/ml tetracycline-HCL for 3 min is enough for obtaining the periodontal regeneration.

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A method for removal of reflection artifact in computational fluid dynamic simulation of supersonic jet noise (초음속 제트소음의 전산유체 모사 시 반사파 아티팩트 제거 기법)

  • Park, Taeyoung;Joo, Hyun-Shik;Jang, Inman;Kang, Seung-Hoon;Ohm, Won-Suk;Shin, Sang-Joon;Park, Jeongwon
    • The Journal of the Acoustical Society of Korea
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    • v.39 no.4
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    • pp.364-370
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    • 2020
  • Rocket noise generated from the exhaust plume produces the enormous acoustic loading, which adversely affects the integrity of the electronic components and payload (satellite) at liftoff. The prediction of rocket noise consists of two steps: the supersonic jet exhaust is simulated by a method of the Computational Fluid Dynamics (CFD), and an acoustic transport method, such as the Helmholtz-Kirchhoff integral, is applied to predict the noise field. One of the difficulties in the CFD step is to remove the boundary reflection artifacts from the finite computation boundary. In general, artificial damping, known as a sponge layer, is added nearby the boundary to attenuate these reflected waves but this layer demands a large computational area and an optimization procedure of related parameters. In this paper, a cost-efficient way to separate the reflected waves based on the two microphone method is firstly introduced and applied to the computation result of a laboratory-scale supersonic jet noise without sponge layers.

A Study on the Silica Removal in Primary System using the Membrane Process (막 분리 공정을 이용한 1차 계통 실리카 제거에 관한 연구)

  • Kim Bong-Jin;Lee Sang-Jin;Yang Ho-Yeon;Kim Kyung-Duk;Jung Hee-Chul;Jo Hang-Rae
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.137-144
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    • 2005
  • Silica in primary system combines with an alkali grammatical particle metal and forms the zeolite layer which is hindering the heat transfer on the surface of the cladding. Zeolite layer becomes the cause of the damage in this way. The problems of the NPP's primary system have been issued steadily by EPRI. Through a series of experiments of the laboratory scale, we confirmed the applicability of NF membrane for silica removal, as silica rejection rate of NF membrane is about $60\;{\sim}\;70\%$ and boron rejection rate is about $10\;{\sim}\;20\%$. We accomplished a site experiment about four NF membranes manufactured by FilmTec and Osmonics Inc. In experiment using 400L of SFP water, when operation pressure is $10kg_{f}/cm^2$, we confirmed that the silica rejection rate of NF90-2540 manufactured by FilmTec Inc. is about $98\%$, boron rejection rate is about $43\%$. The silica rejection rate of NF270-2540 is about $38\%$, boron rejection rate is about $3.5\%$. Afterward, through additional experiments, such as long term characteristic experiments, we are going to design a optimum NF membrane system for silica removal.

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Manufacture and Characteristics of Concrete Sidewalk Blocks Using Photocatalyst Agent (광촉매제를 사용한 콘크리트 보도블록의 제조 및 특성)

  • Jung, Yong-Wook;Chang, Chun-Ho;Kim, Jong-Kyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.423-430
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    • 2019
  • In this study, the flexural strength, absorption rate, methylene blue photo catalyst decomposition performance and anti-fouling performance were evaluated according to the photo catalyst mixing rate and block surface wash status by applying photo catalyst to the surface layer of concrete sidewalk block. The results showed that the flexural strength of the block that mixed photo catalyst only in the surface layer of the concrete block was 5.32MPa of the general block (SNW) of 5% photo catalyst, compared to 5.46MPa of the non-mixed concrete block of the reference concrete block. Surface washing block (SW) 5.26MPa, 10% photo catalyst general block (SNW) 5.26MPa, and 5.15MPa surface washing block (SW). It has been shown that the presence of surface washing and the mixing rate of photo catalyst in the concrete block have no effect on the flexural strength. Moreover, the photoreaction performance of concrete sidewalk blocks showed that the methylene blue removal rate of specimens with 5% TiO2 was 34.2%, the methylene blue removal rate of specimens with 10% TiO2 was 37.1%, and the removal rate of the methylene blue of specimens with 5% TiO2 was about 37.9% and 10% mixed specimens with TiO2 was about 37.6%.

A Study on the effect of TEOS film by Dispel8ion Time and Content of $CeO_2$ Abrasive (DSS에서 $CeO_2$ 연마제의 첨가량과 분산시간이 TEOS 막에 미치는 특성연구)

  • Seo, Yong-Jin;Han, Sang-Jun;Park, Sung-Woo;Lee, Young-Kyun;Lee, Sung-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.487-487
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    • 2009
  • One of the critical consumables in chemical mechanical polishing (CMP) is a specialized solution or slurry, which typically contains both abrasives and chemicals acting together to planarize films. In single abrasive slurry (SAS), the solid phase consists of only one type of abrasive particle. On the other hand, mixed abrasive slurry (MAS) consists of a mixture of at least two types of abrasive particles. In this paper, we have studied the CMP characteristics of mixed abrasive slurry (MAS) retreated by adding of $CeO_2$ abrasives within 1:10 diluted silica slurry (DSS). The slurry designed for optimal performance should produce reasonable removal rates, acceptable polishing selectivity with respect to the underlying layer, low surface defects after polishing, and good slurry stability. The modified abrasives in MAS are evaluated with respect to their particle size distribution, surface morphology, and CMP performances such as removal rate and non-uniformity. As an experimental result, we obtained the comparable slurry characteristics compared with original silica slurry in the viewpoint of high removal rate and low non-uniformity.

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A Study on Purification of Water Works by Multi-filter Bed Method with Aeration(Appliction of Biological Oxidation by Aerobic Microorganism) (상수 정화법에 관한 연구 (폭기식 다단여과에 의한 호기성균의 생물화학적 산화작용을 응용))

  • Chung, Yo-Han;Moon, Jae-Kyu;Jhoo, Heung-Kyu;Seo, Hwa-Jung
    • Journal of Preventive Medicine and Public Health
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    • v.5 no.1
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    • pp.43-48
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    • 1972
  • 5 bed sand filter, applying biological oxidation, was designed and studied on the treatment of water works. Never using any coagulant agent (drugs), which may cause water pollution in pre-treatment of head water, the auther attempt a high rate filtration by the microorganism (nitrofication bacteria) end plant which populate in multi layer sand beds. The result are as follows : In order to evaluate the oxygen effect on filtration, oxygen was injected in aeration tank attached to each filter tank while filtration, and $NH_3$ was tested as a representaiive ingredient. It was found out that the aeration method was more effective, with over 33% of $NH_3$ removal capacity, than the anerobic and this 5 bed filter showed double removal capacity of $NH_3$ by comparing with conventional sand bed (2 stage bed). According to the examination of two kind of head water, pre-treated with coagulant agent and activated carton, the filtration capacity was affected by the polluted condition of head water, resulting that lower value of pollution and slower velocity of filtration showed more efficiency of $NH_3$ removal. In this experiment $NH_3$ content tested in treated water had a fairly good correlation with others.

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Sewage Treatment Using Natural Systems and Effluent Reuse for Crop Irrigation in Small Communities

  • Ham, Jong-Hwa;Yoon, Chun-G.;Jeon, Ji-Hong;Hwang, Ha-Sun
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.45 no.7
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    • pp.70-82
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    • 2003
  • A pilot study was performed from July 1998 to December 2002, including winter performance, to examine seasonal performance of a constructed wetland and subsequent pond system for treatment of sewage in small communities of Korea. Pond was operated as a intermittent-discharge pond during winter period, and continuous flow system during growing season; its effects was evaluated from December 2001 to April 2003. The subsurface flow (SSF) wetland was satisfactory for treating sewage with good removal efficiency even during the winter period. The wetland effluent concentrations of $BOD_5$ and TSS were often higher in winter than in the growing season, but this was explained by the higher loading rates, rather than lower removal efficiency. The relatively poor-quality wetland effluent was further polished during winter in the pond. The upper layer of the pond water column became remarkably clear immediately after ice melt. In the growing season, ponds could be operated as a continuous flow system to remove nutrients and pathogens, and the effluent of pond could be reused as a supplemental irrigation water without risk of infection by sewage-borne pathogens as well as causing adverse effect on growth and yield. Overall, the wetland system was found to be adequate for treating sewage with stable removal efficiency, and the intermittent-discharge pond was found to be effective for further polishing if necessary. Therefore, the combination of a wetland and subsequent pond system and reuse of effluent as crop irrigation water is recommended as a practical alternative to treat sewage in Korean small communities, and partial discharge of pond water in March is suggested.

Re-Repair Method for Deterioration of Partial Depth Repair Section in Portland Cement Concrete Pavement (콘크리트 포장 부분단면보수 재파손 구간의 적정 보수 방안)

  • Lee, Yong Hyeon;Kim, Hyun Seok;Jung, Won Kyong;Oh, Han Jin;Kim, Hyung Bae
    • International Journal of Highway Engineering
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    • v.19 no.5
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    • pp.33-42
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    • 2017
  • PURPOSES : The purpose of this study is to suggest the construction and quality control method for the re-repair of a deteriorated partial depth repair for sections of Portland cement concrete pavement. METHODS : An experimental construction was conducted to extend the repair width for removing an existing repair section. A removal method was used to ensure early performance for a deteriorated partial depth repair section. Bond strength and split tensile strength were measured at the near vertical interface layer between the existing pavement and repair material. The area was analyzed for various conditions such as the extended repair area and the removing method of the existing repair section. RESULTS : As a result of analysis of bond strength and split tensile strength, the bonding performance of a milling removed section was improved over a cutting and hand breaker removed section. The bond strength was analyzed to increase slightly as the extended repair width for removing the existing repair section increased. The split tensile strength did not show a clear relationship to an increased extended repair width of an existing removed repair section. CONCLUSIONS : The milling removal method should be applied in the removal of existing deteriorated partial depth repair sections. The extended repair width for a re-repair section should be wider than the existing partial depth repair with at least a 75-mm length and width for the bond strength and the split tensile strength.

A Pd Doped PVDF Hollow Fibre for the Dissolved Oxygen Removal Process

  • Batbieri G.;Brunetti A.;Scura F.;Lentini F.;Agostino R G.;Kim, M.J.;Formoso V.;Drioli E.;Lee, K.H.
    • Korean Membrane Journal
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    • v.8 no.1
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    • pp.1-12
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    • 2006
  • In semiconductor industries, dissolved oxygen is one of the most undesirable contaminants of ultrapure water. A method for dissolved oxygen removal (DOR) consists in the use of polymeric hollow fibres, loaded with a catalyst and fed with a reducing agent such as hydrogen. In this work, PVDF hollow fibres loaded with Pd were characterized by means of perporometry, scanning electron microscopy (SEM), energy dispersive X-ray (EDX). The hollow fibre analyzed shows a five-layer structure with remarkable morphological differences. An estimation of pore diameters and their distribution was performed giving a mean pore diameter of 100 nm. The permeance and selectivity of the fibres were measured using $H_2,\;N_2,\;O_2$ as single gases, at different operating conditions. An $H_2$ permeance of $37 mmol/m^2s$ was measured and $H_2/O_2$ and $H_2/N_2$ selectivities of ca. 3 were obtained. $H_2$ permeance was 1/3 when a water stream flows in the shell side. Catalytic fibrebehaviour was simulated using a mathematical model for a loop membrane reactor, considering only $O_2$ and $H_2$ diffusive transport inside the membrane and their catalytic reaction. Dimensionless parameters such as the Thiele modulus are employed to describe the system behaviour. The model agrees well with the experimental reaction data.