• Title/Summary/Keyword: Laser absorption spectroscopy

Search Result 118, Processing Time 0.031 seconds

Fabrication of Transient Absorption Spectroscopic System and Measurement of Transient Absorption Changes of DDI (순간흡수 분광학 측정장치 구성 및 DDI의 순간흡수율 변화 측정)

  • Seo, Jung-Chul;Lee, Min-Yung;Kim, Dong-Ho;Jeong, Hong-Sik;Park, Seung-Han;Kim, Ung
    • Korean Journal of Optics and Photonics
    • /
    • v.2 no.4
    • /
    • pp.209-213
    • /
    • 1991
  • Recently, the developments in generating and amplifying ultrashort optical pulses $(ps=10^{-12}s or fs=10^{-15}s)$ have imposed on great advances in the time-resolved laser spectroscopy. Especially, the transient absorption spectroscopy has a wide application range and the main idea of this technique is pump & probe method. After the pump pulse makes the material an excited or a transient states, the probe pulse is sent through the material to measure the absorbance change due to the transient states. Here, if the absorbance change was measured by the time delay between pump & probe pulses, the dynamic information of the excited or the transient states (the transient abnsorption changes by time & wavelength) can be obtained. At our laboratory, the ultrashort optic1 pulse (

  • PDF

Stability of hydrophobic properties of plasma polymerized tetrakis(trimethylsilyloxy)silane film surface

  • Jang, Jinsub;Woo, Sungmin;Ban, Wonjin;Nam, Jaehyun;Lee, Yeji;Choi, Woo Seok;Jung, Donggeun
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2016.02a
    • /
    • pp.147.1-147.1
    • /
    • 2016
  • Hydrophobic thin films are variously applicable for encapsulation of organic devices and water repulsive glass, etc. In this work, the stability of hydrophobic characteristics of plasma polymerized tetrakis (trimethylsilyloxy) silane (ppTTMSS) thin films were investigated. The films were deposited with plasma enhanced chemical vapor deposition (PECVD) on the glass. The deposition plasma power and deposition pressure was 70 W and 600 mTorr, respectively. Thereafter, deposited films were treated by 248nm KrF excimer laser. Stability of hydrophobic properties of plasma polymerized tetrakis(trimethylsilyloxy)silane film surface was tested by excimer laser irradiation, which is thought to simulate severe outdoor conditions. Excimer laser irradiation cycles changed from 10 to 200 cycles. The chemical structure and hydrophobicity of ppTTMSS films were analyzed by using Fourier transform infrared (FTIR) spectroscopy and water contact angle (WCA) measurement, respectively. Absorption spectra peaks and WCA of excimer laser treated ppTTMSS films did not change notably. These results show that our ppTTMSS films possess stable hydrophobic properties.

  • PDF

Measurement of excited Xe($1s_4$) and Xe($1S_5$) atoms by laser absorption spectroscopy in coplanar AC-PDP

  • Oh, P.Y.;Lee, J.H.;Moon, H.S.;Hong, J.W.;Jeon, W.;Cho, G.S.;Choi, E.H.
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2004.08a
    • /
    • pp.515-517
    • /
    • 2004
  • The laser absorption spectroscopy has been used for measuresurement of the xenon atoms in the resonant $1S_4$ and metastable $1S_5$ states in coplanar AC PDP. For the purpose of improving VUV luminous efficiency and optimization of PDP cells, it is important to study behavior of excited Xe atoms in a micro-discharge cell of a coplanar AC-PDP. We measured the xenon excited density of $1S_5$ and $1S_4$ state under mixture gas of Ne-Xe(10%) with gas pressure of 350 Torr and sustaining gap distance of 150 um.

  • PDF

Spatiotemporal Behavior of Excited Xenon Atom Density in Accordance with Xenon Mole Fraction to Neon and Helium in Alternating Current Plasma Display Panels by Laser Absorption Spectroscopy

  • Kim, Yong-Hee;Hong, Young-June;Oh, Phil-Yong;Cho, Guang-Sup;Choi, Eun-Ha
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2010.02a
    • /
    • pp.415-415
    • /
    • 2010
  • 면방전 구조의 AC-PDP는 페닝 혼합 기체 중에서 Xe 플라스마에서 발생되는 VUV (Vacuum Ultra Violet) 에 의해 들뜬 형광체로부터 가시광이 발생된다. Xe 여기종은 828 nm의 공명준위를 거쳐 147 nm의 진공자외선을 방출하며 823 nm의 준안정준위에서 분자선을 거쳐 173 nm의 진공 자외선을 낸다. 이러한 Xe 여기종의 밀도를 측정하기 위해서는 828 nm와 823 nm의 레이저를 외부에서 인위적으로 조사하여 측정하면 IR (Infrared)의 흡수전과 흡수후의 빛의 세기로 Xe 여기종의 밀도 및 분포를 계산할 수 있다. 본 실험에서는 823 nm에 초점을 두었으며 LAS (Laser Absorption Spectroscopy) 기법을 통하여 He-Ne-Xe(15%, 20 %, 30%) 400Torr의 3종 기체의 Xe 함량에 따른 시공간의 Xe($1s_5$) 여기종 밀도 분포와 방전효율을 관측하였다. 최근 3전극 면방전형 AC-PDP 효율 향상을 위해 3종 기체의 Xe함량비의 방전기체에 대한 연구가 수행되고 있다. 이러한 기초 데이터는 혼합기체 조건에 따른 면방전 구조의 3전극 AC-PDP의 발광 효율을 개선하는 데 유용한 자료로 활용될 것이다.

  • PDF

Modeling and Experimental Study of Radio-frequency Glow Discharges and Applications for Plasma Processing

  • Kang, Nam-Jun
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2012.02a
    • /
    • pp.179-179
    • /
    • 2012
  • Low pressure radio-frequency glow discharges are investigated using theoretical modeling and various experimental diagnostic methods. In the calculations, global models and transformer models are developed to understand the chemical kinetics as well as the electrical properties such as the effective collision frequency, the heating mechanism and the power transferred to the plasma electrons. In addition, Boltzmann equation solver is used to compensate the effect of the electron energy distribution function (EEDF) shape in the global model, and the general expression of energy balance for non-Maxwellian electrons is developed. In the experiments, a number of traditional plasma diagnostic methods are used to compare with calculated results such as Langmuir probe, optical emission spectroscopy (OES), optical absorption spectroscopy (OAS) and two-photon absorption laser-induced fluorescence (TALIF). These theoretical and experimental methods are applied to understand several interesting phenomena in low pressure ICP discharges. The chemical and physical properties of low pressure ICP discharges are described and the applications of these methods are discussed.

  • PDF

Electronic structure studies of CoFeRO (R=Hf,La,Nb) thin films by X-ray absorption spectroscopy

  • Song, J.H.;Gautam, S.;Chae, K.H.;Asokan, K.
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2010.02a
    • /
    • pp.378-378
    • /
    • 2010
  • We report the electronic structure of CoFeO-R (R=Hf, La, Nb) thin films studied by x-ray absorption spectroscopy (XAS). These ferrites thin films were prepared by pulsed laser deposition method and characterized by XAS measurements at O K-, Co and Fe L-edges. The O K-edge spectra suggest that there is a strong hybridization between O 2p and 3d electrons of transition metal cations and Fe $L_{3,2}$-edge spectra indicate that Fe-ions exist in $Fe^{2+}$ with tetrahedral site of the spinel structure. Divalent Co ions is also distributed in tetrahedral site with rare earth ions goes to octahedral sites of spinel structure. X-ray magnetic circular dichroism (XMCD) is also used to explain the symmetry and magnetic nature dependence on rare-earth ions.

  • PDF

Application of time-of-flight near infrared spectroscopy to Satsuma mandarin

  • Tsuchikawa, Satoru;Ito, Satomi;Inoue, Kinuyo;Miyamoto, Kumi
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
    • /
    • 2001.06a
    • /
    • pp.1627-1627
    • /
    • 2001
  • In this study, a newly constructed optical measurement system, whose main components were a parametric tunable laser and a near infrared photoelectric multiplier, was applied to detection of the information for the inside of Satsuma mandarin using time-of-flight near infrared spectroscopy (TOF-NIRS). The combined effects on the time resolved profile of sample diameter, sugar content, the wavelength of the laser beam, and the detection position of transmitted light were investigated in detail. The samples used were Satsuma mandarin (Citrus unshu $M^{ARC}$.) (location: Wakayama, Japan) having the diameters of 50-84 mm. The sugar content measured by a refractometer varied from 9.9 to 16.3 Brix%. Equator of sample was irradiated vertically with the pulsed laser, and transmitted output power was measured on the restricted position of the equator using the optical fiber cable. The sampling time and the number of averaging the output power were 100 ns and 100 times, respectively. The variation of the attenuance of peak maxima At, the time delay of peak maxima t and the variation of full width at half maximum w were strongly dependent on the detection position and the wavelength of the laser beam. At, t and w increased gradually as the sample diameter increased to be much absorbed and vigorously scattered. On the other hand, each optical parameter had a tendency to increase as the sugar content increased. Such behavior was remarkable when the transmitted light was detected at the side face of a sample. When we apply TOF-NIRS to detection of the information for the inside of fruit with high moisture content like Satsuma mandarin, it is very important to give attention to the difference in the scattered light within tissues and the semi-straightly propagated light. Furthermore, we tried to express the resulting phenomena by using a model samples composed of water, sucrose, and milk. The variation of the time resolved profile is strongly governed by the combination of the light absorption component, scattering medium, and refractive index.

  • PDF

Application of time-of-flight near infrared spectroscopy to Satsuma mandarin

  • Tsuchikawa, Satoru;Ito, Satomi;Inoue, Kinuyo;Miyamoto, Kumi
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
    • /
    • 2001.06a
    • /
    • pp.1626-1626
    • /
    • 2001
  • In this study, a newly constructed optical measurement system, whose main components were a parametric tunable laser and a near infrared photoelectric multiplier, was applied to detection of the information for the inside of Satsuma mandarin using time-of-flight near infrared spectroscopy (TOF-NIRS). The combined effects on the time resolved profile of sample diameter, sugar content, the wavelength of the laser beam, and the detection position of transmitted light were investigated in detail. The samples used were Satsuma mandarin (Citrus unshu $M_{ARC}$.) (location: Wakayama, Japan) having the diameters of 50-84 mm. The sugar content measured by a refractometer varied from 9.9 to 16.3 Brix%. Equator of sample was irradiated vertically with the pulsed laser, and transmitted output power was measured on the restricted position of the equator using the optical fiber cable. The sampling time and the number of averaging the output power were 100 ns and 100 times, respectively. The variation of the attenuance of peak maxima At, the time delay of peak maxima $\Delta$t and the variation of full width at half maximum Δw were strongly dependent on the detection position and the wavelength of the laser beam. At, $\Delta$t and $\Delta$w increased gradually as the sample diameter increased to be much absorbed and vigorously scattered. On the other hand, each optical parameter had a tendency to increase as the sugar content increased. Such behavior was remarkable when the transmitted light was detected at the side face of a sample. When we apply TOF-NIRS to detection of the information for the inside of fruit with high moisture content like Satsuma mandarin, it is very important to give attention to the difference in the scattered light within tissues and the semi-straightly propagated light. Furthermore, we tried to express the resulting phenomena by using a model samples composed of water, sucrose, and milk. The variation of the time resolved profile is strongly governed by the combination of the light absorption component, scattering medium, and refractive index.

  • PDF

Temperature and Concentration measurement using Semi-conductor diode laser (반도체레이져를 이용한 온도 및 농도의 계측)

  • Chung, D.H.;Noh, D.S.;Ikeda, Yuji
    • 한국연소학회:학술대회논문집
    • /
    • 2000.12a
    • /
    • pp.168-174
    • /
    • 2000
  • A diode laser sensor system based on absorption spectroscopy techniques has been developed to measure $CO_2$ concentration and temperature non-intrusively in high temperature combustion environments using a 2.0 ${\mu}m$ DFB(Distributed Feedback) laser. Two optics was fabricated in pig-tail fashion and all optical components were implemented in a single box. The evolution of measurement sensitivity was done using test cell by changing sweep frequency and $CO_2$ concentration. Gas temperature was determined from the ratio of integrated line strengths. Species concentration was determined from the integrated line intensity and the measured temperature. The result show that the system has 2% error in wide operation frequency range and accuracy of $CO_2$ concentration was about 3%. The system was applied to measure temperature and concentration in the combustion region of a premixed $CH_4$ +air triangular flame. The measurement results of gas temperature agreed well with thermocouple results. Many considerations were taken into account to reduce optical noise, etalon effect, beam steering and base line matching problem. The evaluations results and actual combustion measurement demonstrate the practical and applicability for in-situ and real time combustion monitoring in a practical system.

  • PDF

Spectral Mode Analysis of an Injection-Locked Semiconductor Laser (광 주입-잠금된 반도체 레이저의 모드 분석)

  • Bae, I.H.;Moon, H.S.;Kim, J.N.
    • Korean Journal of Optics and Photonics
    • /
    • v.18 no.5
    • /
    • pp.317-322
    • /
    • 2007
  • We performed injection-locking by two independent semiconductor lasers and investigated the spectral modes of the injection-locked laser From the observation of the saturated absorption spectrum in the $^{85}Rb$ D1 transition line, we have confirmed that the frequency of the injection-locked slave laser is synchronized by the frequency of the master laser, and the slave laser has a narrow linewidth after injection-locking. According to the intensity injected into the slave laser, we measured the variation of the injection-locking range and the mode of the injection-locked slave laser by using the confocal Fabry-Ferret interferometer. In the case of the incomplete injection-locking, we observed the competition between the free running mode of the slave laser and the mode of the master laser and analyzed the modes of the injection-locked slave laser.