• 펄프종이기술
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• 제29권2호
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• pp.83-90
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• 1997

An unbleached hardwood kraft pulp was bleached in vitro with partially purified manganese peroxidase (MnP) from the fungus Phanerochaete sordida YK-624 without the addition of MnSO$_4$ in the presence of oxalate, malonate or gluconate known as manganese chelator, When the pulp was treated without the addition of MnSO$_4$, the pulp brightness increased by about 10 points in the presence of 2 mM oxalate, but the brightness did not significantly increase in the presence of 50 mM malonate. Residual MnP activity decreased faster during the bleaching with MnP without MnSO$_4$ in the presence of malonate than in the presence of oxalate. Oxalate reduced MnO$_2$ which already existed in the pulp or was produced from $Mn^{2+}$ by oxidation with MnP and thus supplied $Mn^{2+}$ to the MnP system. Thus, bleaching of hardwood kraft pulp with MnP, using manganese originally existing in the pulp, became possible in the presence of oxalate, a good manganese chelator and reducing reagent. Properties of partially purified MnPs from liquid cultures of white rot fungi, Ganoderma sp. YK-505, Phanerochaete sordida YK-624 and Phanerochaete chrysosporium were compared. MnP from Ganoderma sp. YK-505 was superior to MnPs from P. sordida YK-624 and P. chrysosporium in stabilities against high temperature and high concentration of $H_2O$$_2$. The MnP from Ganoderma sp. YK-505 differed in pH-activity profile from other MnPs. These data suggest that MnP from Ganoderma sp. YK-505 has different structure from those of other fungi. Bleaching of hardwood kraft pulp using the MnP from ganoderma sp. YK-505 is now in progress.

• 펄프종이기술
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• 제39권4호
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• pp.45-52
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• 2007

Whole, bast and core fibers of kenaf cultivar Tainung-2 were pulped under different pulping methods, thermomechanical and kraft pulping methods. The physical and optical properties of kenaf TMP(thermomechanical pulp) and KP(kraft pulp) handsheets were investigated and the results from the study are summarized as follows: Yields of TMP and KP were $77{\sim}87%\;and\;43{\sim}52%$, respectively. There was no significant change in apparent density between kenaf KP and USKP(unbleached softwood kraft pulp) but TMP showed a little lower apparent density. Bast pulp had the lowest apparent density regardless of pulping methods. Tensile strength of kenaf KP was higher than that of TMP but similar to that of USKP. Both TMP and KP handsheets of bast fraction showed the highest tear strengths among whole, bast, and core fractions. Core fraction showed the lowest tear strengths under different pulping methods. In general burst strength of kenaf pulp under different pulping methods was lower than that of USKP, and kenaf pulp had better stiffness than USKP. Brightness of kenaf KP and TMP was higher than that of USKP. There was no significant variation in opacity between kenaf pulp and USKP even though kenaf pulp showed a little lower opacity. The main difference in paper quality between the core fiber and bast fiber is derived from the fact that bast fiber is long and thin, whereas core fiber is short and thick.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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• pp.395-400
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• 2006

Polylactic acids polymer (PLA) was applied as an additive to improve the strength properties of handsheets prepared from three unbleached southern pine kraft pulps with different kappa number and an aspen bleached chemithermomechanical pulp (BCTMP). The results showed that PLA could greatly improve the tensile and burst strength of the pulp handsheets. Heat pressing effect was also important to enhance the strength properties. For unbleached kraft pulps, it was found that an appropriate amount of residual lignin in pulps had a positive effect on the handsheets strength improvement when adding PLA. The thickness of the handsheet did not change the PLA strengthening effect. In general, PLA effect on tear strength improvement could be neglected. However, it had a significant effect on the improvement of tear strength for the aspen BCTMP handsheets not containing sufficient amount of fines.

• Journal of the Korean Wood Science and Technology
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• 제29권4호
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• pp.103-110
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• 2001

목재 내 리그닌의 선택적 분해 특성을 지닌 백색부후균 중, Phanerochaete chrysosporium KCCM 34740 균주를 현사시나무 목재 칩에 전처리하여 bio-kraft pulping 적용 가능성을 실험적으로 평가하였다. 전처리 결과, 무처리 대조구에 비해 펄프의 정선수율은 전처리 10일에서 최고 약 2%의 증가를 보였으며, 전처리 기간의 증가에 따라 여수도의 감소, WRV의 증가 경향을 나타냈다. 또한 수초지의 물성 개선에도 효과가 있었으며, 주사전자현미경 관찰을 통하여 이러한 효과가 백색부후균의 생물고해 작용, 즉 펄프 섬유의 미세섬유화 및 다공질화에 기인한 것임을 확인할 수 있었다. 이러한 결과로써 향후 kraft 증해 약액 및 제지공정상의 고해 동력에너지의 소비를 절감할 수 있을 것으로 기대한다.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2010년도 춘계학술발표회 논문집
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• pp.195-206
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• 2010

Xylan can be applied to improve the strength properties of paper; however the optical properties, such as brightness, are decreased significantly. To solve that problem, an applicable bleaching process is therefore desired. The aim of this research was to investigate the impact of hydrogen peroxide bleaching on hardwood kraft pulp pretreated with birchwood xylan by measuring optical properties (whiteness, brightness, opacity) as well as physical properties (tensile index, tearing index, bulk) of handsheets made from the bleached pulp. Hydrogen peroxide bleaching, as a kind of totally chlorine free (TCF) bleaching method, is quite important industrially for chemical pulp. In our work, the process variables of peroxide bleaching including bleaching temperature, time, initial pH and $MgSO_4$ dosage were studied. The results showed that both good mechanical properties and optical properties could be achieved when the operating parameters were controlled properly and therefore hydrogen peroxide bleaching was proved to be a suitable method for bleaching hardwood kraft pulp with adsorption of birchwood xylan.

• 펄프종이기술
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• 제43권3호
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• pp.106-112
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• 2011

The effects of alkaline treatment on the WRV, crystalline structure and sheet structure of softwood and hardwood bleached kraft pulp were investigated. Sodium hydroxide and sodium carbonate were used as chemicals for alkaline treatment and two levels of alkali dosage (5%, 10%) were applied respectively. Alkali treated and untreated pulp were refined to three levels (550, 450 and 350 mL CSF). WRV of the alkali treated pulps depended on the alkaline type and concentration. It was found that the crystalline structures of softwood and hardwood pulp were not changed by refining. Sodium carbonate and lower concentration of sodium hydroxide treatment did not caused any modification of cellulose crystalline structure, while higher concentration of sodium hydroxide treatment caused the partial modification of cellulose crystalline structure. Alkaline treatment of hardwood bleached kraft pulp led to the shrinkage of fiber diameter and bulky structure of sheet. Alkaline treatment of softwood bleached kraft pulp did not cause the significant change in fiber shrinkage and bulk of sheet.

• Journal of the Korean Wood Science and Technology
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• 제18권2호
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• pp.25-35
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• 1990

To investigate the effects of swelling treatment by ammonia on characteristics of carboxymethy1cellulose(CMC) and CMC solution, the domestic kraft pulp pretreated with 5%, 10%, 15% and 20% $NH_4OH$ solution, was carboxymethylated by the standard method, and then the CMC prepared was tested. The physical properties of CMC and CMC solution, such as degree of substitution, transparency. viscosity, weight increase and solubility, were measured, and the comparison with commercial domestic CMC used as a food additive was done. The results obtained were as follows; 1. In CMC manufactured by standard solvent method, hardwood bleached kraft pulp(LBKP) was more substituted than safwood bleached kraft pulp(NBKP), and viscosity of NBKP was higher than that of LBKP. 2. When ammonia swelling treatment was done, degree of substitution gradually decreased with increasing concentration of $NH_4OH$, and degree of substitution of LBKP decreased with a larger range than that of NBKP. 3. When ammonia swelling treatment was done. transparency of CMC solution from LBKP was hardly effected, but in case of NBKP gradually increased with increasing concentration of $NH_4OH$. 4. When ammonia swelling treatment was done, viscosity of CMC solution was higher than that of CMC solution without ammonia swelling treatment. Especially, CMC of high viscosity could be manufactured in 5%, 10% concentration levels of $NH_4OH$. 5. In CMC manufactured from domestic NBKP, CMC at the range of 0.40 to 0.50 in DS was dispersed easily and quickly dissolved, and CMC at more than 0.50 in DS was dispersed slowly in water solution. 6. In comparison with commercial domestic CMC used as a food additive, CMC manufactured from domestic NBKP was higher in DS, and was lower in viscosity and transparency.

• Journal of the Korean Wood Science and Technology
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• 제20권3호
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• pp.67-78
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• 1992

The application of white-rot fungi to pulping and bleaching processes has been studied at the Wood Chemistry Laboratory in Kyushu University, cooperatively with the Biotechnology Laboratory of Kobe Steel, Ltd. Some successful results of the studies for a biomechanical pulping process, biobleaching of hardwood and softwood kraft pulp, as well as chlorine free biobleaching of oxygen-prebleached hardwood kraft pulp are dealt with. Biological treatment of the pulp bleaching effluent is also described.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2000년도 춘계학술발표논문집
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• pp.39-46
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• 2000

In pulp and papermaking process, enzymatic treatment of pulp fibres has been a topic of increasing interest in last decade. Lots of patents, papers and research reports were published on the application of enzymes in the fields of enzymatic bleaching, deinking, slime control, pitch control, waste water treatment and fibre modification. Cellulase and hemicellulase are the principal enzymes used for the modification of fibre property. This study was carried out for determinating the behaviors of enzyme to pulp fibres. A commercial enzyme, Denimax BT which is consisted with cellulase and hemicellulase, was treated to the kraft pulp produced from domestic hardwood mixtures. Results were mainly concentrated on the behaviors of freeness, drainability and fines content of fibres, and physical properties of paper with enzyme treatment. The freeness levels and dewatering ability were developed, and the fines contents were decreased. The creation of fines were controlled by the method of pre-enzyme treatment prior to fibre beating. The mechanical strength of paper, like tensile, burst, tear strength and folding endurance, were remarkably improved by the pre-enzyme treatment.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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• pp.331-336
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• 2006

The aim of this work was to inhibit the heat-and moisture-induced yellowing of ECF/TCF bleached hard wood kraft pulp (HBKP) retaining hexenuronic acid (HexA). We have already reported that one of the derivatives of HexA, 5-formyl-2-furancarboxylic acid (FFA), causes yellowing of HBKP in acidic paper, and that FFA might polymerize or react with pulp components to form new chromophoric groups (1). In this study, it was shown that the carboxylic base of FFA interacts with that of glucuronic acid or galacturonic acid, resulting in strong yellowing. Therefore, it seems that preventing the reaction of carboxylic bases could be effective in suppressing this yellowing. We have discovered that polycarboxylic acids (for example, citric acid, tartaric acid, etc.) are useful as a yellowing inhibitor.