• Advances in Energy Research
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• v.4 no.3
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• pp.213-221
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• 2016

The main purpose of this work is to test the validation of use of a four step reaction mechanism to simulate the laminar speed of hydrogen enriched methane flame. The laminar velocities of hydrogen-methane-air mixtures are very important in designing and predicting the progress of combustion and performance of combustion systems where hydrogen is used as fuel. In this work, laminar flame velocities of different composition of hydrogen-methane-air mixtures (from 0% to 40% hydrogen) have been calculated for variable equivalence ratios (from 0.5 to 1.5) using the flame propagation module (FSC) of the chemical kinetics software Chemkin 4.02. Our results were tested against an extended database of laminar flame speed measurements from the literature and good agreements were obtained especially for fuel lean and stoichiometric mixtures for the whole range of hydrogen blends. However, in the case of fuel rich mixtures, a slight overprediction (about 10%) is observed. Note that this overprediction decreases significantly with increasing hydrogen content. This research demonstrates that reduced chemical kinetics mechanisms can well reproduce the laminar burning velocity of methane-hydrogen-air mixtures at lean and stoichiometric mixture flame for hydrogen content in the fuel up to 40%. The use of such reduced mechanisms in complex combustion device can reduce the available computational resources and cost because the number of species is reduced.

• Proceedings of the KSME Conference
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• 2000.11b
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• pp.704-709
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• 2000

Laminar burning velocities of propane- and iso-octane-air mixtures have been numerically modelled over a wide range of equivalence ratio, pressure and temperature. These correlations are applicable to the modelling of stratified charged combustion like that of lean bum and GDI engine combustion. The numerical models are based on the results calculated by PREMIX code with Sloane's detailed chemical reaction mechanism for propane and FlameMaster code with Peters' for iso-octane. Laminar burning velocity for two fuels showed a pressure and temperature dependence in the following form, in the range of $0.1{\sim}4MPa$, and $300{\sim}1000K$, respectively. $S_L={\alpha}\;{\exp}[-\xi({\phi}-{\phi}_m)^2-{\exp}\{-{\xi}({\phi}-{\phi}_m)\}-{\xi}({\phi}-{\phi}_m)]$ where ${\phi}_m=1.07$, and both of ${\alpha}$ and ${\xi}$ are functions of pressure and temperature. Compared with the results of the existing models, those of the present one showed the good agreement of the recent experiment data, especially in the range of lean and rich sides. Judging from the calculated results of the stratified charged combustion by using STAR-CD, the above modelling prove to be more suitable than the other ones.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.207-209
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• 2012

The present experiment was conducted to measure the unstretched laminar burning velocity and cellular instability of DME-air and syngas (in steps of 25 %) added DME-air premixed flames using propagating spherical flame. The experimental results were discussed in two focuses which are effects of syngas fraction and initial pressure on Markstein length, unstretched laminar burning velocities, and cellular instability. The flame instability was evaluated by the Markstein length and cellularity which is caused by diffusional-thermal instability and hydrodynamic instability.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.2
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• pp.195-201
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• 1997

Static and non-static flame methods were used to measure the laminar burning velocity of methane, ethane and natural gas. The flame slot angle and velocity of unburned gas mixture were determined by Schlieren method and LDV, respectively, for static flame. The diameter of nozzle was selected as 11 mm. The experimental results containing the stretch effect showed that the maximum burning velocities were 41.5 for natural gas, 40.8 for methane and 43.4 cm/sec for ethane on equivalence ratio of 1.1. Constant volume combustion chamber was also used for non-static flame. The propagation process of flame front was visualized by high speed camera during constant pressure. The maximum burning velocity of natural gas was determined as 42.1 cm/sec on equivalence ratio of 1.15.

• Journal of the Korean Society of Industry Convergence
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• v.12 no.3
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• pp.137-142
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• 2009

Burning velocity of methane-air mixtures with water vapor have been measured to study the process of flame propagation using schlieren photographs and computation. The computations were carried out for the burning velocity using premix code of Chemkin program to compare the experimental results. The quantity of water vapor contained were changed 5% and 10% of total mixtures, and equivalence ratio of mixtures between 0.8 and 1.2 were tested under the ambient temperature 323K and 373K. The results showed little difference between these two methods, the burning velocity was decreased by increasing the water vapor contents due to the interruption of flame development. And, the effect of ambient temperature was less significant by increasing the water contents on the burning velocity.

• 한국연소학회:학술대회논문집
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• 2004.11a
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• pp.62-69
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• 2004

Zone conditional formulations for the Reynolds average reaction progress variable are used to derive an asymptotic expression for turbulent burning velocity. New DNS runs are performed for validation in a statistically one dimensional steady state configuration. Parametric study is performed with respect to turbulent intensity, integral length scale, density ratio and laminar flame speed. Results show good agreement between DNS results and the asymptotic expression in terms of measured maximum flame surface density and estimated turbulent diffusivity in unburned gas.

• Journal of the Korean Society of Combustion
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• v.9 no.4
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• pp.1-8
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• 2004

Zone conditional formulation for the Reynolds average reaction progress variable is used to derive an asymptotic expression for turbulent burning velocity. New DNS runs are performed for validation in a statistically one dimensional steady state configuration. Parametric study is performed with respect to turbulent intensity, integral length scale, density ratio and laminar flame speed. Results show good agreement between DNS results and the asymptotic expression in terms of measured maximum flame surface density and estimated turbulent diffusivity in unburned gas.

• Transactions of the Korean hydrogen and new energy society
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• v.25 no.1
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• pp.47-58
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• 2014

The characteristics of flame shape, laminar burning velocity, emissions and heat flux of stagnation point in premixed impinging jet flame of syngas fuel with 10% hydrogen content were experimentally investigated. Also, the adiabatic temperature and burning velocity are calculated by Chemkin package with USC-II mechanism. The equivalence ratios(0.8~5.0) and dimensionless separation distance(2.0~5.0) with fixed Reynolds number(1800) are main parameters in this work. Different flame shapes and colors were observed for different impingement conditions. The experimental results of burning velocity by flame surface area have a consistent with previous works and numerical simulation of this work. The inner flame length could be predicted with the ratio of mixture velocity and burning velocity from a simple formulation by the laminar burning velocity definition. It has been observed that the heat fluxes at stagnation point are directly affected by the flame shape including the separation distance. The emission results in impinging flame of syngas fuel show that the characteristics of $NO_x$ emission traced well with adiabatic temperature trend and CO emission due to fuel rich condition increased continuously with respect to the equivalence ratio.

• Journal of the Korean Society of Combustion
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• v.16 no.2
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• pp.23-32
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• 2011

To investigate cell formation in hydrocarbon/hydrogen/carbon monoxide-air premixed flames, the outward propagation and cellular instabilities were experimentally studied in a constant pressure combustion chamber at room temperature and elevated pressures. Unstretched laminar burning velocities and Markstein lengths of the mixtures were obtained by analyzing high-speed schlieren images. In this study, hydrodynamic and diffusional- thermal instabilities were evaluated to examine their effects on flame instabilities. The experimentally-measured unstretched laminar burning velocities were compared to numerical predictions using the PREMIX code. Effective Lewis numbers of premixed flames with methane addition decreased for all of the cases; meanwhile, effective Lewis numbers with propane addition increased for lean and stoichiometric conditions and increased for rich and stoichiometric cases for hydrogen-enriched flames. With the addition of propane, the propensity for cell formation significantly was diminished, whereas cellular instabilities for hydrogen-enriched flames were promoted. However, similar behavior of cellularity was obtained with the addition of methane to the reactant mixtures.

• Journal of the Korean Society of Industry Convergence
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• v.11 no.1
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• pp.5-10
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• 2008

A flame speed of methane mixture of water vapor and air have been measured to study the process of flame propagation using schlieren photographs. The quantity of water vapor contained were changed 5% and 10% of total mixture, and equivalence ratio of mixture between 0.8 and 1.2 were tested under the ambient temperature 323K and 373K. The results showed that the burning velocity was decreased by increasing the water vapor contents due to the interruption of flame development. And, the reduction rate of burning velocity was smaller by increasing the water contents under the same ambient temperature. The effects of ambient temperature on burning velocity was decreased by increasing the water vapor contents.