• Bulletin of the Korean Chemical Society
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• v.28 no.9
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• pp.1553-1561
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• 2007

The new type of heterometallic chiral polymer salen complexes have been synthesized and it has been found that group 13 metal salts (AlCl3, GaCl3 and InCl3) combined to cobalt salen unit played the crucial role in the asymmetric kinetic resolution of racemic epoxides. Polymeric salen catalysts showed very high reactivity and enantioselectivity for the asymmetric ring opening of terminal epoxide with diverse nucleophiles. They provide the enantiopure useful chiral intermediates such as chiral terminal epoxides and α -aryloxy alcohols in one-step process. An efficient methodology for providing very high enantioselectivity can be achieved in the synthesis of valuable chiral building blocks via our catalytic system by combination of various asymmetric ring opening reactions.

• The Transactions of the Korean Institute of Electrical Engineers B
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• v.49 no.5
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• pp.358-363
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• 2000

In this paper, a voltage equations, a thrust force equations and kinetic equation are derived from the basic structure of a 2-phase hybrid type linear stepping motor(HLSM). And a micro-stepping method in order to eliminate effectively the resonant phenomena and to increase the positional resolution of the HLSM was proposed. The proposed micro-stepping method can divide one step into the maximum 128 micro-steps under simple control system. The dynamic characteristics of proposed micro-stepping method were analyzed by the ACSL(Advanced Continuous Simulation Language) with the voltage equations, the thrust force equations and the kinetic equation, and were measured by laser experimental system. As the result, the justice of theory was confirmed, and the resonant phenomena, the positional resolution and dynamic thrust were improved by the proposed micro-stepping method.

• 한국생물공학회:학술대회논문집
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• 2003.04a
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• pp.521-521
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• 2003

• Bulletin of the Korean Chemical Society
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• v.27 no.5
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• pp.755-758
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• 2006

• Journal of Microbiology and Biotechnology
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• v.16 no.1
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• pp.32-36
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• 2006

The genome sequences from several microbes have led to the discovery of numerous open reading frames of unknown functionality. The putative bacterial epoxide hydrolase (EH) genes selected from the genome databases were examined for their activities toward various epoxides. Among the nine open reading frames (ORFs) from four microbial species, the ORF from Caulobacter crescentus showed an epoxide hydrolase activity. The kinetic resolution, using C. crescentus EH (CCEH) of the aryl epoxides such as styrene oxide, could be performed more efficiently than short aliphatic epoxides. The resolution of racemic indene oxide, which could previously be resolved only by fungal epoxide hydrolases, was effectively accomplished by CCEH.

• Bulletin of the Korean Chemical Society
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• v.34 no.8
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• pp.2531-2534
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• 2013

• Korean Journal of Materials Research
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• v.24 no.1
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• pp.60-65
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• 2014

Fe-based amorphous coatings were fabricated on a soda-lime glass substrate by the vacuum kinetic spray method. The effect of the gas flow rate, which determines particle velocity, on the deposition behavior of the particle and microstructure of the resultant films was investigated. The as-fabricated microstructure of the film was studied by field emission scanning electron microscopy (FE-SEM) and high resolution transmission electron microscopy (HR-TEM). Although the activation energy for transformation from the amorphous phase to crystalline phase was lowered by severe plastic deformation and particle fracturing under a high strain rate, the crystalline phases could not be found in the coating layer. Incompletely fractured and small fragments 100~300 nm in size, which are smaller than initial feedstock material, were found on the coating surface and inside of the coating. Also, some pores and voids occurred between particle-particle interfaces. In the case of brittle Fe-based amorphous alloy, particles fail in fragmentation fracture mode through initiation and propagation of the numerous small cracks rather than shear fracture mode under compressive stress. It could be deduced that amorphous alloy underwent particle fracturing in a vacuum kinetic spray process. Also, it is considered that surface energy caused by the formation of new surfaces and friction energy contributed to the bonding of fragments.

• The KSFM Journal of Fluid Machinery
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• v.10 no.4
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• pp.47-54
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• 2007

Simultaneous 3-D LDV measurements of the in-cylinder flows of three different engine setups were summarized for the quantification of the flow characteristics in each vertical or horizontal plane, and in entire cylinder volume. The ensemble averaged-velocity, tumble and swirl motions, and turbulent kinetic energy during the intake and compression strokes were examined from the measured velocity data (approximately 2,000 points for each engine setup). The better spatial resolution of the 3-D LDV allows measurements of the instantaneous flow structures, yielding more valuable information about the smaller flow structures and the cycle-to-cycle variation of these flow patterns. Tumble and swirl ratios, and turbulent kinetic energy were quantified as planar and volumetric quantities. The measurements and calculation results were animated for the visualization of the flow, and hence ease to analysis.

• Bulletin of the Korean Chemical Society
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• v.26 no.5
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• pp.826-828
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• 2005

• 한국생물공학회:학술대회논문집
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• 2003.10a
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• pp.496-496
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• 2003