• 한국신재생에너지학회:학술대회논문집
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• 2008.10a
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• pp.220-222
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• 2008

가스하이드레이트는 물분자들의 수소결합에 의하여 입체 그물구조를 만들게 되면 그 그물구조의 공동(Cavity) 내에 크기가 작은 가스 분자들이 포획되면서 형성되는 결정체이다. 이러한 원리로 포획되어질 수 있는 가스는 130여종에 이른다. 포획가능한 가스 분자들 중 $SF_6$의 경우 보다 쉬운 조건에서 하이드레이트 형성이 되는 점을 이용하여 $SF_6$의 분리 회수에 하이드레이트의 형성 원리를 적용하고자 하였다. 이를 위하여 본 연구에서는 압력조건과 조성변화를 달리하여 $SF_6$ 하이드레이트 형성 특성을 관찰하였다. 본 연구에서 하이드레이트 결정 형성 특성 및 형성 속도에 대한 실험과 분석을 통한 결과를 확보함으로써 향후 $SF_6$ 하이드레이트의 생산, 저장, 회수, 분리 등의 설계의 기본자료로 사용될 수 있을 것으로 사료된다.

• Proceedings of the KIEE Conference
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• 2001.07e
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• pp.72-75
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• 2001

In this paper, we describe the results of a combined experimental theoretical study designed to understand and predict the dielectric properties of $SF_6$ and $SF_6+Ar$ mixtures. The electron transport, ionization, and attachment coefficients for pure $SF_6$ and gas mixtures containing $SF_6$ has been analysed over the E/N range $30{\sim}300Td$ by a two term Boltzrnann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2% and 0.5% $SF_6+Ar$ mixtures were measured by time- of- flight method, The results show that the deduced electron drift velocities, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients and mean energy agree reasonably well with the experimental and theoretical for a rang of E/N values.

• 전기의세계
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• v.29 no.6
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• pp.344-348
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• 1980

$SF_{6}$가스의 절연파괴특성 및 화학적특성에 관한 것을 종합해보면, 첫째, $SF_{6}$의 방전은 1개의 전자 avalanche중의 전자수가 임계치 Norit가 $10^{8}$정도에서 streamer에의 전이가 일어나므로서 이루어지며, 둘째, $SF_{6}$의 (.alpha.-.eta.)/.rho.와 E/.rho.의 관계는 .alpha.=.eta.근방에서 직선으로 상승되어 절연파괴에 극히 중요한 뜻을 가지며, 셋째, 두번째의 .alpha.=.eta.에 있어서의 구배는 보통의 기체보다 수 10배크기 때문에 최대전계를 부여하는 전극근방만이 공극의 방전개시를 지배하며, 넷째, 전기기구에 있어서 $SF_{6}$가스의 화학적변화의 energy원으로서는 arc, corona, 열을 들 수 있으며 특히 $SF_{6}$가스중과 공기중과의 내 Corona성을 구하기 위한 인가전압일내 Corona수명시간은 $SF_{6}$가스중이 공기중보다 길다는 것이다.

• Proceedings of the KIEE Conference
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• 2004.11a
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• pp.129-132
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• 2004

This paper presents an experimental study on the prebreakdown characteristics in $SF_6/N_2$ mixtures under non-uniform electric fields when subjected to the positive and negative lightning impulse voltages. $SF_6/N_2$ mixtures have a merit of an environmental aspect and cost reduction, and safty aspects. In order to analyze the prebreakdown processes in $SF_6/N_2$ mixtures stressed by impulse voltages, prebreakdown current and light were observed by a shunt with high sensitivity and a photo-multiplier tube, respectively. Additionally, characteristics of luminous events in flashovers were discussed.

• International Journal of Industrial Entomology and Biomaterials
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• v.45 no.1
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• pp.12-16
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• 2022

Di-tyrosine photo-crosslinking of silk fibroin (SF) is recently highlighted as a biocompatible hydrogel fabrication process, because this method does not need potentially harmful chemical species. However, the resulting crosslinking density is often insufficient to obtain a mechanically stiff hydrogel unless additional oxygen is provided during the reaction. In this study, we proposed a combinational crosslinking method to form an SF hydrogel via the di-tyrosine photo-crosslinking with riboflavin (photoinitiator) and physical interaction of SF chains. In the UV light-irradiated SF solution, small particles formed and these particles promoted β-sheet formation of SF molecules, resulting in quick gelation. The di-tyrosine photo-crosslinking produced nuclei that might trigger regular assembly of SF molecules in high temperature condition. Conclusively, this process would contribute to a development of biocompatible hydrogel fabrication for biomedical uses of SF hydrogels.

• Journal of the Korean Society of Food Culture
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• v.27 no.1
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• pp.66-74
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• 2012

It is well known that sunflower (SF) sprout has more beneficial effects than SF seed due to increased levels of phytochemical components such as vitamins, total phenolics, and isoflavones during germination. This study investigated the physicochemical properties and antioxidative activities of SF seed during both germination and cultivation. In a proximate analysis, the water content of SF groat was 9.17% and then increased to 15.32% on the 11th day after seeding. On a dry weight basis, crude fat content decreased while the contents of carbohydrates, crude protein, and crude ash increased. As cultivation proceeded, the contents of minerals were in decreasing order of K, Mg, Ca, Na, Zn, Fe, Mn, and Cu, in which SF sprout cultivated for 9 or 11 days contained the highest mineral contents. Though vitamin C was not detected on SF groat, the content of vitamin C continuously increased up to the 5th day of cultivation and then decreased gradually. Vitamin E content in SF groat was higher than that in SF sprout. It was also found that the vitamin E content in SF sprout was the highest on the 5th day of cultivation. Daidzin was not detected in SF groat, but its concentration reached a maximum on the 5th day of cultivation in SF sprouts. Furthermore, higher amounts of daidzein were observed on the 3rd, 5th, and 9th days of cultivation. The highest total isoflavone content was observed on either the 3rd or 5th day of cultivation. The highest content of total phenolics was observed on the 5th of cultivation. When DPPH radical and peroxyl radical scavenging activities of SF sprout were measured in order to measure antioxidant efficacy, it was found that 5 day-cultivated SF sprout had the highest scavenging activities. In conclusion, SF sprout cultivated for 9 or 11 days was found to be a good source of minerals. Furthermore, the fifth-day after seeding was the optimal time for the production of SF sprout with effective natural antioxidant activity and high amounts of functional components such as vitamins, total phenolics, and isoflavones.

• Journal of Korean Society for Atmospheric Environment
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• v.28 no.4
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• pp.446-453
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• 2012

Destruction and removal efficiency (DRE) of $SF_6$ was tested with varying degrees of ionization and initial concentrations of $SF_6$. The applied dose of ionization energy varied from 0 to 400 kGy. The initial concentration of $SF_6$ gas also varied from 1,000 ppm to 2,500 ppm. In order to assess the effect of a residence time on DRE (Destruction and Removal Efficiency, %), experiments were also conducted at different irradiation times of 3, 5, 10, 15, and 20 sec, respectively. The DRE of $SF_6$ increased with an increasing amount of dose and current. Regardless of initial concentration of $SF_6$, 90% level of DRE was achieved by applying over 10 mA of electrical current.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2005.05a
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• pp.57-60
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• 2005

This paper describes the experimental results of the pre-breakdown phenomena in $SF_6/CO_2$ mixtures under non-uniform electric fields caused by positive and negative lightning negative voltages. $SF_6/CO_2$ mixtures have an advantage of an environmental aspect and cost reduction, and safety aspects. In order to analyze the pre-breakdown processes in $SF_6/CO_2$ mixtures stressed by impulse voltages, pre-breakdown current and luminous signals were measured by a shunt and a photo-multiplier tube, respectively. Dielectric strengthes of $SF_6/CO_2$ mixtures were investigated. Additionally, characteristics of discharge channels were observed by high speed cameras and the physical properties were discussed. The pre-breakdown propagates with a stepwise process. The in to breakdown from the corona onset point in positive polarity was shorter than that in negative polarity. The time intervals of positive leaders are shorter than those of negative leaders, and the path of positive leader channel is zigzag.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2004.11a
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• pp.237-240
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• 2004

Sulfur Hexafluoride, SF6 is widely used for leak detection and as a gaseous dielectric in transformers, condensers and circuit breakers. SF6 gas is also effective as a cleanser in the semiconductor industry. This paper presents a numerical study of the sealing force of disk type seal in SF6 gas safety valve. The sealing force on the disk seal is analyzed by the FEM method based on the Taguch's experimental design technique. Disk seals in SF6 gas safety valve are designed with 9 design models based on 3 different contact length, compressive ratio and gas pressure. The calculated results of Cauchy stress and strain showed that the sealing characteristics of Teflon PTFE is more effective compared to that of FKM(Viton), which is related to the stiffness of the materials. And also, the contact length of the disk seal is important design parameter for sealing the SF6 gas leakage in the safety valve.

• The Transactions of the Korean Institute of Electrical Engineers
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• v.36 no.11
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• pp.796-805
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• 1987

The flashover voltages have been investigated for spacer and unbridged-gap in SF6-N2 gas mixtures up to the value of 760(torr. cm), The gap was stressed by DC source The results obtained are as follows` 1) The flashover voltages for an unbridged gap and for a spacer in SF6, N2 and SF6-N2 gas mixtures follow the Paschen's curve. 2) The polarity effects was not observed in both unbridged gap and a spacer which had per ect contact with an electrode. The flashover voltages for negative polatity are lower than those for positive polarity in case of imperfect contact. 3) 3%flashover voltage is decreased by putting a spacer which had perfect contact with an electrode. The spacer which has a gap void shows the lowest flashover voltage. 4) The lowest spacer efficiency was obtained with higher gas pressure & large amount of N2 content. The flashover voltages depend on the gas pressure rather than the spacer efficienty at low value of pd. 5) The flashover voltages of gas mixtures of N2 with SF6 are relatively high, even though the amount of SF6 gas content is small.