• Applied Chemistry for Engineering
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• v.4 no.3
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• pp.474-481
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• 1993

The infinite dilution activity coefficients(${\gamma}{\infty}$) of nonpolar and polar solutes have been determined in different solvents at temperature between 60 and $100^{\circ}C$ by using gas chromatography. The $ln{\gamma}{\infty}$ values of nonpolar solutes(alkanes, cyclohexane, benzene, toluene and $CCl_4$) were linearly increased as 1/T in the nonpolar solvent (n-octadecane) and the polar solvent(n-hexadecyl alcohol) systems and the $ln{\gamma}{\infty}$ values at the constant temperature were increased with the number of carbon atoms of solute molecule. For the polar solutes(alcohols, esters and ketones) and the weak polar solvent(di-2-ethyl adiphate and di-2-ethylhexyl sebacate) systems, the relations of $ln{\gamma}{\infty}$ vs. 1/T were found to be curved with increased slope, and the $ln{\gamma}{\infty}$ values at constant temperature were linearly diminished as increasing the number of carbon atoms of solute molecule. For the polar solutes(alcohols, esters and ketones) and the strong polar solvents(triphenyl phosphate and tricresyl phosphate)systems, the relations of $ln{\gamma}{\infty}$ vs. 1/T were found to be curved with increased slope but $ln{\gamma}{\infty}$ values at constant temperature were linearly increased as increasing the number of carbon atoms of solute molecule.

• Journal of Energy Engineering
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• v.21 no.4
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• pp.339-345
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• 2012

RMembrane LNG storage tanks have been recently investigated to replace full-containment LNG storage tanks because of safety and cost aspects. Quantitative Risk Analysis (QRA) and Finite Element Method (FEM) were used to evaluate safety of membrane LNG storage tanks. In this study, structural safety evaluation results via FEM analysis showed that both membrane type and full-containment type cryogenic LNG storage tanks with 140,000 $m^3$ capacity were equivalently safe in terms of strength safety and leakage safety of a storage tank system. Also, Fault Tree Analysis (FTA) was used to improve the safety of membrane LNG storage tanks and membrane LNG tanks were modified by adding three safety equipments: impact absorber structure for the low part of the membrane, the secondary barrier to diminish the thermal stress of the corner part of the outer tank, and a pump catcher in case of falling of a pump. Consequently, the safety of the modified membrane LNG storage tanks were proved to be equivalent to that of full-containment LNG storage tanks.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.9
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• pp.513-520
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• 2016

It is well known that volatile compounds including disinfection by-products as well as emissive dissolved gas in water can be removed effectively by air stripping. The micro-bubbles of flotation unit are so tiny as microns while the diameter of fine bubbles applied to air stripping is ranged from hundreds to thousands of micrometer. Therefore, the micro-bubbles in flotation can supply very wide specific surface area to transfer volatile matters through gas-liquid boundary. In addition, long emission time also can be gained to emit the volatile compound owing to the slow rise velocity of micro-bubbles in the flotation tank. There was a significant difference of the THMs species removal efficiency between air stripping and flotation experiments in this study. Moreover, the results of comparative experiments on the removal characteristics of THMs between air stripping and flotation revealed that the mass transfer coefficient, $K_La$ showed obvious differences. To overcome the limit of low removal efficiency of dissolved volatile compounds such as THMs in flotation process, the operation range of bubble volume concentration is required to higher than the operation condition of conventional particle separation.

• Journal of the Korean Chemical Society
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• v.46 no.4
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• pp.317-323
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• 2002

The composition of trace materials in domestic circulated LPG are determined. The sampling points are two cylinders of LPG cylinder re-inspection center, six vaporizer of LPG-supplying group facilities, and the compressed oil from one LPG station. In the trace materials from cylinder of LPG cylinder-reinspection center, alkene and diene derivative (No. of carbon ${\leq}9),$ aromatic compounds, and tarry chemicals(No. of carbon ${\geq}10)$ are 1.5~39.9%, 0.7%, 57.8~96.0%, respectively. While in the trace materials from LPG-supplying group facilities and in the oil from LPG station, tarry chemicals(No. of carbon>10) exceed 96.6%. Nine samples are classified into three clusters. One cluster is the sample of SE company cylinder-reinspection center(Euclidian distance between S company LPG cylinder-reinspection center and SE company cylinder-reinspection center=2.11), the other is the sample of SE company LPG cylinder-reinspection center(Euclidian distance between from samples of LPG-supplying group facilities including compressed oil from LPG station=0.110) the third is the samples of LPG-supplying group facilities(Euclidian distances among them<0.075). The compositions of samples from LPG-supplying group facilities are similar to those of oil from LPG station. Furthermore densities of samples from LPG-supplying group facilities and compressed oil in LPG station are 0.873, 0.873 [0.00798 (99% confidence limits) respectively. It was presumed that tarry chemicals had been leached from the compressed oil of LPG supplying facilities.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.7
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• pp.746-751
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• 2006

In this study, drying and carbonization experiment was conducted in a fluidized bed reactor according to the variations in gas velocity, particle size, and reactor temperature. As a result, the weight loss rates of sludge by drying in the fixed bed and fluidized bed type dryer showed that drying in the fluidized bed was about 6 times faster than drying in the fixed bed, and the weight loss rates of sludge by carbonization in the fixed bed and fluidized bed type reactor showed that carbonization in the fluidized bed was about 4 times faster than drying in the fixed bed. This implies that carbonization in the fluidized bed was completed within 10 minutes. Although the amount of char decreased with the increase of carboniration temperature, the amount of char became similar at upper 873K. Also, the amount of char decreased with increasing gas velocity. Consequently, it could be efficient that slow fluidization should be maintained within the range of fluidization in case of fluidized carbonization of sewage sludge at 873K.

• Journal of the Korean Institute of Gas
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• v.2 no.2
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• pp.1-11
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• 1998

A quantitative risk assessment and consequence analysis for PBL(Poly Butadiene Latex) reaction processes were performed. As a result of the Quantitative risk assessment, for the accident probability of PBL reactors causing a reaction runaway, was calculated as $9.197{\times}10^{-5}/yr$ The most important factor that affected the accident probability of PBL reactor was the relief device. When the reactor exploded, peak overpressure at the target point was $5.066{\times}10^5(Pa)$ and the range of effects windows to be broken occurred in almost all of the factory areas. The maximum radius of effect was 27m, in which workers could be die by the direct for eardrum damage was calculated at 77m. When the PBL reactor exploded, the extent of structural damage to buildings was calculated from the center of the explosion to a range of 52m. The results of the study's assessment have provided a direction for facility's improvement as well as effective safety investment.

• Journal of Energy Engineering
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• v.28 no.3
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• pp.18-25
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• 2019

In this study, in order to solve the problem of the program of calculating code input by experienced users in the power generation, the wide area energy network research group developed the local heating operation analysis program EntPLAN, which can be easily used by anyone, including scalability, with domestic technology. Therefore, the Commission intended to compare the heat sources, heat demand, and the results of operation of the combined heat plant (CHP) on the energy network through simulation with the EnetPLAN and the program A on the market. The results showed that the heat and power output on the energy network of the EnetPLAN and A programs were mostly similar in pattern in the simulation results of the heat supply and the operation method of the accumulator. This enabled the application of the simulation for the various operation modes of the cogeneration facilities existing on the energy network. It is expected that EntPLAN, which was developed with domestic technology, will be easily applied in the field in the future and will present efficient operation simulation results.

• Journal of the Korea Organic Resources Recycling Association
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• v.11 no.3
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• pp.75-86
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• 2003

In the near future, the capacity of conventional anaerobic digester is thought to be insufficient because of the increase of the total solids from expansion of intercepting sewer, sewage quantity and direct input of night soil from near apartment districts. The objectives of this study was to investigate the improvement of digestion efficiency using microbial agent(Bio-dh). The system was a pilot-scale, two-staged, anaerobic sludge digestion system. The first-stage digester was heated and mixed. The agitation velocity of the first-stage digester was 120rpm. The second-stage digester was neither heated nor mixed. The Digestion temperature was kept at $35{\pm}1^{\circ}C$ The detention time of digester was 19 days. The dosage of sewage sludge and microbial agent were $0.65m^3/day$ and $0.5{\ell}/day$, respectively. The experiments was run for 25days. Three times a week, $COD_{Mn}$ and SS of effluent, TS, VS, and biogas production rate were measured. Temperature, pH, and alkalinity were measured daily. The results were as follows ; Without microbial agent, digestion efficiencies ranged 46.0%~50.9%(mean=48.6%), with microbial agent(Bio-dh), digestion efficiencies ranged 52.8%~57.3%(mean=54.2%). Consequently, microbial agent(Bio-dh) increased the sludge digestion efficiency about 12%. Also, Without microbial agent, the mean concentration of $COD_{Mn}$ and SS of second-stage digester effluent were 1,639mg/L, 4,888mg/L respectively. With microbial agent, the mean concentration of $COD_{Mn}$ and SS of second-stage digester effluent were 859mg/L, 2,405mg/L respectively. Consequently, microbial agent(Bio-dh) increased the removal efficiency of $COD_{Mn}$ and SS about 47.6% and 50.8%, respectively.

• Korean System Dynamics Review
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• v.2 no.2
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• pp.25-40
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• 2001

This paper describes the forecast of power plant construction in a competitive korean electricity market. In Korea, KEPCO (Korea Electric Power Corporation, fully controlled by government) was responsible for from the production of the electricity to the sale of electricity to customer. However, the generation part is separated from KEPCO and six generation companies were established for whole sale competition from April 1st, 2001. The generation companies consist of five fossil power companies and one nuclear power company in Korea at present time. Fossil power companies are scheduled to be sold to private companies including foreign investors. Nuclear power company is owned and controlled by government. The competition in generation market will start from 2003. ISO (Independence System Operator will purchase the electricity from the power exchange market. The market price is determined by the SMP(System Marginal Price) which is decided by the balance between demand and supply of electricity in power exchange market. Under this uncertain circumstance, the energy policy planners such as government are interested to the construction of the power plant in the future. These interests are accelerated due to the recent shortage of electricity supply in California. In the competitive market, investors are no longer interested in the investment for the capital intensive, long lead time generating technologies such as nuclear and coal plants. Large unclear and coal plants were no longer the top choices. Instead, investors in the competitive market are interested in smaller, more efficient, cheaper, cleaner technologies such as CCGT(Combined Cycle Gas Turbine). Electricity is treated as commodity in the competitive market. The investors behavior in the commodity market shows that the new investment decision is made when the market price exceeds the sum of capital cost and variable cost of the new facility and the existing facility utilization depends on the marginal cost of the facility. This investors behavior can be applied to the new investments for the power plant. Under these postulations, there is the potential for power plant construction to appear in waves causing alternating periods of over and under supply of electricity like commodity production or real estate production. A computer model was developed to sturdy the possibility that construction will appear in waves of boom and bust in Korean electricity market. This model was constructed using System Dynamics method pioneered by Forrester(MIT, 1961) and explained in recent text by Sternman (Business Dynamics, MIT, 2000) and the recent work by Andrew Ford(Energy Policy, 1999). This model was designed based on the Energy Policy results(Ford, 1999) with parameters for loads and resources in Korea. This Korea Market Model was developed and tested in a small scale project to demonstrate the usefulness of the System Dynamics approach. Korea electricity market is isolated and not allowed to import electricity from outsides. In this model, the base load such as unclear and large coal power plant are assumed to be user specified investment and only CCGT is selected for new investment by investors in the market. This model may be used to learn if government investment in new unclear plants could compensate for the unstable actions of private developers. This model can be used to test the policy focused on the role of unclear investments over time. This model also can be used to test whether the future power plant construction can meet the government targets for the mix of generating resources and to test whether to maintain stable price in the spot market.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.6
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• pp.19-25
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• 2019

The CleanSYS(Clean SYStem) is operated to monitor air pollutants emitted from specific industrial complexes in Korea. So the industrial complexes without the system are directly monitored by the control officers. For efficient monitoring, studies using various sensors have been conducted to monitor air pollutants emitted from industrial complex. In this study, hyperspectral sensors were used to model and verify the equations for estimating the concentration of $NO_2$(nitrogen dioxide) in air pollutants emitted. For development of the equations, spectral radiance were observed for $NO_2$ at various concentrations with different SZA(Solar Zenith Angle), VZA(Viewing Zenith Angle), and RAA(Relative Azimuth Angle). From the observed spectral radiance, the calculated value of the difference between the values of the specific wavelengths was taken as an absorption depth, and the equations were developed using the relationship between the depth and the $NO_2$ concentration. The spectral radiance mixed gas of $NO_2$ and $SO_2$(sulfur dioxide) was used to verify the equations. As a result, the $R^2$(coefficient of determination) and RMSE(Root Mean Square Error) were different from 0.71~0.88 and 72~23 ppm according to the form of the equation, and $R^2$ of the exponential form was the highest among the equations. Depending on the type of the equations, the accuracy of the estimated concentration with varying concentrations is not constant. However, if the equations are advanced in the future, hyperspectral sensors can be used to monitor the $NO_2$ emitted from the industrial complex.