• Journal of ILASS-Korea
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• v.23 no.4
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• pp.212-220
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• 2018

As increase the number of vehicles, the issue of greenhouse gas that was emitted by them became important. As a result, greenhouse gas (GHG) regulations are being strengthened and efforts are being actively made to reduce greenhouse gas emissions in the automotive industry. In the other hand, regulations for harmful emission of vehicles have been reinforced by step. Especially, the lastly applied step, so called Euro 6, not only decreased NOx limit down to half of Euro 5 but also introduced real driving emission limit for NOx and PN. It is a challenge for manufacturers to meet the recent GHG regulation as well as the latest emission regulation. To overcome these regulations a De-NOx after-treatment system is being applied to diesel vehicles that are known emitting the lowest GHG among conventional internal combustion engines. At the time of the introduction of Euro 6 emission standard in Korea, in the domestic fuel economy certification test, some diesel vehicles emitted more $CH_4$ than Euro 5 vehicles. As a result, it was confirmed that LNT-equipped vehicles emitted a high level $CH_4$ and the level exceeded the US emission standard. In order to determine the reason, various prior literature was investigated. However, it was difficult to find a detailed study on the methane increase with LNT. In this paper, to determine whether the characteristics of vehicles equipped with LNT the affects the above issue and other greenhouse gases, 6 passenger cars were tested on several emission test modes and ambient temperatures with a environment chamber chassis dynamometer. 2 cars of these were equipped with LNT only, other 2 cars had SCR only, and LNT + SCR were applied to remaining 2 cars. The test result shown that the vehicles equipped with LNT emitted more $CH_4$ than the vehicles with SCR only. Also, $CH_4$ tended to increase as the higher acceleration of the test mode. However, as the test temperature decreases, $CH_4$ tended to decreased. $CO_2$ was not affected by kinds of De-NOx device but characteristic of the test modes.

• Journal of ILASS-Korea
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• v.21 no.4
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• pp.200-206
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• 2016

Recently, the certification procedure for exhaust emission regulation of LDV has tested with the NEDC mode in the laboratory. But the on-road exhaust emissions exceed the standard emission limits. Therefore, it is important to analyze the real-driving emissions (RDE) with a portable emissions measurement system (PEMS). In present study, the on-road emissions were measured with a PEMS and evaluated by moving averaging window (MAW) method. Also, it was compared with the $CO_2$ and $NO_x$ emissions for real-driving and test modes from euro-6 light-duty vehicles equipped with SCR and LNT systems. In results, on-road $NO_x$ emission has been 2.3-10.0 times higher than the standard $NO_x$ emission limit on NEDC mode. The reason was that the test modes did not reflect traffic and various real-driving patterns sufficiently.

• Proceedings of the KIEE Conference
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• 1993.07b
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• pp.1103-1105
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• 1993

Microwave characteristics of the system (1-X) ${Na}_{1/2}{Sm}_{1/2}TiO_3$[NST]-X ${Li}_{1/2}{Nd}_{1/2}TiO_3$[LNT] were investigated. The dielectric constant and unloaded Q were 86,1950 respectively for NST at 3GHz and 80,500 for LNT. 0.4 NST - 0.6 LNT system has the dielectric constant ${\varepsilon}r$=86.2, Q=930(3GHz), temperature coefficient of the resonant frequency ${\tau}f$ = 8 ppm/$^{\circ}C$ when sintered at $1450^{\circ}C$ for 2h.

• Clean Technology
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• v.21 no.3
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• pp.184-190
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• 2015

Most of LNT catalysts use noble metals such as Pt for low temperature NO_x oxidation but there is an economic weakness. For the purpose of overcoming this, this study is to develop DeNO_x catalyst for LNT excluding PGM (platinum group metal) such as Pt, Pd, Rh, etc. To do so, Al/Co/Ni catalyst selected as a preliminary test is used to study fundamental property and NO_x’s conversion according to calcined temperature. Ultimately, that is, Al/Co/Ni mixed metal oxide which does not use PGM is selected and physicochemical characterization is performed by way of XRD, EDS, SEM, BET and ramp test and NO_x conversion is also analyzed. This study shows that all samples consist of mixed oxides of spinel structure of Co₂AlO₄ and NiAl₂O₄ and have enough pore volume and size for redox. But as a result of NH₃-TPD test, it is desired that calcined temperature needs to be maintained at 700 ℃ or lower. Also only samples which are processed under 500 ℃ satisfied NO and NO_x conversion simultaneously through ramp test. Based on this study’s results, optimum calcined temperature for Al/Co/Ni=1.0/2.5/0.3 mixed metal oxide catalyst is 500 ℃.

• Clean Technology
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• v.21 no.2
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• pp.117-123
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• 2015

This inquiry was conducted to develop DeNOx catalyst for LNT. In order to develop appropriate catalysts, four catalysts, which do not use PGM (Platinum Group Metal), were carefully selected : Al/Co/Mn, Al/Co/Ni/Mn, Al/Co/Mn/Ca, Al/Co/Ni mixed metal oxides during preliminary experiments. Also, XRD, EDS, SEM, BET and TPD tests were carried as well to evaluate both physicochemical properties of such four catalysts. As a result of the experiment, four catalysts were composed of spinel-shaped crystals and had more than enough pore volume and size to have oxidation-reduction reaction of NOx gases. Additionally, through TPD test, all four types of catalysts were proved to possibly have an oxidation-reduction acid site and NO oxidation activities similar to commercial catalysts. Based on the results above, if we have further change in the composition components and active ingredients according to the catalysts that were chosen in this investigation, then we are more welcomed to expect to have an enhanced DeNox catalyst for LNT.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.72.2-72.2
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• 2013

대기 환경의 오염에 크게 영향을 주는 자동차용 배기가스를 줄이기 위함과 강화되고 있는 배기가스 규제를 만족시키기 위한 최첨단의 기술을 개발하기 위하여 전세계 많은 연구진이 연구 개발을 진행하고 있는 상황에서, 가솔린 차량과 디젤차량분야 에서 배기가스 저감을위한 후처리 장치용 촉매 개발동향을 설명하고자 한다. 본 발표에서는 가솔린, 디젤 차량 적용 촉매의 기본 원리 및 규제 대응 신기술 개발 동향으로 TWC, DOC, DPF, SCR, LNT등의 기술과 후처리 시스템의 개발 동향을 설명한다.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.5
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• pp.179-189
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• 2008

The performance of Lean NOx Trap (LNT) based on the catalysts of Pt/K/Ba/$\gamma-Al_2O_3$ with proprietary washcoat formulation is studied using a bench flow reactor system. To investigate the effect of temperature and gas hourly space velocity (GHSV) on the nitrogen oxides (NOx) trapping capacity as well as NOx breakthrough time and final ratio of $NO_2$ to NO of LNT, series of adsorption isotherms are carried out with simulated exhaust gases of the lean burn engines. Since typical operation of LNT requires periodic regeneration with a short rich excursion, where the stored or trapped NOx is released and subsequently reduced to $N_2$, the effect of the duration of lean and rich phase and type of reductants on the NOx conversion is investigated. NOx storage capacity and breakthrough time obtained from adsorption isotherms shows a volcano-type dependence on the temperature with a maximum NOx storage capacity occurring $350^{\circ}C$ and with a maximum breakthrough time occurring $400^{\circ}C$ at all GHSVs investigated in this study. Also, maximum ratio of $NO_2$ to NO is obtained at $400^{\circ}C$ with a GHSV of $75,000\;hr^{-1}$ Lean/rich cycle of 100 s lean and 5 s rich used with a concentration of 1.33% of $H_2$ and 4% of CO in the rich phase is found to be optimum at operating temperature of $350^{\circ}C$ and a GHSV of $50,000\;hr^{-1}$.

• Journal of Radiation Protection and Research
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• v.23 no.3
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• pp.185-196
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• 1998

현재의 방사선방호 원칙과 체계는 국제방사선방호위원회 (ICRP)의 권고에 기반을 두고 있 다. ICRP 의 권고는 대부분 히로시마/나카사키 원폭피해 생존자들에 대한 역학조사 및 수명 연구결과 그리고 관련 방사선생물학 연구결과를 바탕으로 전세계 5개 인구집단(일본, 미국, 푸에리토리코, 영국과 중국)에 대한 방사선위험계수의 예측 및 평가결과에 근거를 두고 있다. 이 저선량 방사선의 (확률적 영향) 위험계수는 인체피폭 방사선량과 그 영향간에는 선형 비례관계가 있으며 영향유발의 문턱값이 존재하지 않는다는 가정인 '선형 무문턱값 선량-영향 모델 (Linear No-Threshold Dose-Effect Model, 이른바 LNT 모텔)' 을 도입하여 유도된 것이다(譯者 밑줄). 그러나 이 LNT 가정의 과학적 근거와 정당성에 대한 비난이 원자력산업계나 일부 과학자들에 의해 제기된 이래, 최근에는 미국 보건물리학회 (HPS)에서 'LNT 가정이 선량과 영향의 관계를 단순화하며 낮은 선량의 위험음 과대평가한다'는 성명서를 발표하기도 했다. 이후 이에 대한 논쟁이 다시 시작되어, 1997 년에 스페인의 Sevill에서는 IAEA와 WHO의 공동주최와 UNSCEAR의 협조로 '저준위 방사선 영향에 대한 국제회의'가 개최되기도 하였으나 아직 어느 쪽에도 유리한 결론이 단정적으로 나지 않았으며, 실질적인 대안이 없는 현실에서 이 LNT 가정은 여전히 방사선방호의 철학적 기초로 남아 있다(譯者 밑줄). 한편, 저선량 방사선의 영향에 대해서는 우리나라에서도 '방사선방어학회, ‘98 년 춘계 심포지움' 및 '원자력학회, '98 년 춘계 학술발표회 워크??????'에서 한양대학교의 이재기 교수에 의하여 소개, 논의된 바 있다.이 논문은 이러한 논의의 후속으로 역자중 일인이 위원으로 있는 OECD/NEA 방사선방호위원회 (CRPPH)가 최근에 ('98.7.) 발간한 보고서를 번역, 주해한 것으로, 과학지식의 진보에 따라 방사선방호분야에서 관심이 되는 주제들에 대한 위원회의 검토의견을 소개하고 있다. 따라서 이 논문이 국내의 방사선방호분야 관계자들에게 최신정보 습득과 지식함양에 좋은 도움이 되기를 기대한다.

• Transactions of the Korean Society of Automotive Engineers
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• v.19 no.1
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• pp.117-124
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• 2011

Automotive engines require strategies to fulfill the emission regulations in terms of NOx and PM. A dramatic reduction in NOx and PM emissions could be achieved with high pressure injection, innovative combustion strategies and EGR. Recently, Lean NOx Trap (LNT) and Urea-SCR are considered as more practical strategy to suppress the engine-out emissions substantially for copying with severe regulation. These systems need to reduce the reducing agent injection system which has a huge impact on NOx purification efficiency. In this paper, different three injectors have been used to investigate spray characteristics and engine emission test was conducted to clarify the effect of these injectors on the NOx reduction.

• Journal of ILASS-Korea
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• v.23 no.3
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• pp.136-148
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• 2018

Major countries have tighten their NOx regulation of diesel passenger cars. In the case of the EU, the regulation has been toughen up to 6.25 times since 2000. Despite the regulation the NOx concentration of the ambient has not been reduced proportionally. As these issues, to reduce NOx emission practically, Korea and the EU introduced the real-world driving emission (RDE) regulation and the test method that will be applied after 2017. In this paper, for the regulation to make a soft landing in Korea, 6 diesel passenger cars which met Euro 6a~6d regulation and were equipped with LNT/SCR were tested at a chassis dynamometer with environmental chamber applying the off-cycles (FTP, US06, SC03, HWFET and CADC) and several ambient conditions (-7 and $14^{\circ}C$) as well as certification modes (NEDC, WLTC@ $23^{\circ}C$). The result of the test showed that the ambient temp. and the engine load as a test mode impacted the NOx emission of the cars while the vehicles with SCR emitted NOx lower than with LNT. Additionally, to propose an effective RDE test method, the above result was compared with the results of the other papers which tested RDE using the same cars.