• 한국가스학회지
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• 제11권2호통권35호
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• pp.65-70
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• 2007

LP 가스의 폭발현상 및 위험성을 평가하기 위하여, 산소농도변화와 LP 가스의 농도에 따른 혼합가스 조성을 변화시켜 실험을 행하였다. 산소농도 21%에서 LP 가스의 농도가 증가할수록 폭발하한계는 낮아졌으며, 최소산소농도(MOC, Minimum Oxygen Concentration)는 1.0 bar, 1.5 bar, 2.0 bar에서 각각 14.5%, 12.0%, 11.5%로 낮아졌다. 최대폭발압력은 압력이 증가할 경우 $6.46kg/cm^2,\;9.41kg/cm^2,\;13.49kg/cm^2$로 증가하였으며, LP 가스의 초기압력이 클수록 화염의 전파속도가 증가하였다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2015년도 제51회 KOSCO SYMPOSIUM 초록집
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• pp.61-63
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• 2015

In the low pressure selective catalytic reduction (LP SCR) system, the uniformity of both ammonia concentration and exhaust gas flow at the SCR catalyst layer are important design factor for the efficient SCR-deNOx performance. According to the shape of the guide vane and static mixer, numerical simulations were conducted to analyze flow patterns and finally to find out the appropriate alternative for uniform flow at the front of catalyst in the real scale LP SCR reactor. The variations of gas velocity and ammonia concentration were quantitatively evaluated. Based on the present results, the shape was devised to satisfy the design criteria.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집D
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• pp.708-714
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• 2001

Although LP gas has lots of advantages, there has been limitation in application for automotive engine due to the several disadvantages, such as power decrease, complex fuel supply unit, and back fire etc. However LP gas direct injection engine has possibility to solve the problems above mentioned. LEM(Light Extinction Method) was employed for analysis of spacial and temporal distribution of LP gas which is directly injected into combustion chamber under various pressure and temperature conditions. The results from CVC(Constant Volume Chamber) were compared to those of RICEM(Rapid Induction, Compression and Expansion Machine) which simulate early- and late injection of direct injection engine. LPG fuel spray is affected by temperature and pressure in evaporation characteristics but it is more benefit to direct injection engine in every way such as, fuel distribution, evaporating speed and well wetting reduction.

• 한국대기환경학회지
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• 제21권1호
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• pp.1-14
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• 2005

In this study, a Long Path Differential Optical Absorption Spectroscopy system (K-JIST LP-DOAS) has been used to simultaneously measure atmospheric monoaromatic hydrocarbons and other trace compounds. The validity of the K-JIST LP-DOAS for measuring atmospheric monoaromatic hydrocarbons was tested during a field campaign between 12 February and 14 March 2003 at an urban site in Seoul, Korea through inter-comparative measurements against a collocated on-line Gas Chromatography (GC) system. The concentrations of benzene, toluene, p-xylene, and m-xylene were measured with the K-JIST LP-DOAS system in the UV region (239～302 nm) over a 740 m beam path. For the other trace compounds, a longer spectral range (299～362 nm) was used. In order to remove the interference of atmospheric abundant species (such as oxygen, sulfur dioxide and ozone), two oxygen optical density spectra obtained at two pathlengths, 697 and 1133m, and reference spectra of sulfur dioxide and ozone were incorporated in the fitting procedure. The mean concentrations measured by our LP-DOAS during the measurement period were 0.77 ($\pm$0.38) ppbv for benzene, 3.68 ($\pm$1.90) ppbv for toluene, 0.41 ($\pm$0.19) ppbv for p-xylene, 0.54 ($\pm$0.24) ppbv for m-xylene. The concentration data of benzene, toluene, p-xylene and m-xylene obtained by our LP-DOAS were found to be in relatively good correlations with those of the online GC system. Pearson's coefficients in the observed concentrations between LP-DOAS and on-line GC were 0.84 for benzene, 0.83 for toluene and 0.65 for m,p-xylene. This study suggests that the LP-DOAS system can be used to provide reliable information on both the mixing ratios and temporal distribution characteristics of monoaromatic hydrocarbons in the urban air.

• 한국안전학회지
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• 제8권4호
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• pp.107-113
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• 1993

Small rectangular explosion chamber of its size 25cmX25cmX32cm with a circular bursting diaphram at the top was used to study the mechanism of gas explosion to fire transition phenomena, the process of ignition of solid combustibles during a gas explosion. To visulize the explosion to fire transition phenomena, transparent acryl window and high speed camera system were used. The test piece of solid combustible in this experiments was a 5cm$\times$5cm square sheet of newspaper which was placed in the explosion chamber filled with a LPG-air mixture. The mixture was ignited by an electric spark at the center of the chamber. Explosion to fire transition phenomena and the behavior of out flow and in flow of gas through the opening yielded by bursting the diaphram was visualized with shlieren system and without shlieren system. Diameter of a bursting dlaphram at the top of the explosion chamber was varied 5cm, 10cm, and 15cm, and the position of test piece were varied with 6 point. Explosion pressure was measured with strain type pressure transducer, and the weight difference of the test piece before and after each experimental run was measured. By comparing the weight difference of solid combustibles before and after the experiment and the behavior of out flow and inflow of gas after explosion, it was found that the possibility of ignition was depends on the LPG-air mixture concentration and the exposure period of test piece to the burnt gas. Test result of this experiments it was found that the main factor of this phenomena are that heat transfer to the test piece, and the pyrolysis reaction of test piece. Based on the results, the mechanism of the explosion to fire transition phenomena were inferred ; gas explosion- heat transfer to solid combustibiles ; pyrolysis reaction of solid combutibles : air inflow ; mixing of the pyroly gas with air ignition.

• 한국화재소방학회논문지
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• 제18권2호
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• pp.20-26
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• 2004

본 논문은 가스폭발로부터 화채로의 전이현상 및 전이 방지 연구를 위해 가로 세로 높이가 각각 $100 cm {\times} 60 cm {\times} 45 cm$인 폭발용기를 사용하여 폭발 후 화재로의 전이현상을 고속 비디오로 가시화하고 가시화된 영상을 분석하여 그 기구들을 확인하였다. 고체 가연물로는 신문용지를 가로 세로가 $30cm {\times} 20cm$크기로 절단하여 사용하였고 LPG-공기 혼합가스는 10㎸ 전기 스파크를 사용하여 점화시켰다. 실험 변수로는 혼합가스의 농도, 개구부의 크기 및 가연물의 위치 등이었으며, 파열면의 크기는 $10cm {\times} 9cm, 13cm {\times} 10cm, 27cm {\times} 20cm, 40cm {\times} 27cm$로 하였고 가연물의 설치 위치는 4종류로 하였다. 폭발 후 전이 방지 기구의 고찰은 가스 소화약제인 이산화탄소를 이용하여 실험하였다. 실험 결과 가스폭발로부터 화재로의 전이 현상은 혼합가스의 농도와 고온의 화염 및 연소가스에 노출되는 시간에 많은 영향을 받으며 폭발 후 분위기의 냉각이나 불활성화를 통해 화재로의 전이를 방지 할 수 있음을 알 수 있었다.

• 에너지공학
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• 제14권4호
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• pp.268-276
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• 2005

액체연료(중유)공급량 기준 20kg/hr규모의 반응로에서 증기분무 내부 혼합식 노즐을 이용하여 잔사유의 연소실험을 수행하였다. 본 실험에서 사용한 감압 잔사유는 점도가 높고 황함량, 잔류탄소와 금속성분의 함량도 높았다. 잔사유의 착화를 위해서는 반응로를 일정온도까지 예열하여야 했으며 이는 LPG를 이용하였다. 잔사유 공급량을 변화시키면서 축방향 및 반경방향의 로내 가스 온도, 주요 가스농도 및 채집된 고체 입자를 분석하였다. 잔사유의 주반응영역은 버너 팁으로부터 약 1 m 근방에서 형성되었으며 이는 축방향 가스 온도, 농도 분포 및 입자의 크기로부터 확인할 수 있었고, 반응로의 하류에서는 완전 확립된 온도분포를 보여주고 있었다. 고체 입자의 SEM 분석으로부터 잔류 탄소입자는 기공이 많은 형태를 띠고 있었다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.136.1-136.1
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• 2015

In the present study, UHF (320 MHz) in combination with RF (13.56 MHz) plasmas was used for the synthesis of hydrogenated silicon nitride (SiNx:H) films by PECVD process at low temperature. RF/UHF hybrid plasmas were maintained at a fixed pressure of 410 mTorr in the N2/SiH4 and N2/SiH4/NH3 atmospheres. To investigate the radical generation and plasma formation and their control for the growth of the film, plasma diagnostic tools like vacuum ultraviolet absorption spectroscopy (VUVAS), optical emission spectroscopy (OES), and RF compensated Langmuir probe (LP) were utilized. Utilization of RF/UHF hybrid plasmas enables very high plasma densities ~ 1011 cm-3 with low electron temperature. Measurements using VUVAS reveal the UHF source is quite effective in the dissociation of the N2 gas to generate more active atomic N. It results in the enhancement of the Si-N bond concentration in the film. Consequently, the deposition rate has been significantly improved up to 2nm/s for the high rate synthesis of highly transparent (up to 90 %) SiNx:H film. The films properties such as optical transmittance and chemical composition are investigated using different analysis tools.

• 한국진공학회지
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• 제5권3호
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• pp.206-212
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• 1996

저압MOCVD 방법을 이용하여 76 Torr에서 $In_{1-x}Ga_xAs$ 에피층을 성장하였다. 성장온도에 따른 성장속도의 변화는 크지 않았으며, 격자불일치와 성장온도, $AsH_3/(TMIn+TMGa)$ 비에 따라 표면형상이 변화하는 경향성을 관찰하였다. 깨끗한 byaus을 가지는 $In_{1-x}Ga_xAs$ 에피층의 5K PL 측정을 통하여 2.8meV 반가폭을 가지는 결정성이 좋은 에피가 성장되었음을 확인하였다. 성장온도에 따른 조성의 변화는 크지 않았으며, 고체상에서의 $In_{1-x}Ga_xAs$ 조성은 기체상에서의 원료가스의 확산단계에 의해 결정되었다. 격자불일치와 성장온도가 $In_{1-x}Ga_xAs$ 에피층의 전기적 특성을 결정하는 가장 중요한 변수로 확인되었고, 최적조건에서 성장한 에피층에 대해 상온에서 $8{\times}10^{14}/cm^3$의 전자농도와 11,000$\textrm{cm}^2$/V.sec 의 전자이동도를 얻었다.