• Food Science and Preservation
• /
• v.24 no.4
• /
• pp.505-509
• /
• 2017

Water vapor adsorption kinetics of vacuum-dried jujube powder were investigated in temperature and relative humidity ranges of 10 to $40^{\circ}C$ and 32 to 75%, respectively. Water vapor was initially adsorbed rapidly and then reached equilibrium condition slowly. Reaction rate constant for water vapor adsorption of vacuum-dried jujube powder increased with an increase in temperature. The temperature dependency of water activity followed the Clausius-Clapeyron equation. The net isosteric heat of sorption increased with an increase in water activity. Good straight lines were obtained with plotting of $1/(m-m_0)$ vs. 1/t. It was found that water vapor adsorption kinetics of vacuum-dried jujube powder was accurately described by a simple empirical model, and temperature dependency of the reaction rate constant followed the Arrhenius-type equation. The activation energy ranged from 50.90 to 56.00 kJ/mol depending on relative humidity. Arrhenius kinetic parameters ($E_a$ and $k_0$) for water vapor adsorption by vacuum-dried jujube powder showed an effect between the parameters with the isokinetic temperature of 302.51 K. The information on water vapor adsorption kinetics of vacuum-dried jujube powder can be used to establish the optimum condition for storage and processing of jujube.

• Korean Journal of Metals and Materials
• /
• v.49 no.12
• /
• pp.956-966
• /
• 2011

Bioleaching studies of metals from a spent catalyst were conducted using both adapted and unadapted bacterial cultures. The bacterium used in this experiment was Acidithiobacillus ferrooxidans. A comparison of the kinetics of leaching was made between the two cultures by varying the leaching parameters, including the pulp density, particle size and temperature. Both cultures showed similar effects with respect to the above parameters, but the leaching rates of all metals were higher with the adapted compared to the unadapted bacterial cultures. The leaching reactions were continued for 240 h in the case of the unadapted bacterial culture, but only for 40 h in the case of the adapted bacterial culture. The leaching reactions followed first order kinetics. In addition, the kinetics of leaching was concluded to be a diffusion control model; therefore, the product layers were impervious.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.37 no.4
• /
• pp.383-391
• /
• 2009

The detonation wave characteristics of JP-7 and oxygen mixture is investigated by one-step induction parameter model (IPM) obtained from a detailed chemistry mechanism. A general procedure of obtaining reliable one-step kinetics IPM for hydrocarbon mixture from the fully detailed chemistry is described in this study. The IPM is obtained by the reconstruction of the induction time database obtained from a detailed kinetics library. The IPM was confirmed by the comparison of the induction time calculations with that from detailed kinetics. The IPM is later implemented to a fluid dynamics code and applied for the numerical simulation of detonation wave propagation. The numerical results show the detailed characteristics of the detonation wave propagation in JP-7 and oxygen mixture at affordable computing time, which is not be possible by the direct application of the detailed chemical kinetics mechanism of hydrocarbon fuel combustion.

• Journal of Environmental Science International
• /
• v.14 no.9
• /
• pp.881-888
• /
• 2005

The biosorption of dye, Rhodamine B(Rh-B), onto waste activated sludge was investigated. The biosorption capacity and contact time were shown as a simulation of dye adsorption equilibrium and kinetics models. We observed that biosorption of Rh-B occurred rapidly less than 4 hr. These experimental data could be better fitted by a pseudo-second-order rate equation than a pseudo-first-order rate equation. The equilibrium dependence between biosorption capacity and initial concentration of Rh-B was estimated and it was found that the equilibrium data of biosorption were fitted by four kinds of model such as Langmuir, Freundlich, Redlich-Peterson, and Koble-Corrigan model. The average percentage errors, $\varepsilon(\%)$, observed between experimental and predicted values by above each model were $21.19\%,\;9.97\%,\;10.10\%\;and\;11.76\%$, respectively, indicating that Freundlich and Redlich-Peterson model could be fitted more accrately than other models.

• 한국연소학회:학술대회논문집
• /
• 2012.11a
• /
• pp.67-70
• /
• 2012

Many computational fluid dynamic (CFD) simulations have treated the coal kinetics poorly due to large physical domain sizes and high computational complexity, particularly for the recent oxy-coal boilers. Furthermore, some modelers' lack of understanding of the kinetic rate model seems to worsen the simulation accuracy. This study is to suggest the importance of proper use of single-film global kinetic model generally used in CFD code to describe the oxy-fuel combustion of coal char through simple char burnout calculation.

• Nuclear Engineering and Technology
• /
• v.53 no.2
• /
• pp.414-422
• /
• 2021

The aim of this work considers a second order point reactor kinetics model based on the P1 approximation of transport theory, called in this work as P1 point reactor model. The P1 point reactor model implicitly considers the time derivative of the neutron source which has not been thus considered previously. The inverse method to calculate the reactivity in nuclear reactors -chosen because its high accuracy- Matrix Formulation. The numerical results shown that the Matrix Formulation for the reactivity estimation constitutes a method with insignificant calculation errors.

• Korean Chemical Engineering Research
• /
• v.52 no.6
• /
• pp.821-825
• /
• 2014

Steam gasification of sawdust char was performed in a thermobalance reactor at high temperature. Gasification temperature was changed from $850^{\circ}C$ to $1400^{\circ}C$ and steam partial pressure was 0.3, 0.5 and 0.7 atm. Three models of gas-solid reaction were applied to the reaction kinetics analysis and modified volumetric model was an appropriate model. Reaction control regime and diffusion control regime were distinct depending on the temperature. Apparent activation energy and pre-exponential factors for both of the regimes were evaluated and the effects of steam partial pressure were examined. $H_2$ concentration in the produced gas was two times higher than that of CO due to the gasification accompanying by the water gas shift reaction.

• Journal of Sensor Science and Technology
• /
• v.3 no.2
• /
• pp.16-23
• /
• 1994

Developed fiber-optic biosensor for the detection of organophosphorus compounds in a contaminated water needs the analysis of an enzyme kinetics and the transport phenomena in the reaction part to analyze the sensor signal and to design the sensor. The enzyme inhibition kinetics was investigated and the reactor model was proposed to design the reaction part in the proposed sensor. Since the acetylcholinesterase was inhibited by the organophosphorus compounds, experiments for enzyme inhibition reaction were performed from 0 to 2 ppm to be detected by the developed sensor, and irreversible enzyme inhibition kinetics was proposed. The reactor parts were divided into the two phases, i.e. bulk phase and immobilized enzyme layer, to analyze the flow and diffusion. Sensor signal was able to be analyzed based on the total reactor model established by linking the enzyme reaction kinetics. Based on the proposed model, the effects of loading enzyme amount and enzyme layer thickness on the magnitude of readout signal were simulated.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.34 no.7
• /
• pp.89-96
• /
• 2006

The combustion temperature in gas generator should be kept below around 1,000K to avoid any possible thermal damages to turbine blade by adopting either fuel rich or oxidizer rich combustion. Thus, non-equilibrium chemical reaction dominates in the gas generator. Meanwhile, Kerosene is a compounded fuel mixed with various types of hydrocarbon elements and difficult to model the chemical kinetics. This study focus to model the non-equilibrium chemical reaction of kerosene/LOX with detailed kinetics developed by Dagaut using PSR(Perfectly stirred reactor) assumption. Also, droplet evaporation time is taken into account by calculating for the residence time of droplet and by decoupling reaction temperature from the reactor temperature. In Dagaut’s surrogate model for kerosene, chemical kinetics of kerosene consists of 1592 reaction steps with 207 chemical species. The comparison of calculation results with experimental data could provide very reliable and accurate numbers in the prediction of combustion gas temperature, species fraction and other gas properties.

• Journal of Microbiology and Biotechnology
• /
• v.27 no.2
• /
• pp.297-305
• /
• 2017

The use of peroxidase in the nitration of phenols is gaining interest as compared with traditional chemical reactions. We investigated the kinetic characteristics of phenol nitration catalyzed by horseradish peroxidase (HRP) in an aqueous-organic biphasic system using n-butanol as the organic solvent and ${NO_2}^-$ and $H_2O_2$ as substrates. The reaction rate was mainly controlled by the reaction kinetics in the aqueous phase when appropriate agitation was used to enhance mass transfer in the biphasic system. The initial velocity of the reaction increased with increasing HRP concentration. Additionally, an increase in the substrate concentrations of phenol (0-2 mM in organic phase) or $H_2O_2$ (0-0.1 mM in aqueous phase) enhanced the nitration efficiency catalyzed by HRP. In contrast, high concentrations of organic solvent decreased the kinetic parameter $V_{max}/K_m$. No inhibition of enzyme activity was observed when the concentrations of phenol and $H_2O_2$ were at or below 10 mM and 0.1 mM, respectively. On the basis of the peroxidase catalytic mechanism, a double-substrate ping-pong kinetic model was established. The kinetic parameters were ${K_m}^{H_2O_2}=1.09mM$, ${K_m}^{PhOH}=9.45mM$, and $V_{max}=0.196mM/min$. The proposed model was well fit to the data obtained from additional independent experiments under the suggested optimal synthesis conditions. The kinetic model developed in this paper lays a foundation for further comprehensive study of enzymatic nitration kinetics.