• 제목/요약/키워드: Lattice materials

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The Evolution of Preferred Orientation and Morphology of NiO Thin Films under Variation of Plasma Source and RF Power (Plasma source와 RF power에 따른 NiO박막의 우선배향성 및 표면형상)

  • Hyunwook Ryu;Park, Jinseong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.121-121
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    • 2003
  • NiO thin films are very attractive for use as an antiferromagnetic layer, p-type transparent conducting films, in electrochromic devices and functional sensor layer for chemical sensors, due to their excellent chemical stability, as well as optical, electrical and magnetic properties. In addition, (100)- and (111)-oriented NiO films can be used as buffer layers on which to deposit other oriented oxide films, such as c-axis-oriented perovskite-type ferromagnetic films and superconducting films, because of the similarity in symmetry of oxygen ion lattice and lattice constants between the NiO films and the oriented oxide films. Thus, controlling the crystallographic orientation and surface roughness of the NiO films for a buffer layer are very important.

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Crystal Growth of $Ca_3(Li,Nb,Ga)_5O_{12}$ Garnet Crystals

  • Yu, Young-Moon;Chani, Valery-I.;Shimamura, Kiyoshi;Fukuda, Tsuguo
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06a
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    • pp.351-374
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    • 1996
  • Various types of garnet compounds were synthsized by iso-and aliovalent substitutions and sintering method. Among them, fiber shapes of garnet crystals were grown from the $Ca_3Li_xNb_{(1.5+x)}Ga_{(3.5-2x)}O_{12}$ melt where x = 0 ~ 0.5 by modified micro-pulling down method in air using Pt crucibles. The measured lattice constants as a function of solidification fraction of grown fiber crystals are about $12.54\;{\AA}$ irrespective of x. It was found that the $Ca_3Li_{0.275}Nb_{1.775}Ga_{2.95}O_{12}$ garnet melts congruently at about $1450\;^{\circ}C$ based on the purities of garnet phase and variations of lattice parameter. Transparent and bubble-free crystals of x = 0.25 and 0.275 were grown by Czochralski techniques in air using Pt crucibles. An absorption spectrum is also reported.

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Ab-initio calculation on Co substitution into NiSi (NiSi에의 Co 치환에 대한 ab-initio 계산)

  • Kim, Yeong-Cheol;Seo, Hwa-Il
    • Korean Journal of Materials Research
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    • v.17 no.7
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    • pp.358-360
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    • 2007
  • Cobalt subtitution on NiSi is investigated by using an ab-initio calculation. Firstly, a relaxed NiSi structure is calculated and the calculated lattice parameters are compared with experimentally determined lattice parameters. The calculated values are smaller than the experimental values by about 2%. As the calculation is based on 0 K, and the experimental measurement is performed at room temperature, those values are in good agreement. Next, a Co atom substitutes a Ni and Si site, respectively, to evaluate the preferable site between them. Co prefers Ni site to Si site. The calculated total energy also indicates that the Co substitution to Ni site stabilizes the NiSi structure. Therefore, the thermal stability of NiSi with Co addition can be achieved by the structure stabilization of NiSi by Co substitution into Ni site of NiSi.

Enhanced superconducting properties of MgB2 by doping the carbon quantum dots

  • K.C., Chung;S.H., Jang;Y.S., Oh;S.H., Kang
    • Progress in Superconductivity and Cryogenics
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    • v.24 no.4
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    • pp.55-58
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    • 2022
  • Carbon-based doping to MgB2 superconductor is the simplest approach to enhance the critical current densities under magnetic fields. Carbon quantum dots is synthesized in this work as a carbon provider to MgB2 superconductors. Polyvinyl Pyrrolidone is pyrolyzed and dispersed in dimethylfomamide solvent as a dopant to the mixture of Mg and B powders. Doped MgB2 bulk samples clearly show the decrease of a-axis lattice constant, grain refinements, and broadening of FWHM of diffraction peaks compared to un-doped MgB2 possibly due to the carbon substitution and/or boron vacancy at the boron site in MgB2 lattice. Also, high-field Jc for the doped MgB2 is enhanced significantly with the crossover about 3 T at 5 & 20 K when increasing the doping of carbon quantum dots.

Study on Evaluation Method of Structural Integrity of Cylindrical Composite Lattice Structures (원통형 복합재 격자구조체의 구조안전성 평가 기법 연구)

  • Im, Jae-Moon;Kang, Seung-Gu;Shin, Kwang-Bok;Lee, Sang-Woo
    • Composites Research
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    • v.30 no.6
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    • pp.338-342
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    • 2017
  • In this paper, evaluation method of structural integrity of cylindrical composite lattice structures was conducted. A finite element analysis was used to evaluate the structural integrity of composite lattice structures. In order to verify the optimal finite element in the evaluation of the structural integrity, finite element models for cylindrical composite lattice structure were generated using beam, shell and solid elements. The results of the finite element analyses with the shell and solid element models showed a good agreement. However, considerable differences were found between the beam element model and the shell and solid models. This occurred because the beam element does not take into account the degradation of the mechanical properties of the non-intersection parts of cylindrical composite lattice structures. It was found that the finite element analysis of evaluation of structural integrity for cylindrical composite lattice structures have to use solid element.

A Study on the Stability of the Single-Layer Latticed Dome during Erection Using the Step-Up Method (Step-Up 공법에 의한 단층래티스돔의 시공시 안정성 연구)

  • Koo, Choong-Mo;Jung, Hwan-Mok;Kim, Cheol-Hwan
    • Journal of Korean Association for Spatial Structures
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    • v.12 no.4
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    • pp.109-118
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    • 2012
  • The large-space single-layer lattice dome is relatively simpler in terms of the arrangement of the various framework members and of the design of the junction than the multi-layered lattice dome, can reduce the numbers and quantity of the framework members, and has the merit of exposing the beauty of the framework as it stands. The single-layer lattice dome, however, requires a stability investigation of the whole structure itself, along with an analysis of the stress of the framework members, because an unstable phenomenon called "buckling" occurs when its weight reaches critical levels. Many researchers have systematically conducted researches on the stability evaluation of the single-layer lattice dome. No construction case of a single-layer lattice dome with a 300-m-long span, however, has yet been reported anywhere in the world. The large-space dome structure is difficult to erect due to the gigantic span and higher ceiling compared with other common buildings, and its construction cost is generally huge. The method of erecting a structure causes major differences in the construction cost and period. Therefore, many researchers have been conducting various researches on the method of erecting such structure. The step-up method developed by these authors can reduce the construction cost and period to a great extent compared with the other general methods, but the application of this method inevitably requires the development of system supports in the center section as well as pre-existing supports in the boundary sections. In this research, the safety during the construction of a single-layer lattice dome with 300-m-long span using pre-existing materials was examined in the aspect of structural strength, and the basic data required for manufacturing the supports in the application of the step-up method developed by these authors during the erection of the roof structure were obtained.

The High Density Sintering of Green-emitting β-SiAlON:Eu Ceramic Plate Phosphor (녹색발광 β-SiAlON:Eu 세라믹 플레이트 형광체의 치밀화 소결)

  • Park, Young-Jo;Lee, Sung-Hoon;Jang, Wook-Kyung;Yoon, Chang-Bun;Yoon, Chul-Soo
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.503-508
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    • 2010
  • $Eu^{2+}$-doped $\beta$-SiAlONs ($Si_{6-z}Al_zO_zN_{8-z}:Eu_y$) are recognized as promising phosphor materials to build an white LED for lighting application due to its excellent absorption/emission efficiency in the long wave length region. In this research, the fabrication of $\beta$-SiAlON:Eu plate phosphor by sintering was investigated with fixed Eu content(y) and varied composition of the host lattice(z). The addition of the activator $Eu_2O_3$ lead to enhanced densification by forming the transient liquid phase. The refinement of a composition by the calculated lattice parameter indicated that the measured composition of the fabricated specimens is nearly same to that of designed one. The single phase $\beta$-SiAlON:Eu plate with relative density of 96.4% was achieved by addition of 2 wt% CaO, which implies the possibility of full densification by adjusting the processing variables.