• 한국수소및신에너지학회논문집
• /
• 제26권1호
• /
• pp.1-7
• /
• 2015

In this study, characteristics of reforming process of automotive liquefied petroleum gas (LPG) fuel using plasma reactor are investigated. Because plasma reformer technology has advantages of a fast start-up and wide fuel/oxidizer ratio of operation, and reactor size is smaller and more simple compared to typical combustor and catalytic reactor, plasma reforming is suitable to the on-board vehicle reformer. To evaluate the characteristics of the reforming process, parametric effect of $O_2/C$ ratios, reactant flow rate and metal form on the process were investigated. In the test of varying $O_2/C$ ratio from partial oxidation to stoichiometry combustion, conversion of LPG was increased but selectivity of $H_2$ decreased. The optimum condition of $O_2/C$ ratio for the highest $H_2$ yield was determined to be around 1.0 for 20~50 lpm, and 1.35 for 100 lpm. Specific energy density (SED) was major factor in reforming process and higher SED leads to higher $H_2$ yield. And metal form in the reformer increased $H_2$ yield of about 34 % as compared to the case of no metal form. The result can be a guide to map optimal condition of reforming process.

• 대한화학회지
• /
• 제48권2호
• /
• pp.156-160
• /
• 2004

LPG용 고압고무호스의 가소제 추출률에 대하여 연구하였다. 가소제 추출을 위한 침지용 용매는 프로판, n-부탄, n-펜탄, n-헥산, n-헵탄이며, 프로필렌, 1,3-부타디엔, 1-펜텐, 1-헥센, 에탄티올, t-부탄티올, 황화에틸메틸, 황화이메틸으로 조성되어 있다. 다중회귀분석으로 가소제 추출량과 침지용매의 설명인자사이의 상관관계를 다음과 같이 얻을 수 있었다. PE(wt%)=7.5193(${\pm}$0.2466) - 0.585000(${\pm}$0.05437)Carbon${\sharp}$ + 2.3294(${\pm}$0.1967)DB + 2364(${\pm}$896.2)SH (N = 13, F = 24.135, R$^2$ = 0.8894, R$_{adj}^2$ = 0.8526, Variance = 7.588) 증기압이 높고 극성도가 높은 조성의 LPG에 의하여 가소제는 많이 용출되었다. LPG에서 티올계 황화합물과 프로필렌이나 부타디엔 등의 불포화 탄화수소의 함량이 높아질수록 추출되는 가소제량은 증가한다. 반면에 큰 탄화수소일수록 고무로부터 추출된 가소제량은 적었다.

• 한국가스학회지
• /
• 제11권1호
• /
• pp.23-28
• /
• 2007

본 본문에서는 LPG 용기용 가스밸브의 O-링과 밸브패킹의 밀봉결함과 크랙에 관련된 실험적 연구를 수행하고자 한다. LP 가스의 누출을 방지하기 위해 사용하는 O-링은 LPG 밸브의 밀봉 안전성을 확보하는 핵심부품으로 대단히 중요하다. 밸브패킹은 LPG 연료의 공급과 충전을 하는데, 가스 공급구를 열고 닫는 중요한 역할을 담당한다. 이들 두개의 밀봉부품에 대한 성능은 밸브의 누설 안전성과 장수명에 밀접한 관련이 있다. 연구결과에 의하면, O-링의 대부분은 파티션 부근의 결합불량과 과도한 압축률로 인해 원주방향으로 크랙이 발생하는 것으로 분석되었다. 그 이외의 결함으로 거론된 경우는 LP가스의 과도한 가스압력으로 인한 압출현상의 발생은 압출크랙을 일으키는 원인으로 작용하고 있다. 따라서 본 논문에서는 가스밸브의 누설 안전성을 확보하고 수명을 연장하기 위해 O-링과 밸브패킹에 대한 엄격한 품질관리와 인증제도의 도입을 권장하고자 한다. 결국에는 LPG용기용 밸브의 품질과 안전성 확보를 위해 밀봉장치에 대한 품질안전 보증제도를 도입해야 밸브를 오랫동안 사용할 수 있을 것이다.

• 대한기계학회논문집B
• /
• 제27권11호
• /
• pp.1563-1571
• /
• 2003

This paper is the second part of several companion papers which compare the method of Air-fuel ratio(AFR) determination. In the previous paper, Eltinge chart was applied to the arbitrary fuel composition and the charts for gasoline, diesel, methanol, M85, liquefied petroleum gas(LPG), natural gas(NG), propane and butane were illustrated. In Eltinge chart, however, unburned hydrocarbon (UHC) is not used for determination of AFR. For improving accuracy, Eltinge suggested UHC compensation after the AFR reading in the chart. This compensation reduced the difference between real and reading value. In the compensation, however, the correction of oxygen and carbon dioxide is uncertain and there might be a mistake in conversion of UHC reading value. Therefore, the error is overestimated comparing with Spindt one which is most widely used. In addition, there is no comparison of the value with other useful methods. In this paper, the compensation of unburned HC was performed in Eltinge chart and the compensated value was compared with Spindts formula over wide range of AFR. The objects of investigating fuel are gasoline, methanol, NG and LPG. The result shows that Eltinge and Spindt method is flawlessly compatible and the difference between the two methods is under 0.3% in a λrange from 0.9 to 1.7. The method fur debugging instrumentation error is also presented.

• 한국안전학회지
• /
• 제25권3호
• /
• pp.53-60
• /
• 2010

액화석유가스 자동차는 대도시의 대기환경 개선을 위해 적용되고 있으며 대기 오염물질을 저감시키는데 효과적인 것으로 입증되고 있다. 이와 더불어 환경 친화적인 에너지원으로서 가스의 수요가 날로 급증하고 있으며, LPG 충전소도 해마다 증가추세이다. 따라서 본 논문에서는 충전소에서 증기운폭발에 의한 화염의 영향으로 인간에게 미치는 영향을 알아보고자 한다. 이를 위하여 API에서 규정한 피해예측을 통하여 평가를 실시하였다. 폭발장소에서의 화염에 의해 미치는 영향 거리를 산출하여 거리별 복사열의 크기를 알게 되면 그 지점에서의 피해는 간단하게 예측할 수 있다. 또한 폭발장소 주변에 위치한 인간에게 미치는 영향을 PROBIT 모델에 적용하여 사고피해예측을 평가하였다. 프로빗 분석에 의하면 화염에서 30m 이격된 곳은 1도 화상에 의한 손상확률이 100%, 2도 화상에 의한 손상확률은 99.2%, 화재로 인한 사망확률은 93.4%로 나타났다.

• 동력기계공학회지
• /
• 제19권2호
• /
• pp.49-56
• /
• 2015

As an alternative fuel that can be used in SI engine, LPG is one of clean fuels with larger H/C ratio compared to gasoline, low $CO_2$ emission, and small amount of pollutants such as sulfur compounds. When LPG is used in spark ignition engine, volumetric efficiency of the engine can be improved and pumping loss can be reduced by performing direct injection into the combustion chamber instead of port fuel injection. LPG-DI engine allows for lean combustion and stratified combustion under low load. In case of stratified combustion, air fuel ratio can be greatly increased compared to theoretic mixture ratio combustion. Improved thermal efficiency of the engine and reduced pumping loss can be expected from stratified combustion. Accordingly in this study, an experimental apparatus for visualization was designed and manufactured to study the combustion process of LPG after injection and ignition, intended to examine ignition probability and combustion characteristics of spark ignition direct injection(SIDI) LPG fuel. Ambient pressure, ambient temperature and fuel injection pressure were found as important variables that affect ignition probability and flame propagation characteristics of LPG-air mixture. Also, it was verified that the injected LPG fuel can be directly ignited by spark plug under appropriate ambient conditions.

• Journal of Advanced Marine Engineering and Technology
• /
• 제35권5호
• /
• pp.566-575
• /
• 2011

LPG 연료공급방식은 배출가스를 저감시킬 수 있는 유용한 시스템으로 연구가 지속적으로 진행되고 있다. LPG는 경유와 휘발유보다 높은 증기압과 낮은 점도와 표면장력을 유지하므로 고무류와 화학 반응에 따른 연료펌프의 기계적인 손상으로 내구성이 저하되고 있는 실정이다. 본 연구에서는 이러한 문제점을 해결하기 위해 LPLi 시스템에서 유지보수의 편리함과 가격경쟁을 위해 개발된 외장형 펌프를 사용하여 LPG 연료의 조성 및 온도에 따른 특성을 평가하고자 실험을 하였다. 그 결과로서, 내장형 펌프와 외장형 펌프의 성능차이는 거의 없으며 프로판 함유율이 높고, 연료온도가 높아짐에 따라 유량은 많아지나 펌프효율은 거의 차이가 없었다. 또한 LPG 자동차 연료공급장치의 특성상 연료조성 및 온도변화에 따른 차압도 거의 일정하게 나타내었다.

• 한국분무공학회지
• /
• 제12권4호
• /
• pp.204-210
• /
• 2007

The worldwide energy problem and global warming cause the need of alternative fuels which feature low carbon-dioxide emission and another energy source. Liquefied Petroleum Gas (LPG) is one of the alternative fuels widely used as domestic and transportational fuel. The third generation LPLi fuel supply system has merits in the increase of engine power and low emissions. The injectors used in LPLi system should overcome a leakage problem and satisfy the durability conditions. Therefore, 1000 hour durability test of the injectors was carried out throughout this research. First, the spray pattern and the penetration length of the selected injectors is graphically shown. Next, the leakage amount with respect to the injection cycle is introduced. Finally, the shapes of nozzle holder and nozzle tip after durability test was investigated by analyzing the microscopic image of the injector tip. The variation in the shape of nozzle tip mainly due to the residue of rubber materials is found to be the reason for leakage.

• 한국연소학회지
• /
• 제14권2호
• /
• pp.18-25
• /
• 2009

Fuel lean reburning method is very attractive way in comparison with conventional reburning method for reducing NOX. Meanwhile, the knowledge of the how flue gas re-circulated, temperature distribution and species concentration is crucial for the design and operation of an effective fuel lean reburning system. For this reason, numerical analysis of fuel lean reburning system is a very important and challenge task. In this work, the effect of fuel lean reburn system on NOX reduction has been experimentally and numerically conducted. Experimental study has been conducted with a 15kW lab scale furnace. Liquefied Petroleum Gas is used as main fuel and reburn fuel. To carry out numerical study, the finite-volume based commercial computational fluid dynamics (CFD) code FLUENT6.3 was used to simulate the reacting flow in a given laboratory furnace. Steady state, three dimensional analysis performed for turbulent reactive flow and radiative heat transfer in the furnace.

• Journal of Power Electronics
• /
• 제5권4호
• /
• pp.305-311
• /
• 2005

Throughout the world, studies on the water energization are currently under way. Of those, Brown gas, which is generated through the electrolyzation of water and is a mixed gas of the constant volume of 2 parts hydrogen to 1 part oxygen, has better characteristics in terms of economy, energy efficiency, and environmental affinity than those of acetylene gas and LPG (Liquefied Petroleum Gas) used for existing welding machines. This paper analyzes the characteristics of Brown gas and presents methods for increasing the generating efficiency of Brown gas by designing a power supply to deliver power to a water-electrolytic cell and designing a cylindrical electrode to improve the efficiency of the electrolyzer needed for water electrolyzation. Based on the above the methods, a welding machine using Brown gas is developed. And the generation efficiency of Brown gas is measured tinder different conditions (duty ratio, frequency and amplitude) of supplied power.