• Proceedings of the Korean Environmental Sciences Society Conference
• /
• 1997.04a
• /
• pp.68-70
• /
• 1997

• Korean Chemical Engineering Research
• /
• v.48 no.1
• /
• pp.58-67
• /
• 2010

Combustion of the Korean Anthracite and wood-pellet was characterized in air atmosphere with variation of heating rate(5, 10, 20 and $30^{\circ}C/min$) in TGA. The results of TGA have shown that the combustion of the wood-pellet occurred in the temperature range of $200{\sim}620^{\circ}C$ which is much lower than that of Korean anthracite. Activation energies of the wood-pellet and Korean anthracite, determined by using Friedman method were 44.12, 21.45 kcal/mol respectively. Also, their reaction orders(n) and pre-exponential factors(A) were 5.153, 0.7453 and $4.01{\times}10^{16}$, $1.39{\times}10^6(s^{-1})$ respectively. In order to find out the combustion mechanism of the wood-pellet and Korean anthracite, twelve solidstate mechanisms defined by Coats Redfern Method were tested. The solid state combustion mechanisms of the woodpellet and Korean anthracite were found to be sigmoidal curve A3 type and a deceleration curve F1 type respectively. Also, from iso-thermal combustion($300{\sim}900^{\circ}C$) of their char, the combustion characteristics of their char was found. Activation energies of the their char were 27.5, 51.2 kcal/mol respectively. Also, pre-exponential factors(A) were $2.55{\times}10^{12}$, $1.49{\times}10^{10}(s^{-1})$ respectively. Due to the high combustion reactivity of wood-pellet compared with Korean anthracite, combustion atmosphere will be improved by co-combustion with Korean anthracite and wood-pellet.

• Korean Journal of Soil Science and Fertilizer
• /
• v.28 no.4
• /
• pp.334-339
• /
• 1995

To investigate the utilization of fly ash in agriculture, sorghum [Sorghum bicolor(L.) Moench] was used as the test crop. Soil was treated in pot experiments with anthracite and bituminous fly ash at 5 levels of 0, 6, 12, 18, and 24%, respectively. Growth status in terms of plant height and the number of nodes was improved in the order of bituminous treatment > anthracite treatment > control. The increment of fly ash had a positive effects on plant growth in both anthracite and bituminous treatment. The ratio of the senescent leaves to the all leaves during the maturing period was higher in fly ash treatments than in the control. As increasing the fly ash treatment, the ratio of senescent leaves was increased. Total yield was higher in the order of bituminous treatment > anthracite treatment > control. Grain yield also was higher in fly ash treatment than in the control. Bituminous fly ash treatments were more favourable in grain yield than anthracite. The increment of up to 12% fly ash to soil increased grain yield in both anthracite and bituminous. Application of bituminous fly ash could be recommended due to the fact that high pH of soil is favorable for growth of sorghum.

• Journal of Korean Society for Atmospheric Environment
• /
• v.23 no.4
• /
• pp.440-448
• /
• 2007

Although the anthracite power plant is an important source of greenhouse gas, research on this type of power plant has not been conducted much. The present study investigated the entire anthracite power plants in Korea and analyzed the emitted gas in connection with GC/FD and a methanizer in order to develop $CO_2$ emission factors. The study also sampled the anthracite to analyze the amount of carbon and hydrogen using an element analyzer, and to measure the calorie using an automatic calorie analyzer. The emission factors computed through the fuel analysis was 30.45 kg/GJ and that computed through the $CO_2$ gas analysis was 26.48 kg/GJ. The former is approximately about 15% higher than the latter. When compared the carbon content factors of anthracite with that of bituminous coal, the value of anthracite was 24% higher Compared with IPCC values, the emission factors by the fuel was 14% higher, and that by the emitted $CO_2$ gas was about 1.2% lower. More research is needed on our own emission factors of various energy-consuming facilities in order to stand on a higher position in international negotiations regarding the treaties on climate changes.

• Resources Recycling
• /
• v.13 no.2
• /
• pp.16-23
• /
• 2004

To increase the recycling rate of anthracite fly ash, the properties of anthracite fly ash were compared to that of bituminous fly ash. Especially, the high temperature properties of the fly ash are investigated by using thermal analysis, high temperature microscope and X-ray diffraction analysis for utilizing anthracite fly ash to prepare the calcinated bricks. The average ratio of $A1_2$$O_3$/$SiO_2$ for anthracite is 0.62 and the ratio for bituminous is 0.34. The content of $SiO_2$ in anthracite fly ash was higher than that of bituminous fly ash. The $A1_2$$O_3$ of anthracite fly ash reacted with the $A1_2$$O_3$ in the fly ash and formed new mullite crystal at over $1000^{\circ}C$, so anthracite fly ash showed high fire resistance. And, the fly ash mixtures having kaolin were prepared, and then extruded in vacuum to evaluate the extruding property of anthracite fly ash mixture. The extruding velocity was decrease with increasing the addition amount of fly ash in the mixture, and the maximum addition amount of fly ash that could be extruded was 60 wt%.

• Journal of the Korean Chemical Society
• /
• v.6 no.1
• /
• pp.47-53
• /
• 1962

The "reactivity" of coal is one of the important characteristics of a coal used as a process raw material as well as a fuel. In this study, the reactivity was measured in terms of the magnitude of the reaction rate constant in the reduction of carbon dioxide with coal. A reactivity-testing apparatus was designed and constructed, and its performance characteristics were investigated by using Korean anthracite and hard-wood charcoal. Experiments were carried out at temperatures ranging from 750 to 1100$^{\circ}C$ with pulverized Korean anthracite whose sizes range from 1 to 10mm in diameter. Results showed that the reaction rate constant was not appreciably affected by the particle size investigated, and the reactivities of the anthracite and the charcoal were found to be a function of reaction temperature alone. It was also found that a straight line was produced when the logarithm of the rate constant is plotted against the reciprocal of the absolute temperature. The reactivities of the charcoal were found to be 2 to 10 times higher than those of the anthracite at a temperature ranging from 750 to 1100$^{\circ}C$, and 90% of carbon dioxide was reduced to carbon monoxide by the anthracite at a temperature above 1050$^{\circ}C$.

• Journal of the Korean Chemical Society
• /
• v.7 no.2
• /
• pp.182-185
• /
• 1963

In the previous paper of the series of researches on the graphitic properties of anthracites, authors have already reported the results on the electrical specific resistance measurements for Korean anthracites in order to develope a simple methods which differentiate graphite from anthracite. In this paper, the X-ray diffraction method and oxidation have been applied and compared with the results which were obtained by the specific resistance measurements in the previous paper. It has been confirmed that there is a parallel relation between the value of specific resistance measurement and height of hexagonal peak by X-ray diffraction, but the color reaction due to graphitic acid by oxidation does not show any definite critical points between graphite and anthracite.

• Journal of the Korean Society of Safety
• /
• v.11 no.2
• /
• pp.96-101
• /
• 1996

The effects of coal type and mixing fraction of coal on attrition and elutriation were studied in a 15. 5cm diameter fluidized bed coal combustor. The domestic low-grade anthracite coal with heating value 2010kcal/kg and the imported bituminous coal from Australia with heating value of 6520kcal/kg were used as coal sample. It was found from the experimental that the elutriation rate inclosed with an increseing anthracite mixing fraction. The size of elutriated particle had a very wide distribution was found in this experiment. The mean size of elutriated particle increased with decreaseing anthracite mixing fraction.

• Journal of Korean Society of Water and Wastewater
• /
• v.21 no.6
• /
• pp.763-770
• /
• 2007

There are many design parameters affecting filtration efficiency such as filteration rate, media packing depth, size distribution, and so on. The sphericity, the ratio of the surface area of an equal volume sphere to the real surface area of the particles, is one of major physical characters of media. The effect of sphericity on the performance of anthracite filter has been investigated. Media from eight water treatment plants have been collected. The sphericity of each media has been calculated by using well known headloss equations such as Kozeny equation, Dahmarajah equation etc.. Columns packed with anthracite media having different sphericity have been used to compare headloss development, floc accumulation in the bed, particles in bed water, filtrate turbidities after backwash and so on. The repeated experiments have indicated that the sphericity of anthracite media may not have remarkable influence on the filter performance as it has been suspected. It also has been prospected in the experiment that the media of higher sphericity would store more particles in the bed and give better filtrate quality, if provided that the effective size and the size distribution of media would be the same.

• Journal of the Korean Society of Combustion
• /
• v.9 no.2
• /
• pp.30-37
• /
• 2004

Coal combustion in an iron ore sintering bed is a key parameter that determines quality of the sintered ores and productivity of the process. In this study, effects of the different types of coal - coke and anthracite - on the combustion in the iron ore sintering bed are investigated by modeling and experiment. Fuel characteristics of coke and anthracite are observed through a set of basic analysis and thermo-gravimetric analysis. Coke has a higher reactivity than anthracite due to the difference of surface area and density, and these characteristics are reflected in the 1-D unsteady simulation of the iron ore sintering bed. Calculation results show that different reactivity of the fuel can affect the bed combustion.