• Journal of Korean Society of Environmental Engineers
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• v.35 no.8
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• pp.540-546
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• 2013

The main purpose of the present study was to establish a quicker and cheaper model for predicting the LHV of MSW based on its wet physical composition being brought into C Incinerator. The one regression model was developed to correlate the energy content with variables from physical composition based on a wet matter. The performance of this model for MSW of the C Incinerator was superior to that of equations developed on a dry matter basis by other researchers for estimating energy content. The applicability of this model at the other 4 incinerators showed also an acceptable precision level.

• Korean Journal of Soil Science and Fertilizer
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• v.48 no.6
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• pp.697-704
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• 2015

This study was carried out to assess bioenergy conversion efficiency by biogas and solid fuel production in the cattle feedlot manure discharged from beef cattle barn. Feedlot manure was sampled from the cattle farmhouse located in Yong-in, Gyeonggi during the mid-fattening stage, periodically. The chemical characteristics, BMP (Biochemical methane potential) and HV (Heating values) of feedlot cattle manures were analyzed. Total solid contents of cattle feedlot manure were in the range of 29.98~44.28%, and volatile solid contents were in the range of 23.53~24.47%. In the anaerobic digestion of cattle feedlot manure, the methane production potential has increased from 0.141 to $0.187Nm^3kg^{-1}-VS_{added}$. The methane production of fresh cattle feedlot manure showed the range $0.141{\sim}0.187Nm^3kg^{-1}$-Manure (average $0.047Nm^3kg^{-1}$-Manure), the LHVs (lower heating values) of the produced methane were in the range of $316{\sim}560kcalkg^{-1}$-Manure (average $400kcalkg^{-1}$-Manure). In the direct combustion of fresh cattle feedlot manure, the LHVs were measured in the range of $747{\sim}1,271kcalkg^{-1}$-Manure (average $916kcalkg^{-1}$-Manure), and LHVs of solid fuel which have the water content of 20% were in the range of $2,694{\sim}2,876kcalkg^{-1}$-Manure (average $2,791kcalkg^{-1}$-Manure). Then, the drying energy of average $443kcalkg^{-1}$-Manure was consumed in the production of solid fuel which has a water content of 20%. Therefore, the direct combustion of cattle feedlot manure showed about 2.3 times higher LHV than the LHV of methane produced by anaerobic digestion. And LHV of solid fuel was about 6.0 times higher than the LHV of methane produced by anaerobic digestion. Then, the production of solid fuel presented more bioenergy conversion efficiency than the biogas production in the bioenergy use of cattle feedlot manure.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.2
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• pp.159-165
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• 1999

Experimental studies have been performed to observe the basic phenomena of waste bed combustion in MSW incinerator. A reduced scale apparatus was utilized to simulate the combustion behavior in real plant with 1-dimensional transient behavior at the experimental setup, which uses wet cubic wood with ash content as simulated waste. LHV (lower heating value) of solid fuel, fuel particle size and flow rate of combustion air were taken as important parameters of the bed combustion. For the quantitative analysis, FPR (flame propagation rate), TBT (total burn-out time) and PBT (particle burn-out time) was defined. LHV represent the capability of heat release of the fuel, so that a higher LHV results in faster reaction rate of the fuel bed, which is shown by higher FPR. Fuel particle size is related with surface area per unit mass as well as heat and mass transfer coefficient. As the particle size increases the FPR decreases owing to decreasing specific surface area. Air injection supplies oxygen to the reaction zone. However oversupply of combustion air increases convection cooling of the bed and possibly extinguishes the flame.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.7
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• pp.693-699
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• 2011

Internal combustion engines running on syngas, which can be obtained from biomass or organic wastes, are expected to be one of the suitable alternatives for power generation, because they are environment-friendly and do not contribute to the depletion of fossil fuels. However, syngas has variable compositions and a lower heating value than pure natural gas, owing to which the combustion conditions need to be adjusted in order to achieve stable combustion. In this study, a gas that has the same characteristics as syngas, such as low heating value (LHV), was produced by mixing $N_2$ with compressed natural gas (CNG). In addition, this study investigates the combustion characteristics of syngas when it is mixed with hydrogen in a ratio ranging from 10% to 30% with a constant LHV of total gas.

• Journal of The Korean Society of Agricultural Engineers
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• v.59 no.5
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• pp.17-23
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• 2017

In South Korea, 25 % of annual agricultural residues (11.64 million tons) are unused. The hydrophilicity, low lower heating value (LHV), and low energy density of agricultural residues can be obstacles for efficient usage. Torrefaction, a low temperature pyrolysis process, can be a solution to overcome these disadvantage of agricultural residues. In this study, agricultural residues such as bean stem, pepper stem, perilla stem, sorghum stem, acorn shell, and ginkgo shell are torrefied at 200, 230, and $250^{\circ}C$ and evaluated energy properties, respectively. The torrefaction can increase the LHV and energy density rate of agricultural residues from 3,331~4,444 kcal/kg to 4,166~5,830 kcal/kg and 20~30 %, respectively.

• Journal of the Korean Applied Science and Technology
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• v.34 no.2
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• pp.327-337
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• 2017

A continuous low temperature ($510^{\circ}C{\sim}530^{\circ}C$) pyrolysis experiment in a pilot-scale of 85.3 kg/hr was carried out by the mixed feedstock of half dried digested sewage sludge and waste plastics. As a result, the amount of pyrolysis gas generated was maximum 68.3% of input dry mass and scored $40.9MJ/Nm^3$ of lower heating value (LHV), and the percentage of air inflow caused by continuous pyrolysis was 19.6%. The oil was produced 4.2% of the input dry mass, and the LHV was 32.5 MJ/kg. The sulfur and chlorine contents, which could cause corrosion of the facility, were found to be 0.2% or more respectively. The carbide generated was 27.5% of the input dry mass which shows LHV of 10.2 MJ/kg, and did not fall under designated waste from the elution test. The concentration of carbon monoxide, sulfur oxides and hydrogen cyanide of emitted flu gas from pyrolysis gas combustion was especially high, and dioxin (PCDDs/DFs) was within the legal standards as $0.034ng-TEQ/Sm^3$. Among the 47 water pollutant contents of waste water generated from dry flue gas condensation, several contents such as total nitrogen, n-H extract and cyanide showed high concentration. Therefore, the merge treatment in the sewage treatment plants after pre-treatment could be considered.

• Resources Recycling
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• v.19 no.2
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• pp.45-53
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• 2010

During the biomass gasification, tar generation is typically accompanied, which causes many problems, such as pipe plugging and equipment fouling. In the experiments, activated carbon was applied to the upper reactor of the two-stage gasifier in order to remove the tar generated during gasification. In addition, the effects of the upper-reactor temperature and equivalence ratio on the producer gas characteristics (composition, tar content and lower heating value) were investigated. To investigate the effect of the upper reactor-temperature, experiments were performed at 743, 793, $838^{\circ}C$, respectively. To examine the influence of the equivalence ratio, a comparison experiment was carried out at a equivalence ratio of 0.17. In all experiments, tar contents in the producer gases were below $2mg/Nm^3$. The maximum LHV of the producer gas was above $10MJ/Nm^3$, which is much higher than the typical LHV($3\sim6MJ/Nm^3$) in the air gasification of biomass.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.123.2-123.2
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• 2010

Fuel Cell cogeneration system is a promising technology for generating electricity and heat with high efficiency of low pollutant emission. We have been developed 5kW class fuel cell cogeneration system for commercial and residential application. The fuel processor is a crucial part of producing hydrogen from the fossil fuels such as LNG and LPG. The 5kW class high efficiency fuel processor consists of steam reformer, CO shift converter, CO preferential oxidation(PrOx) reactor, burner and heat exchanger. The one-stage CO shift converter process using a metal oxide catalyst was adopted. The efficiency of 5 kW class fuel processor shows 75% based on LHV. In addition, for the purpose of continuous operation with load fluctuations in the commercial system for residential use, load change of fuel processor was tested. Efficiency of 30%, 50%, 70% and 100% load shows 75%, 75%, 73% and 72%(LHV), respectively. Also, during the load change conditions, the product gas composition was stable and the outlet CO concentration was below 5 ppm. The Fuel processor operation was carried out in residential fuel cell cogeneration system with fuel cell stack under dynamic conditions. The 5kW class fuel processor have been evaluated for long-term durability and reliability test including with improvement in optimal operation logic.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.231-234
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• 2005

수소 기반의 에너지 사회는 중소규모 분산 발전과 연료 전지 자동차에서 시작될 거라는 예측이 지배적이다. 가정용 고분자 연료전지 시스템은 상업화에 가장 가까운 소규모 분산 발전 시스템중의 하나이며, 에너지기술연구위원에서는 가정용 고분자 연료전지에 수소를 공급하기 위한 천연가스 수증기 개질시스템의 개발을 진행해 왔다. 효율 향상과 제작의 용이성, 그리고 소형화에 초점을 맞추어 개발된 prototype-I은 $2.0Nm^3/hr$의 순수 수소 생산 용량을 가지고 있으며, 수증기 개질기와 수성가스 전이 반응기 수중기 생성 장치, 그리고 반응열 공급에 필요한 버너 등을 이중 동심원관에 통합한 형태이다. 수중기 개질과 수성가스 전이 반응을 거쳐 나오는 개질 가스의 조성은 $72.3\%\;H_2,\;4.8\%\;CH_4,\;0.7\%\;CO,\;22.2\%\;CO_2$이며, 이때 S/C 비율은 2.5였다. 고분자 연료 전지 공급 시 요구되는 CO 농도가 10ppm 이하이기 때문에, 본 시스템에는 선택적 산화 반응기를 2단으로 설치하여 CO. 농도를 10ppm 이하로 낮추어주었다. 전체 시스템의 열효율은 LHV 기준으로 $68\%$. Prototype-I의 운전을 통해 설계 개선안을 도출하였으며, 이를 적용해 제작한 prototype-II가 시험 운전 중이다,. 통합된 개질 시스템에서는 각 단위 반응기사이의 열교환을 최적화하여 단위 반응들이 적정 온도 범위에서 일어나도록 유도하는 것이 중요하다. Prototype-II는 수증기 개질 반응기와 WGS 반응기, 수증기 생성 장치 사이의 열교환율을 향상시켜 농도를 $2.5\%$로 감소시키면서 CO의 농도는 $1\%$이하로 유지하였다. 이 결과를 바탕으로 얻어진 메탄 전환율은 $87\%$이고, 열효율은 LHV 기준으로 $75\%$이다. 아울러 개선점을 적용한 선택적 산화 반응기를 제작하였다. 개질 가스와 산소의 혼합을 유도하고, 반응기 온도의 제어를 통해 선택적 산화 반응의 속도와 선택성을 향상시키고자 한다. 시스템의 운전을 통해 메탄 전환율과 열효율의 개선을 진행할 예정이다.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.323-327
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• 2009

To extract hydrogen for stack, fuels such as LPG and LNG were reformed in the fuel processor, which is comprised of desulfurizer, reformer, shift converter, CO remover and steam generator. All elements of fuel processor are integrated in a single package. Highly active catalysts (desulfurizing adsorbent, reforming catalyst, CO shift catalyst, CO removal catalyst) and the various burners were developed and evaluated in this study. The performance of the developed catalysts and the commercial ones was similar. 1 kW, 5 kW class fuel processor systems using the developed catalyst and burner showed efficiency of 75 %(LHV, for LNG). The start-up time of the 1 kW class fuel processor was less than 50 minutes and its volume including insulation was about 30 l. The start-up time of 3 kW and 5 kW class fuel processors with the volume of 90 l and 150 l, respectively, was about 60 minutes. In the case of LPG fuel, efficiency, volume and start-up time of 1kW class fuel processor showed 73 %(LHV), < 60 l and < 60 min, respectively. Advanced fuel processor showed more highly efficiency and shorter start-up time due to the improvement of heat exchanger and operating method. 1 kW and 3 kW class fuel processors have been evaluated for reliability and durability including with on/off test of developed catalysts and burner.